Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or syngas) produced in a heat-generating unit such as a partial oxidation (POX) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

The present disclosure relates to a process and a system for producing synthesis gas. The carbonaceous feedstock is gasified, in the presence of at least one of oxygen and steam, in a first reactor to obtain a gaseous mixture comprising H2, CO, CH4, CO2, H2O, tar and char. The gaseous mixture is treated in a second, reactor, in the presence of a catalyst, to obtain synthesis gas. The system comprises a first reactor, a connecting conduit, a second reactor, at least one cyclone separator, at least one heat exchanger and at least one synthesis gas filter unit. The process and the system of the present disclosure are capable of producing synthesis gas with comparatively higher conversion of the unreacted char.

Catalysts useful in transforming biomass to bio-oil are disclosed, as are methods for making such catalysts, and methods of transforming biomass to bio-oil. The catalysts are especially useful for, but are not limited to, microwave- and induction-heating based pyrolysis of biomass, solid waste, and other carbon containing materials into bio-oil. The catalysts can also be used for upgrading the bio-oil to enhance fuel quality.

Catalysts useful in transforming biomass to bio-oil are disclosed, as are methods for making such catalysts, and methods of transforming biomass to bio-oil. The catalysts are especially useful for, but are not limited to, microwave- and induction-heating based pyrolysis of biomass, solid waste, and other carbon containing materials into bio-oil. The catalysts can also be used for upgrading the bio-oil to enhance fuel quality.

This invention relates to a process for the conversion of a feedstock comprising a lignin-comprising material, comprising the steps (a) to (c): (a) charging the feedstock to a fluidized bed reactor; (b) pyrolyzing at least part of the feedstock in the fluidized bed reactor while introducing a carrier gas into the reactor, to produce pyrolysis vapors; (c) reacting at least part of the pyrolysis vapors coming from step (b) in a second reactor comprising a catalyst, to produce hydrocarbon products comprising aromatics.

This invention relates to a process for the conversion of a feedstock comprising a lignin-comprising material, comprising the steps (a) to (c): (a) charging the feedstock to a fluidized bed reactor; (b) pyrolyzing at least part of the feedstock in the fluidized bed reactor while introducing a carrier gas into the reactor, to produce pyrolysis vapors; (c) reacting at least part of the pyrolysis vapors coming from step (b) in a second reactor comprising a catalyst, to produce hydrocarbon products comprising aromatics.

The disclosure pertains to a plasmonic catalytic process for the reverse water gas shift reaction and corresponding catalysts. In an embodiment, TiO.sub.2-supported Au nanoparticles are used as catalyst.

A catalyst for performing the reverse-water-gas-shift (RWGS) reaction is provided comprising an alkali carbonate dispersed on a porous support.

The technology relates to a method of producing synthesis gas comprising carbon monoxide (CO) and hydrogen (H.sub.2), wherein the synthesis gas is produced by a reduction reaction of a first flow comprising a carbon source and an excess of hydrogen in contact with an Oxy-flame. The hydrogen comes from a reducing stream, a first portion of which ends up in the first flow, and a second part of which is used to generate the Oxy-flame by combustion of the hydrogen in the presence of a second flow comprising oxygen (O.sub.2), the second flow coming from an oxidizing stream. The first flow and the second flow are at a distance from each other such that the Oxy-flame supports the reaction between the carbon source and the hydrogen. A reactor, which can have different configurations, is also proposed for implementing the method.

A system for processing carbonaceous in-feed material has a pyrolyzer kiln for pyrolysis the carbonaceous in-feed material, the kiln operating in a slow pyrolysis process in which the in-feed material is pyrolyzed in the kiln for a period of minutes in order to produce primarily a gaseous output fraction; a steam reformer positioned downstream of the kiln to which combustion gasses from the pyrolyzer kiln are fed; a water scrubber positioned gas flow-wise downstream of the steam reformer; a methanation stage; a CO2 scrubbing stage. The system includes means for splitting the gas and directing a portion of the split gas back to the pyrolyzer kiln.