A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.5 wt % by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO.sub.2/Al.sub.2O.sub.3 molar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%. The modified Y-type molecular sieve has a high crystallinity and a high thermal and hydrothermal stability, and is rich in secondary pores.

Described are a process and a system for processing aromatics-rich fraction oil. The process includes: (1) introducing an aromatics-rich fraction oil into a fifth reaction unit for hydrosaturation, followed by fractionation, to provide a first light component and a first heavy component; (2) introducing a deoiled asphalt and an aromatics-comprising stream including the first heavy component into a hydrogen dissolving unit to be mixed with hydrogen, and introducing the mixed material into a first reaction unit for a hydrogenation reaction; (3) fractionating a liquid-phase product from the first reaction unit to provide a second light component and a second heavy component; (41) introducing the second light component into a second reaction unit for reaction; and (42) introducing the second heavy component into a delayed coking unit for reaction; or using the second heavy component as a component of low sulfur ship fuel oil.

A method for the aromatization of hydrocarbons, comprising: introducing a feed stream to an aromatization catalyst in a fixed bed reactor wherein the feed stream comprises a hydrocarbon having 2 to 4 carbon atoms, converting the hydrocarbon having 2 to 4 carbon atoms to form an outlet stream comprising an aromatic hydrocarbon; wherein the feed stream is introduced at a GHSV of greater than or equal to 4,000 milliliters per gram of catalyst per hour(ml.Math.g.sup.−1 Cat.Math.h.sup.−1), and a pressure of greater than or equal to 0.4 MPa. The feed stream can comprise hydrogen in an amount of at least 0.1 volume percent (vol %) up to 20 vol % based upon total volume of the feed stream.

In a method and system for treating a catalytic cracking gasoline, a catalytic cracking process, or a plant employs a fluidized reactor to carry out hydrodealkylation treatment on a catalytic cracking oil gas or catalytic cracking gasoline, so that heavy aromatics present therein can be efficiently converted into light olefins and light aromatics. The method and system can improve the yield of light olefins, allow a long-period stable operation, relieve the contradiction between supply and demand of light aromatics, and solve the problem of high content of heavy aromatics that have low value and are difficult to be utilized in aromatics present in oil gas from catalytic cracking units.

A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.

An integrated process for conversion of a hydrocarbon stream comprising light naphtha to enhanced value products. The process includes passing the hydrocarbon stream through the first reactor, the first reactor being an isomerization reactor with an isomerization catalyst disposed therein to generate an isomerate stream comprising at least 20% by weight iso-paraffins. The process further includes passing the isomerate from the first reactor through a second reactor, the second reactor being an aromatization reactor with an aromatization catalyst disposed therein to generate an aromatic rich stream. The process finally includes passing the aromatic rich stream to an aromatic recovery complex to separate the aromatic rich stream into an aromatic fraction, a raffinate fraction comprising unconverted paraffins, and an aromatic bottoms fraction comprising C9+ hydrocarbons, where the aromatic fraction comprises benzene, toluene and mixed xylenes. An associated system for performing the process is also provided.

Described are methods for converting methane to olefins, aromatics, or a combination thereof using a single atom catalyst comprising CeO.sub.2 nanoparticles impregnated with individual atoms of noble metals including Pt, Pd, Rh, Ru, Ag, Au, Ir, or a combination thereof. These single atom catalysts of the present invention are heated with methane to form olefins and aromatics.

A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of P.sub.2O.sub.5, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, and an active element content of about 0.1% to about 5% by weight on the basis of the oxide, with the active element being gallium and/or boron. The modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm of about 20% to about 40%; a lattice constant of about 2.440 nm to about 2.455 nm, and a lattice collapse temperature of not lower than about 1060° C.

A process for converting pyrolysis effluent stream into hydrocarbon products. Waste plastics are pyrolyzed at high temperature in a pyrolysis reactor to obtain a plastic pyrolysis effluent stream. The plastic pyrolysis effluent stream is further sent to a steam cracking unit for the separation of plastic pyrolysis effluent stream into a C5+ hydrocarbon stream and a C4 hydrocarbon stream. The pyrolysis reactor is operated at a to obtain hydrocarbon products of high value.

Described are a process and a system for hydrotreating a deoiled asphalt. The process includes: (2) introducing a deoiled asphalt and an aromatics-containing stream into a first reaction unit for hydrogenation reaction, wherein the first reaction unit comprises a mineral-rich precursor material and/or a hydrogenation catalyst, and the first reaction unit is a fixed bed hydrogenation unit; (21) fractionating the liquid-phase product from the first reaction unit to provide a first light component and a first heavy component; (31) introducing the first light component into a second reaction unit for reaction, to provide a gasoline component, a diesel component and/or a BTX feedstock component; and (32) introducing the first heavy component to a delayed coking unit for reaction; or using the first heavy component as a low sulfur ship fuel oil component.