C10J2300/16

PROCESS OF ALKALINE CATALYTIC CRACKING OF INFERIOR HEAVY OIL WITH DOUBLE REACTION TUBES IN MILLISECONDS AND GASEOUS COUPLING

The invention provides a process of alkaline catalytic cracking of inferior heavy oil with double reaction tubes in milliseconds and gaseous coupling, the process comprising: a high-efficiency atomizing nozzle sprays the preheated heavy oil into an upper portion of a downflow reaction tube, the produced oil mist mixes with a high temperature regenerated alkaline catalyst flowing downward from a dual-regulation return feeder, so as to heat, vaporize and crack the oil mist, the obtained stream containing a cracked oil and gas and an alkali catalyst to be generated flows rapidly and downward to the bottom of the downflow reaction tube to carry out a gas-solid separation; then the cracked oil and gas obtained from the gas-solid separation enters a fractionation column to be separated, the oil slurry obtained by separating the cracked oil and gas returns to mix with the heavy oil for recyclable use, while the other products separated from the cracked oil and gas are output as intermediate products; the alkali catalyst to be generated obtained from the gas-solid separation is subject to steam stripping and enters into a lower portion of a riser gasification reactor and carries out a catalytic gasification reaction with an oxidant and water vapor at a reaction temperature of 750 C. to 1,000 C., the subsequently generated material stream containing synthesis gas and regenerated alkaline catalyst flows rapidly and upward to a top of the riser gasification reactor to carry out a gas-solid separation; the high-temperature regenerated alkaline catalyst obtained from the gas-solid separation flows into the dual-regulation return feeder, wherein a portion of the high-temperature regenerated alkaline catalyst flows into the downflow reaction tube to continue to crack the heavy oil, the remaining portion of the high-temperature regenerated alkaline catalyst returns to the riser gasification reactor so as to continue the regeneration gasification; the synthesis gas obtained from the gas-solid separation is subject to a heat exchange and then output as a product.

Use of methanol in the production of hydrogen and fuel, processes and plants for the production of hydrogen and fuel

The invention relates to the use of biomethanol from the pulp industry in the production of biohydrogen. The preferred biomethanol comprises purified biomethanol derived from black liquor. The invention also relates to a process for the production of biohydrogen from crude biomethanol recovered from black liquor and to a process for producing hydrocarbon biofuel using such biohydrogen as a hydrogen source. The invention further relates to a biofuel production facility for producing fuel from biohydrogen and biohydrocarbon, and to biofuel so produced. The invention makes it possible to produce a biofuel, wherein 100% of the raw material stems from non-fossil sources.

Method of electrolytically assisted carbochlorination
10326155 · 2019-06-18 ·

Method of combining industrial processes having inherent carbon capture and conversion capabilities offering maximum flexibility, efficiency, and economics while enabling environmentally and sustainably sound practices. Maximum chemical energy is retained throughout feedstock processing. A hybrid thermochemical cycle couples staged reforming with hydrogen production and chlorination. Hydrogen generated is used to upgrade feedstocks including bitumen, shale, coal, and biomass. Residues of upgrading are chlorinated, metals of interest are removed, and the remainder is reacted with ammonia solution and carbon dioxide to form carbonate minerals. The combination provides emissions free production of synthetic crude oil and derivatives, as well as various metals and fertilizers. Sand and carbonate minerals are potentially the only waste streams. Through this novel processing, major carbon dioxide reduction is afforded by minimizing direct oxidation. Supplemental heat to run the reactions is obtained through external means such as concentrated solar, geothermal, or nuclear.

COMBINED GASIFICATION AND VITRIFICATION SYSTEM
20180273415 · 2018-09-27 · ·

An optimized gasification/vitrification processing system having a gasification unit which converts organic materials to a hydrogen rich gas and ash in communication with a joule heated vitrification unit which converts the ash formed in the gasification unit into glass, and a plasma which converts elemental carbon and products of incomplete combustion formed in the gasification unit into a hydrogen rich gas.

