A Fischer-Tropsch (FT) process with a hybrid membrane/PSA configuration provides high component recoveries from FT off gas with minimum power consumption. Synthesis gas from a synthesis gas production zone is reacted in an FT reaction zone forming a liquid stream and an off gas stream. The off gas from the FT reaction zone, which contains hydrogen, carbon monoxide, and methane reactants, is recycled to the synthesis gas production zone. A purge stream from the recycle loop is sent to a membrane separation unit where it is separated into a permeate stream and a residue stream. The residue stream is separated in a pressure swing adsorption (PSA) unit into a fuel gas stream and a second stream. The second stream can be compressed and recycled to the synthesis gas production zone.

Method of producing hydrocarbon fuels from polyolefin waste materials, wherein: polyolefin waste materials are subjected to continuous depolymerisation in a tower flow reactor with a movable packing, which comprises a heating system for heating the lower half of the reaction chamber, where products of depolymerisation are collected in a gaseous state through an outlet in the upper half of the reaction chamber; and the obtained products of depolymerisation are subjected to catalytic hydrogenation and isomerization in an atmosphere of synthesis gas, under atmospheric pressure, to obtain a mixture of hydrocarbon fuels; characterised in that: polyolefin waste materials are mixed with heated elements constituting the packing of the reactor until the surface of the packing elements is coated with a thin layer of plasticised material, wherein in the depolymerisation process that obtained mixture is fed as a stream into the reaction chamber from the top of the chamber, whereas a synthesis gas is fed in a counter current from the bottom, the gas comprising carbon monoxide (CO) and hydrogen (H.sub.2) with the molar ratio CO:H.sub.2 being from 0.25 to 1.5: from 0.5 to 3.

A method for reducing CO.sub.2 emissions from steam cracking operations can include: introducing an oxygen-rich stream comprising oxygen and from 0 wt % to 15 wt % nitrogen to a vessel; introducing hydrocarbon combustion fuel to the vessel; combusting oxygen and hydrocarbon combustion fuel in the vessel to (1) produce a flue gas comprising carbon dioxide and water and (2) heat a cracking coil passing through the vessel; and performing a steam cracking reaction in the cracking coil passing through the vessel.

A method upgrading waste to produce fuel can include: introducing a hydrocarbon feed stream into a 450 C. to 1050 C. coking zone of a reactor containing a fluidized bed of coke particles maintained at coking temperatures to produce a vapor phase hydrocarbon product while coke is deposited on the coke particles; allowing the coke particles to pass downwards to a stripper section of the reactor; introducing a steam stream into the stripper section; transferring the coke particles from the stripper section to a gasifier/burner; contacting the coke particles in the gasifier/burner an oxygen-containing gas in an oxygen-limited atmosphere at 850 C. to 1200 C. to heat the coke particles and form a fuel gas product that comprises carbon monoxide and hydrogen; recycling the heated coke particles from the gasifier/burner to the coking zone of the reactor; and introducing at least one waste stream to the reactor and/or the gasifier/burner.

Treatment of hydrocarbon streams, and in one non-limiting embodiment refinery distillates, with reducing agents, such as borohydride and salts thereof, alone or together with at least one co-solvent results in reduction of the sulfur compounds such as disulfides, mercaptans, thiophenes, and thioethers that are present to give easily removed sulfides. In one non-limiting embodiment, the treatment converts the original sulfur compounds into hydrogen sulfide or low molecular weight mercaptans that can be extracted from the distillate with caustic solutions, hydrogen sulfide or mercaptan scavengers, solid absorbents such as clay or activated carbon or liquid absorbents such as amine-aldehyde condensates and/or aqueous aldehydes.

A reforming reactor and process of using same in which residence time of feed within a chamber of a reactor is shortened. Feed is injected into the reactor into a non-reactive zone. The non-reactive zone has two portions, a first portion receiving the feed, and a second portion receiving a purge gas. The purge gas will flow from the second portion to the first portion to prevent flow of the feed from the first portion to the second portion. The combined gas may be passed to a reaction zone for catalytic reforming. The first portion and the second portion may be separated by a baffle.

A recycling method for plastic waste includes the steps of: (a) placing the plastic waste into a reactor; (b) heating the plastic waste in the reactor through a pyrolysis recovery process to generate flammable gas; (c) transferring flammable gas through a condensing unit to convert the flammable gas into liquid phase products; and (d) filtering the remaining out clean gas from the flammable gas by a filtration unit. A recycling system for plastic waste includes a reactor to decompose the plastic waste to create usable fuel products; a condensing unit operatively connected with the reactor; and a filtration unit operatively connected with said condensing unit to filter the usable fuel products.

A process for producing C2 and C3 hydrocarbons by a) subjecting a mixed hydrocarbon stream comprising a middle distillate to first hydrocracking to produce a first hydrocracking product stream, b) subjecting a second hydrocracking feed stream to second hydrocracking to produce a second hydrocracking product stream, wherein the second hydrocracking is more severe than the first hydrocracking and c) subjecting a C4 hydrocracking feed stream to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to obtain a C4 hydrocracking product stream, wherein the C4 hydrocracking is more severe than the second hydrocracking. The first hydrocracking product stream, the second hydrocracking product stream and the C4 hydrocracking product stream are fed to a separation system.

The present invention relates to a method for treating a cracked stream stemming from a fluid catalytic cracker unit (FCCU) in order to improve propylene recovery. The present invention also relates to the corresponding installation to implement the method.

Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC unit from which a liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is recovered. The liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, with a propane and butane fraction recovered from the alkylation unit. The propane and butane fraction is then passed to a steam cracker for ethylene production. In another embodiment, a naphtha fraction (C.sub.5-C.sub.8) is recovered from the alkylation unit and passed to the steam cracker. In another embodiment, a propane/propylene fraction (C.sub.3-C.sub.3) is recovered from the FCC and passed to the steam cracker.