A pyrolysis gas reforming system is provided. The pyrolysis gas reforming system includes a pyrolysis unit configured to perform pyrolysis of waste, an oil-gas separation unit configured to separate a product generated by the pyrolysis unit into oil and gas, a pyrolysis gas purification unit configured to refine pyrolysis gas generated through the separation by the oil-gas separation unit, a pyrolysis gas reforming unit configured to generate synthesis gas by reforming the pyrolysis gas purified by the pyrolysis gas purification unit, a hydrogen gas shift reaction unit configured to convert carbon monoxide contained in the synthesis gas generated by the pyrolysis gas reforming unit into hydrogen and carbon dioxide, and a hydrogen separation unit configured to separate hydrogen from the synthesis gas discharged from the hydrogen gas shift reaction unit, wherein combustion gas generated by a burner of the pyrolysis gas reforming unit and used to supply heat to the pyrolysis gas reforming unit is used to supply heat to the pyrolysis unit.

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

A process for the stepwise separation of accompanying gases from a raw synthesis gas stream by a liquid absorbent countercurrently guided through all process steps and circulated via regeneration plants, wherein either the accompanying gases H.sub.2S, COS and CO.sub.2 are separated in a common absorption step or, in one of the selective absorption steps chiefly H.sub.2S and COS are separated and in the next step in flow direction of the gas chiefly CO.sub.2 is separated, and in the last step a separation of accompanying gas residues (fine wash) is effected, wherein before the separation of H.sub.2S and COS an absorption step chiefly for the separation of aromatics and subsequently an absorption step chiefly for the separation of methyl mercaptan is carried out.

The present invention is intended to provide a gas purification apparatus and a gas purification method with an excellent thermal efficiency and capable of degrading COS at a high degradation rate. A gas purification apparatus configured to purify gas at least including COS, H.sub.2O, CO.sub.2, and H.sub.2S includes a COS treatment device which is provided with a COS conversion catalyst and configured to treat and degrade COS in the gas by hydrolysis, and H.sub.2O adjustment means configured to adjust the concentration of H.sub.2O in the gas to be introduced into the COS treatment device.

An equilibrium approach reactor with the ability to receive a highly variable gas and normalise it to a useful quality, and further to utilise the energy from the gas itself to robustly elevate the operating temperature, to ensure good mixing and high conversion while having the ability to handle solids in multiple states.

A system for gasifying biomass is disclosed. The system comprises a water storage tank, a water pump, a heat exchanger, a plasma torch heater, a gasifier, an ash cooler, a spray tower, a dust collector, a deacidification tower, and a desiccator. The water storage tank is connected to the water inlet of the heat exchanger; the vapor outlet of the heat exchanger is connected to the vapor inlet of the plasma torch heater; the vapor outlet of the plasma torch heater is connected to the vapor nozzle of the gasifier; the ash outlet of the gasifier is connected to the ash inlet of the ash cooler; the gas outlet of the gasifier is connected to the gas inlet of the spray tower; and the gas outlet of the spray tower is connected to the gas inlet of the heat exchanger.

A catalyst is illustrated, which has 70-90 parts by weight of mica, 1-10 parts by weight of zeolite, 5-15 parts by weight of titanium dioxide, 1-10 parts by weight of aluminum oxide, 1-5 parts by weight of sodium oxide and 1-5 parts by weight of potassium oxide. The present disclosure also illustrates a pyrolysis device using the catalyst, and further illustrates a pyrolysis method using the catalyst and/or the pyrolysis device for thermally cracking an organic polymer.

There is provided an absorbent for decreasing the leakage of halogen compound gases in subsequent processes, at high temperatures and in the presence of high concentrations of water vapor in the process of heating and gasifying a fuel, such as coal, to produce a synthesis gas.

The adsorbent includes a halogen compound absorbent containing 30 to 90% by mass of a basic calcium compound and 10 to 70% by mass of a metal compound other than basic calcium compounds and/or of a clay mineral. A method for producing synthesis gas using the absorbent is also disclosed.

A process for producing products from biomass comprises pyrolysing biomass at a selected temperature and producing a bio-syngas, processing bio-syngas from pyrolysis step (a) to remove condensable constituents from the bio-syngas, and processing the non-condensable bio-syngas from bio-syngas processing step (b) and producing one or more than one product, such as bio-fuels, bio-chemicals, bio-solvents and bio-plastics.

Carbonaceous-containing material including biomass, municipal solid waste, and/or coal and/or contaminated soil, and/or other carbonaceous materials may be gasified at low temperatures utilizing a reactor designed to generate shockwaves in a supersonic gaseous vortex. Preprocessed waste may be introduced into the reactor. A gas stream may be introduced substantially tangentially to an inner surface of a chamber of the reactor to generate a gaseous vortex rotating about a longitudinal axis within the chamber. The gas stream may be introduced using a nozzle that accelerates the gas stream to a supersonic velocity, and may impinge on an impactor positioned within the reactor chamber. A frequency of shockwaves emitted from the nozzle into the gaseous vortex may be controlled. The processed waste discharged from the reactor, which may include a gas component and at least a solid component, can be subjected to separation, and at least some of the gas component and at least one solid component (i.e., tars) may be fed back to the feeding device so that the solids from the processed waste condense on preprocessed waste contained in the feeding device and are reprocessed within the reactor. The gas component from the feeding device may be cleaned after the solids have been condensed out in the feeding device.