The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

Clean, safe and efficient methods, systems, and processes for utilizing thermolysis methods to processes to convert various carpet, rug, polymeric materials and other waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like into a Clean Fuel Gas and Char source are disclosed. The invention processes the carpet, rug, polymeric material to effectively shred and/or grind the waste source, such as post-consumer carpet remnants and waste, and then process using thermolysis methods to destroy and/or separate halogen and other dangerous components to provide a Clean Fuel Gas and Char source. Additional waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like, are suitable for the processing of the invention disclosed.

The present description is related to the field of hydrocarbon production by gasification of carbonaceous material. It provides a two-stage gas washing method as a part of gas refining. More specifically it discloses a method for hydrogen sulfide and carbon dioxide removal from synthesis gas produced by gasification. It introduces a use of a novel combination of wash approaches for this application. As a specific application, this process is utilized as a part of biomass to liquid (BTL) process.

Clean, safe and efficient methods, systems, and processes for utilizing thermolysis methods to processes to convert various carpet, rug, polymeric materials and other waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like into a Clean Fuel Gas and Char source are disclosed. The invention processes the carpet, rug, polymeric material to effectively shred and/or grind the waste source, such as post-consumer carpet remnants and waste, and then process using thermolysis methods to destroy and/or separate halogen and other dangerous components to provide a Clean Fuel Gas and Char source. Additional waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like, are suitable for the processing of the invention disclosed.

Sour syngas treatment apparatuses and processes for treating a sour syngas stream are provided herein. In an embodiment, a process for treating a sour syngas stream that includes sulfur components and carbon dioxide includes absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream. The liquid absorbent stream includes the solvent, the sulfur components, and carbon dioxide. A portion of the sulfur components from the liquid absorbent stream is directly oxidized in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream. The recycle stream includes an unconverted portion of the sulfur components and carbon dioxide. The recycle stream is recycled for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.

Sour syngas treatment apparatuses and processes for treating a sour syngas stream are provided herein. In an embodiment, a process for treating a sour syngas stream that includes sulfur components and carbon dioxide includes absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream. The liquid absorbent stream includes the solvent, the sulfur components, and carbon dioxide. A portion of the sulfur components from the liquid absorbent stream is directly oxidized in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream. The recycle stream includes an unconverted portion of the sulfur components and carbon dioxide. The recycle stream is recycled for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.

The present disclosure relates to a processes and systems for producing fuels from biomass with high carbon conversion efficiency. The processes and systems described herein provide a highly efficient process for producing hydrocarbons from biomass with very low Green House Gas (GHG) emissions using a specific combination of components, process flows, and recycle streams. The processes and systems described herein provide a carbon conversion efficiency greater than 95% with little to no GHG in the flue gas due to the novel arrangement of components and utilizes renewable energy to provide energy to some components. The system reuses water and carbon dioxide produced in the process flows and recycles naphtha and tail gas streams to other units in the system for additional conversion to syngas to produce hydrocarbon-based fuels.

The invention relates to a method for the chemical conversion of mixtures of materials produced from solid and liquid hydrocarbons into gas/vapor mixtures and carbonaceous materials by thermal actions, catalysis and other processes and a device comprising jacket-heated, vertically and horizontally oriented reactors known per se with conveying devices and further apparatus in a process cycle.

The invention relates to a method for the chemical conversion of mixtures of materials produced from solid and liquid hydrocarbons into gas/vapor mixtures and carbonaceous materials by thermal actions, catalysis and other processes and a device comprising jacket-heated, vertically and horizontally oriented reactors known per se with conveying devices and further apparatus in a process cycle.