The disclosure provides for the separation and combustion of at least one hydrocarbon, oxygenate, sulfur compound, and or nitrogen compound, from industrial gas or gasification derived syngas to generate steam. A gasification process and a gas fermentation process may be integrated using tail gas from the fermentation process for the flame to combust tar and other compounds from the syngas generated by a gasification process. Integration may be achieved by removing tar and other compounds from industrial gas or gasification derived syngas using an adsorbent and regenerating the adsorbent using tail gas from the gas fermentation process. Tail gas enriched with the desorbed tar and other compounds may be used to generate steam in a steam boiler and the steam may be used for a variety of purposes including power generation to power, for example, a compressor of the gas fermentation process.

The disclosure provides for the separation and combustion of at least one hydrocarbon, oxygenate, sulfur compound, and or nitrogen compound, from industrial gas or gasification derived syngas to generate steam. A gasification process and a gas fermentation process may be integrated using tail gas from the fermentation process for the flame to combust tar and other compounds from the syngas generated by a gasification process. Integration may be achieved by removing tar and other compounds from industrial gas or gasification derived syngas using an adsorbent and regenerating the adsorbent using tail gas from the gas fermentation process. Tail gas enriched with the desorbed tar and other compounds may be used to generate steam in a steam boiler and the steam may be used for a variety of purposes including power generation to power, for example, a compressor of the gas fermentation process.

Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

Systems and methods are provided for co-processing of plastic waste with biomass to generate gas phase product streams with improved properties. The systems and methods can include having a high temperature swing adsorption process integrated with a pyrolysis process, gasification process, or other thermal conversion process, so that CO.sub.2 can be removed from at least a portion of the effluent. This can facilitate capture of CO.sub.2 when using pyrolysis, gasification, or other thermal conversion to generate a hydrogen-containing stream. Additionally, the integrated system and/or method can allow for production of multiple product streams having desirable ratios of hydrogen to carbon oxides.

An automatic control system (ACS) for capturing and utilizing carbon dioxide (CO.sub.2) of one or more gases from one or more plants may receive, from one or more sensors, one or more parameters of at least one gas of one or more gases through a system gas flow inlet channel, a first volumetric flow rate of the one or more gases through a plug flow reactor (PFR), a second volumetric flow rate of the one or more gases through a bypass channel that bypasses the PFR, the CO.sub.2 flowing into the CO.sub.2 capture unit, or the syngas flowing into the CO.sub.2 capture unit. The ACS may also command one or more flow controllers to modulate at least one of the first volumetric flow rate of the one or more gases through PFR or the second volumetric flow rate of the one or more gases through the bypass channel based on the one or more parameters.

The disclosure relates to a rotary kiln catalytically enhanced oxy-fuel gasification and oxy-fuel combustion system—power plant including an air separation unit arranged to separate oxygen from air and produce a stream of substantially pure liquid oxygen; rotary kiln gasifiers to convert municipal solid waste, biomass, alternate wastes, coal, or hydrocarbon fuels into a synthesis gas in the presence of oxygen, carbon dioxide, high temperature steam and lime catalysts; an oxy-fuel fired boiler arranged to combust synthesis gas, in the presence of substantially pure oxygen gas, to produce an exhaust gas comprised of water and carbon dioxide; and a carbon dioxide removal unit arranged to recover carbon dioxide gas from the exhaust gas, recycle a portion of the recovered carbon dioxide gas for use in the rotary kiln gasifier, and liquefy the remainder of the recovered carbon dioxide gas for removal from the plant. In this new plant, the carbon dioxide removal unit is thermally integrated with the air separation unit or alternately the liquid oxygen storage and supply system by directing a stream of liquid oxygen to the carbon dioxide removal unit to liquefy the recovered carbon dioxide gas, the liquid oxygen thereby evaporating and forming cold oxygen gas which is heated prior to consumption in the rotary kiln and oxy-fuel fired boiler.

An automatic control system (ACS) for capturing and utilizing carbon dioxide (CO.sub.2) of one or more gases from one or more plants may receive, from one or more sensors, one or more parameters of at least one gas of one or more gases through a system gas flow inlet channel, a first volumetric flow rate of the one or more gases through a plug flow reactor (PFR), a second volumetric flow rate of the one or more gases through a bypass channel that bypasses the PFR, the CO.sub.2 flowing into the CO.sub.2 capture unit, or the syngas flowing into the CO.sub.2 capture unit. The ACS may also command one or more flow controllers to modulate at least one of the first volumetric flow rate of the one or more gases through PFR or the second volumetric flow rate of the one or more gases through the bypass channel based on the one or more parameters.

Methods and apparatuses for producing fuel and power from the reformation of organic waste include the use of steam to produce syngas in a Fischer-Tropsch reaction, followed by conversion of that syngas product to hydrogen. Some embodiments include the use of a heated auger both to heat the organic waste and further to cool the syngas.

Methods and apparatuses for producing fuel and power from the reformation of organic waste include the use of steam to produce syngas in a Fischer-Tropsch reaction, followed by conversion of that syngas product to hydrogen. Some embodiments include the use of a heated auger both to heat the organic waste and further to cool the syngas.

Proposed are a process and a plant for producing a synthesis gas product stream having an adjustable H.sub.2/CO ratio and a pure hydrogen stream, wherein it is provided according to the invention that a substream of a deacidified synthesis gas stream is supplied to a membrane separation plant fitted with a hydrogen-selective membrane and the remaining substream is supplied to a pressure swing adsorption plant, wherein the latter affords a pure hydrogen stream and a fuel gas stream. The hydrogen-enriched permeate stream obtained from the membrane separation is likewise supplied to the pressure swing adsorption plant, thus enhancing the yield of pure hydrogen. The hydrogen-depleted retentate stream obtained from the membrane separation is discharged as a synthesis gas product stream and if of a suitable composition may be utilized as oxo gas.