A bio-renewable conversion process for making fuel from bio-renewable feedstocks is combined with a hydrogen production process that includes recovery of CO.sub.2. The integrated process uses a purge gas stream comprising hydrogen from the bio-renewable hydrocarbon production process in the hydrogen production process.

The disclosure relates to a process for converting lignin (10) to renewable product (80), wherein the process comprises the following steps; mixing (100) lignin (10) with aqueous solution (20) to obtain a mixture (30); heating (110) the mixture (30) of step (a) to a temperature between 290 and 350° C., under a pressure from 70 to 165 bar, to obtain a first product mix (40); separating aqueous phase (53) and oil phase (50), and optionally gas (51) and solids (52), of the first product mix (40) of step (b); and heating (130) the oil phase (50) of step (c) and solvent (60) to obtain a second product mix (70). The second product mix (70) can be used as such, it can be directed to separation (140) or it can be upgraded. The obtained liquid renewable product is suitable as chemicals, fuel, fuel components or feedstock for fuel production.

Ionic liquids of the general formula C.sup.+A.sup.− where C.sup.+ represents an organic cation, specifically, but not limited to the imidazolium, pyridinium, isoquinolinium, ammonium types, which have aliphatic and aromatic substituents, while A.sup.− represents a carboxylate, aromatic and aliphatic anion. The ionic liquids are synthesized under conventional heating or microwave irradiation This invention is also related to the application of ionic liquids to remove sulfur compounds of naphthas through a liquid-liquid extraction and the recovery and reuse of ionic liquids by the application of heat, reduced pressure and washing with solvents.

In one aspect, the present invention relates to a furnace having a heated portion arranged adjacent to an unheated portion. A plurality of straight tubes are formed of a first material and are at least partially disposed in the heated portion. A plurality of return bends are operatively coupled to the plurality of straight tubes. The plurality of return bends are formed of a second material and are at least partially disposed in the unheated portion. The first material exhibits a maximum temperature greater than the second material thereby facilitating increased run time of the furnace. The second material exhibits wear-resistance properties greater than the first material thereby facilitating wear-resistance of the furnace.

An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.

Chemical reactor with high speed rotary mixing, system thereof, and method thereof, for catalytic thermal conversion of organic (hydrocarbon-containing) materials (coal, plastics, rubber, plant matter, wood shavings, biomass, organic wastes) into diesel and other liquid fuels (automobile or/and jet engine fuels). Relevant to non-conventional commercial scale production of liquid fuels, and to commercial scale processing and disposing of organic waste materials. Chemical reactor includes: integrated combination of a reactor stationary assembly (RSA), having only stationary components remaining stationary during chemical reactor operation, and a reactor rotary mixing assembly (RRMA), having only rotatable components rotating during chemical reactor operation. May include anti-abrasion shield for shielding inner surface of reactor central housing from abrasion during chemical reactor operation. Rotor may include a reinforcement disc. Rotor blades or/and reinforcement disc may include rotor-based performance and process control structural features (openings, or/and protrusions, or/and depressions), for additionally controlling performance of the rotor.

Methods for reducing impurities and improving color in liquid hydrocarbon products (e.g., diesel fuel) are provided herein.

A three step method for the conversion of ethanol into fuels that can be utilized as full-performance military jet or diesel fuels. Embodiments of the invention further describe methods for the selective conversion of ethanol to full performance saturated hydrocarbon fuels that are suitable for both jet and diesel propulsion.

A method and process of producing gasoline and diesel from hydrocarbon wastes, by gradually heating the hydrocarbon waste in a reducing atmosphere, up to 550° C. During the heating process and at various temperature points long chains of hydrocarbon are broken down into smaller hydrocarbon chains. During the heating process radical hydrogen gas is introduced to the reactor where the radical hydrogen gas reacts with smaller hydrocarbon chains to produce 45% coke petroleum oil, 45% liquid hydrocarbons composed of gasoline and gasoil and 10% gases including methane, ethane, propane and steam. The radicalized hydrogen atoms are produced at low temperatures and atmospheric pressure. Hydrogen gas is produced by dissolving aluminum scraps are dissolved in a sodium hydroxide solution in a reactor. As hydrogen gas is produced the reactor is heated to 120° C. in the presence of electromagnetic waves causing the breakdown of hydrogen gas into hydrogen gas radicals.

According to the present invention, organic material is converted to biogas through anaerobic digestion and the biogas is purified to yield a combustible fluid feedstock comprising methane. A fuel production facility utilizes or arranges to utilize combustible fluid feedstock to generate renewable hydrogen that is used to hydrogenate crude oil derived hydrocarbons in a process to make transportation or heating fuel. The renewable hydrogen is combined with crude oil derived hydrocarbons that have been desulfurized under conditions to hydrogenate the liquid hydrocarbon with the renewable hydrogen or alternatively, the renewable hydrogen can be added to a reactor operated so as to simultaneously desulfurize and hydrogenate the hydrocarbons. The present invention enables a party to receive a renewable fuel credit for the transportation or heating fuel.