Patent classifications
C10G2400/04
CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYPROPYLENE AND LUBRICATING OIL VIA REFINERY FCC AND ISOMERIZATION DEWAXING UNITS
A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas C.sub.3 olefin/paraffin mixture. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with a propane/propylene splitter. The C.sub.3 olefin fraction is passed to a propylene polymerization reactor. The C.sub.3 paraffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting C.sub.3 olefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil.
CO-PROCESSING OF WASTE PLASTIC PYROLYSIS OILS AND BIORENEWABLE FFEDSTOCKS
A process is provided for producing a liquid hydrocarbon material suitable for use as a fuel or as a blending component in a fuel. The process includes co-processing a pyrolysis oil derived from a waste plastic raw material and a biorenewable feedstock comprising triglycerides in a catalytic cracking process in a presence of a solid catalyst at catalytic cracking conditions to provide a cracking product. The cracking product may be fractionated to provide at least one of a gasoline fraction and a middle distillate fraction.
Process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries
The present invention relates to a process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries, in particular comprising recycling streams from the steam reforming hydrogen production process as the feedstock for the Fischer-Tropsch process.
WASTE RECOVERING SYSTEM AND METHOD THEREOF
The present invention relates to automated waste recovering system and method which is not limited to a specific type of waste only. The system comprises a reactor for pyrolysis, a condensing unit connected to a water-cooled chiller to obtain liquid phase products and non-condensable gas, a gas treatment unit, a series of gas filtration unit to obtain clean gas, a storage and a control unit. The system also comprises a gas mixer unit to mix the non-condensable gas with hydrogen to obtain hydrocarbon rich gas, an artificial fuel condensing unit for condensing the hydrocarbon rich gas to obtain artificial fuel and water, which subsequently separated in a phase separator unit. The present invention provides a means to achieve constant yield by controlling conditions in the reactor and further increase the yield by producing artificial fuel.
MULTI-STAGE PROCESS AND DEVICE UTILIZING STRUCTURED CATALYST BEDS AND REACTIVE DISTILLATION FOR THE PRODUCTION OF A LOW SULFUR HEAVY MARINE FUEL OIL
A multi-stage process for the production of a Product Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel from a high sulfur Feedstock Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel except for the sulfur level, involving hydrotreating under reactive distillation conditions in a Reaction System composed of one or more reaction vessels. The reactive distillation conditions allow more than 75% by mass of the Process Mixture to exit the bottom of the reaction vessel as Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a maximum sulfur content (ISO 14596 or ISO 8754) less than 0.5 mass %. A process plant for conducting the process for conducting the process is disclosed.
Process for purification and conversion of carbon dioxide using renewable energy
The present invention is generally directed to processes and systems for the purification and conversion of CO.sub.2 into low-carbon or zero-carbon high quality fuels and chemicals using renewable energy. In one aspect, the present invention provides a process for producing a stream comprising at least 90 mol % CO.sub.2. In certain cases, the CO.sub.2 stream is processed to make low carbon fuels and chemicals. In this process at least a portion of the CO.sub.2 is reacted with a stream comprising H.sub.2 in a Reverse Water Gas Shift (RWGS) reactor to produce a product stream that comprises CO.
CO-PROCESSING OF RENEWABLE JET AND DIESEL
Systems and methods are provided for co-processing of renewable distillate fractions with mineral fractions to produce at least a jet (or kerosene) boiling range product and a diesel boiling range product. A combination of a jet boiling range product fraction and a diesel boiling range product fraction with unexpected properties can be formed by first blending i) a distillate boiling range feed fraction containing a renewable distillate component with ii) a mineral feed fraction (possibly corresponding to a whole or partial crude oil) that includes diesel boiling range compounds to form a blended composition. The blended composition can then be fractionated to form a jet boiling range product fraction and a diesel boiling range product fraction. Optionally, the resulting jet boiling range product fraction and/or diesel boiling range product fraction can be exposed to further processing, such as hydroprocessing or catalytic cracking.
PROCESS FOR OBTAINING ALKYL-NAPHTHENICS
The present invention addresses to a process for the production of alkyl-naphthenics for use as diesel and/or aviation kerosene (JET A-1), whose process involves the alkylation of olefins with monoaromatics and subsequent hydrogenation to alkyl-naphthenics. The process and catalysts of the present invention allow the regeneration of the acidic catalyst with a hydrogenating function and full recovery of its activity with hydrogen hot stripping. The catalyst is used for the formation of intermediate alkyl-aromatics and can also be used in the subsequent hydrogenation to alkyl-naphthenics.
METHOD OF MANUFACTURING RENEWABLE DIESEL FROM BIOLOGICAL FEEDSTOCK
A method for producing renewable diesel includes introducing a primary feedstock comprising biologically-derived triglycerides with catalyst poisons into a first reaction chamber and hydrolyzing the primary feedstock within the first reaction and liquid-liquid extraction chamber for at least an hour such that the reacted triglycerides are separated into an aqueous solution comprising glycerol and catalyst poisons, and an intermediate feedstock comprising free fatty acids and catalyst poisons. The method also includes distilling the intermediate feedstock to separate the intermediate feedstock into a purified intermediate stream and a lower volume bottom stream containing unreacted triglyceride, diglyceride, monoglyceride, FFA and catalyst poisons. The method also includes combining the purified intermediate feedstock with a hydrogen stream and converting, in a second reaction chamber comprising a metallic catalyst bed, the purified intermediate feedstock into a product comprising long-chain alkanes. The method also includes hydrotreating the purified intermediate feedstock into a renewable diesel product.
Process for the manufacture of diesel range hydrocarbons
The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400° C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.