A biofuel includes a mixture having a gasoil generated from hydropyrolysis and hydroconversion of a solid biomass containing lignocellulose and an isomerized hydroprocessed ester and fatty acid (HEFA) generated from hydrotreating a renewable resource having fats and oils. The gasoil has a cetane index less than 46 and at least 10 parts per million weight (ppmw) of a heteroatom and a cetane index of the biofuel is greater than 46.

A biofuel includes a mixture of a gasoil generated from hydropyrolysis and hydroconversion of a solid biomass containing lignocellulose. The gasoil has a cetane index less than 46. The biofuel also includes a hydroprocessed ester fatty acid (HEFA) generated from hydrotreating a renewable resource having fats and oils. A cetane index of the biofuel is greater than 46.

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.

In an aspect, a method of decontaminating a hydrocarbon fluid comprises applying an ultrasonic wave to the hydrocarbon fluid in a storage tank to maintain or reduce an amount of a microorganism in the storage tank; wherein a source of the ultrasonic wave is located within the storage tank and the storage tank has at least one of an inner volume of greater than or equal to 20 meters cubed and/or that is capable of storing 55 to 160,000 liters of the hydrocarbon fluid. In another aspect, a method of decontaminating a hydrocarbon fluid comprises applying an ultrasonic wave to the hydrocarbon fluid to disrupt a cell membrane of a microorganism to form a disrupted microorganism and to reduce a particle size of the disrupted microorganism to be less than or equal to 1.5 micrometers thereby forming a clean hydrocarbon fluid suitable for injecting through an injection nozzle.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

A process for reducing the environmental contaminants in a ISO 8217: 2017 Table 2 compliant Feedstock Heavy Marine Fuel Oil and resulting product, the process involving: mixing a Feedstock Heavy Marine Fuel Oil with a Activating Gas to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture; separating the Product Heavy Marine Fuel Oil from the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil complies with ISO 8217:2017 Table 2 for residual marine fuel and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, are less than 0.5 wt. %. The Product Heavy Marine Fuel Oil can be used as blending stock for an ISO 8217:2017 Table 2 compliant, IMO 2020 compliant, low sulfur heavy marine fuel composition.

The invention is directed to a process to prepare a gas oil product from a carbonaceous particles of a biomass source comprising the following steps: (a) pyrolysis of the carbonaceous particles to a gaseous mixture of hydrocarbons in the absence of oxygen, (b) quenching the gaseous mixture of hydrocarbons by contacting with a liquid quench mixture of hydrocarbons having a lower temperature than the gaseous mixture thereby obtaining a rich liquid quench mixture and a quenched gas, and (c) isolating from the quenched gas a gas oil product by means of vacuum distillation, wherein the liquid gas oil is partly supplied to the top of the vacuum distillation column as a distillation reflux, partly used as part of the liquid quench mixture in (b) and partly discharged as the gas oil product.

A system and method are provided for the separation of hydrogen from natural gas feedstock to form hydrocarbon radicals. Aspects of the system include perpendicular magnetic and electric fields, a method of radical formation that separates hydrogen from the reaction process, and a separation method based on centrifugal forces and phase transitions. The gases rotate in the chamber due to the Lorentz force without any mechanical motion. Rotation separates gases and liquids by centrifugal force. The lighter species are collected from the mid region endpoint of the apparatus and fed back for further reaction. A new concept of controlled turbulence is introduced to mix various species. A novel magnetic field device is introduced comprised of two specially magnetized cylinders. A novel control of temperatures, pressures, electron densities and profiles by, RF, microwaves, UV and rotation frequency are possible especially when atomic, molecular, cyclotron resonances are taken into account. The electrodes can be coated with catalysts; the entire apparatus can be used as a new type of chemical reactor.

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.

A new catalyst hydroisomerizes C18 paraffins from fatty acids to a high degree to produce a composition with acceptable freeze point which retains 18 carbon atoms in the hydrocarbon molecule for jet fuel. We have discovered a fuel composition comprising at least 14 wt % hydrocarbon molecules having at least 18 carbon atoms and a freeze point not higher than −40° C. The composition also may exhibit a exhibiting a final boiling point of no more than 300° C. The hydroisomerization process can be once through or a portion of the product diesel stream may be selectively hydrocracked or recycled to hydroisomerization to obtain a fuel composition that meets jet fuel specifications.