Exemplary apparatus or method implementations for a universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe permitting access to the feed screw and pipe interior for inspection, maintenance and/or cleaning during production, without disassembly or screw removal. The clamshell screw feeder pipe provides access to the screw by opening or removing the multi-section top portion of the clamshell pipe. The top pipe section is bolted and or hinges to the bottom portion of the clamshell pipe. The number of segmented multiple clamshell top sections depends on the length of the screw. One or more clamshell top sections may be configured with an inspection port. The universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe transfers feedstock feed from one or more feed vessels to one or more reactor vessel.

High concentrations of recycle polymer are gasified in a partial oxidation gasifier to make a syngas useful to make a variety of chemicals and polymers, such as cellulose ester. Polymers such as cellulose esters can be made that are obtained from sustainable sources, recycle sources, and are biodegradable. Circularity in the manufacture of textiles and/or plastics made from the fibers of such cellulose esters can now be achieved. The process of making such a syngas from high concentrations of recycle polymer (e.g. textiles and/or plastics) includes campaigning for the production of syngas.

Gasifiers, gasification systems, and methods for producing synthesis gas are disclosed. A gasifier can include a gasifier body. A feeder can be positioned to feed an organic material into the gasifier body. A pulse detonation burner can be located under or above the gasifier body and connected to the gasifier body to direct supersonic shockwaves upward into the gasifier body to heat the organic material and to form a jet spouted bed of the organic material or to operate as an entrained flow reactor. An outlet can be located at the gasifier body to allow removal of synthesis gas, residual ash, and other reaction products.

Torrefied textiles can be gasified to produce a syngas suitable for making chemicals. Gasifying torrefied textile can generate a consistent quality of syngas and a hydrogen/carbon monoxide ratio closer to that of coal relative to gasifying textiles. A variety of chemical compounds, reactants, polymers, fibers, and textiles can now be made utilizing syngas made by gasifying torrefied textiles.

An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

Densified textile aggregates are co-fed with a fuel into a partial oxidation gasifier. High solids concentrations in the feedstock composition can be obtained without significant impact on the feedstock composition stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The syngas quality, composition, and throughput are suitable for produce a wide range of chemicals.

A method of producing high conductivity carbon material from coal includes subjecting the coal to a dissolution process to produce a solubilized coal material, and subjecting the solubilized coal material to a pyrolysis process to produce the high conductivity carbon material.

A method of producing high conductivity carbon material from coal includes subjecting the coal to a dissolution process to produce a solubilized coal material, and subjecting the solubilized coal material to a pyrolysis process to produce the high conductivity carbon material.

Pre-ground plastics of small particle size not more than 2 mm are co-fed into a solid fossil fuel fed entrained flow partial oxidation gasifier. High solids concentrations in the feedstock stream can be obtained without significant impact on the feedstock stream stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The subsequent syngas produced from this material can be used to produce a wide range of chemicals.

The present disclosure provides methods and apparatuses of producing hydrogen. The methods comprise: (a) contacting a plastic with a catalyst and a gas feed; and (b) applying a microwave at a first temperature. The apparatuses comprise: a reactor for mixing plastic with a catalyst to form a mixture; an inlet for introducing a gas feed; a microwave generator; an optional temperature sensor; and an outlet configured to exhaust the product hydrogen formed in the reactor.