Apparatus to convert organic waste into syngas while manufacturing glass products and method thereof
20180237322 · 2018-08-23 · ·

This invention relates to using a production glass furnace to melt waste glass and other glass constituents thereby providing a radiant heat source within the furnace to efficiently gasify organic waste materials recovered from a variety of waste streams to thereby produce a synthesis gas (Syngas) that is comprised mostly of carbon monoxide, hydrogen, and carbon dioxide that can be further refined and sold as a high value fuel. The gasification of the organic waste within the production glass furnace has minimal impact on the composition of the glass melt thus allowing for the production of the same range of glass products as if no organic waste was added to the furnace.

Combined gasification and vitrification system
09994474 · 2018-06-12 · ·

An optimized gasification/vitrification processing system having a gasification unit which converts organic materials to a hydrogen rich gas and ash in communication with a joule heated vitrification unit which converts the ash formed in the gasification unit into glass, and a plasma which converts elemental carbon and products of incomplete combustion formed in the gasification unit into a hydrogen rich gas.

Gasification system
09914890 · 2018-03-13 · ·

A gasification system method and apparatus to convert a feed stream containing at least some organic material into synthesis gas having a first region, a second region, a gas solid separator, and a means for controlling the flow of material from the first region to the second region. The feed stream is introduced into the system, and the feed stream is partially oxidized in the first region thereby creating a solid material and a gas material. The method further includes the steps of separating at least a portion of the solid material from the gas material with the gas solid separator, controlling the flow of the solid material into the second region from the first region, and heating the solid material in the second region with an electrical means.

System and method for using board plant flue gases in the production of syngas
09862903 · 2018-01-09 · ·

Disclosed is an apparatus and method for capturing the hot humid gases from a gypsum board dryer and utilizing those gases in the production of a synthetic gas (referred to as syngas). The syngas produced can then be utilized within a gypsum board plant to reduce the amount of natural gas needed. The method utilizes the heated water vapor (H.sub.2O) and carbon dioxide (CO.sub.2) found within the flue gas of a board dryer. The H.sub.2O and CO.sub.2 are used in a gasification process to yield the syngas.

Chlorination of processing residues as a variable load for grid scale electrical load following and storage
09786940 · 2017-10-10 ·

Disclosed are systems and methods having inherent carbon capture and conversion capabilities offering maximum flexibility, efficiency, and economics while simultaneously enabling environmentally and sustainably sound practices. A hybrid thermochemical cycle couples staged reforming with hydrogen production and residue chlorination. The residues of the upgrading are chlorinated, metals of interest are removed and bulk material is re-mineralized. Through the residue chlorination process, various metals including rare earths are concentrated and extracted. Energy is retained through chemical synthesis such as hydrocarbon and metal and non-metal chloride production. Produced chemicals are later exploited by redox reactions in the operation of an integrated gasification flow battery.

Methods for processing a hydrocarbon oil feed stream utilizing a gasification unit, steam enhanced catalytic cracker, and an aromatics complex

In accordance with one or more embodiments herein, an integrated process for upgrading a hydrocarbon oil feed stream utilizing a gasification unit, steam enhanced catalytic cracker, and an aromatics complex includes solvent deasphalting the hydrocarbon oil stream; processing the heavy residual hydrocarbons in a gasification unit to form syngas and gasification residue; hydrotreating the deasphalted oil stream to form a light C.sub.5+ hydrocarbon stream and a heavy C.sub.5+ hydrocarbon stream; steam enhanced catalytically cracking the light C.sub.5+ hydrocarbon stream; steam enhanced catalytically cracking the heavy C.sub.5+ hydrocarbon stream; passing at least a portion of the light steam enhanced catalytically cracked stream, the heavy steam enhanced catalytically cracked stream, or both to a product separator to produce a olefin product stream, a naphtha product stream, and a BTX product stream; and processing the naphtha product stream in the aromatics complex to produce benzene and xylenes.