A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.

The present invention relates to a process for converting carbon dioxide and hydrogen by performing a reverse water gas shift reaction at elevated temperature, the process comprising introducing carbon dioxide, hydrogen and oxygen into a reaction vessel having an inlet and an outlet, and, wherein the reverse water gas shift reaction takes place in two different zones of the reaction vessel, being a top zone (z1) adjacent to a bottom zone (z2). The process produces a product stream comprising mainly carbon monoxide, hydrogen and water. The process is useful in reducing the carbon footprint of certain industrial technologies, and in addition, the process is useful in the production of synthesis gas.

A method for the generation of a gas mixture including carbon monoxide, carbon dioxide and optionally hydrogen for use in hydroformylation plants or in carbonylation plants, including mixing an optional steam with carbon dioxide in the desired molar ratio, feeding the resulting gas to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while effecting a partial conversion of carbon dioxide to carbon monoxide and optionally of steam to hydrogen, removing some or all the remaining steam from the raw product gas stream by cooling the raw product gas stream and separating the remaining product gas from a liquid, and using the gas mixture containing CO and CO.sub.2 for liquid phase synthesis reactions utilizing carbon monoxide as one of the reactants while recycling CO.sub.2 to the SOEC or SOEC stack.

A reverse water gas shift catalyst (RWGS catalyst) for conducting reverse water gas shift reactions to convert carbon dioxide to carbon monoxide includes reduced iron oxide and an alkali metal promoter supported on a solid catalyst support. The solid catalyst support includes a plurality of catalyst support particles, and the reduced iron oxide may have iron having an oxidation state of less than 3. Methods of making the RWGS catalyst and processes for converting carbon dioxide to carbon monoxide using the RWGS catalyst are also disclosed.

A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.

Methods and systems of the present disclosure can function to capture flue gas and convert the flue gas to a synthesis gas, which can be further processed to other components such as liquid fuels. Aspects of the present disclosure provide for a process designed to capture flue gas from large scale (i.e. GW), fossil based power plants in a 24/7 continuous operation. In addition, the method and system can convert the flue gas to a synthesis gas (mainly carbon monoxide and hydrogen), which will be processed into high quality liquid fuels, like diesel.

Methods and systems of the present disclosure can function to capture flue gas and convert the flue gas to a synthesis gas, which can be further processed to other components such as liquid fuels. Aspects of the present disclosure provide for a process designed to capture flue gas from large scale (i.e. GW), fossil based power plants in a 24/7 continuous operation. In addition, the method and system can convert the flue gas to a synthesis gas (mainly carbon monoxide and hydrogen), which will be processed into high quality liquid fuels, like diesel.

A method of preparing synthetic oil, the method including producing synthetic gas by introducing the feed into a synthetic gas production reaction in the presence of a catalyst, producing synthetic oil and an FT tail gas by introducing the synthetic gas into a Fischer-Tropsch (FT) reaction, regenerating the catalyst used in the producing of the synthetic gas in a catalyst regenerator, and supplying the FT tail gas to a catalyst regenerator.

A gas production apparatus includes: a separator configured to separate and capture a separated gas including carbon dioxide as a main component from an exhaust gas of exhaust gas equipment; reactors which are downstream of the separator, each of the reactors: (i) containing a reductant configured to contact the separated gas to produce carbon monoxide through a reduction reaction of carbon dioxide; (ii) being configured to separate at least some oxygen atoms split off from carbon dioxide in the reduction reaction; and (iii) having a reducing agent containing a metal oxide configured to reduce carbon dioxide as the reductant; a reducer configured to supply a reducing gas containing a reducing substance configured to reduce the reducing agent oxidized by contact with carbon dioxide; a pressure regulator configured to regulate a pressure of the separated gas; and a flow regulator configured to regulate a flow rate of the separated gas.

An unsupported bulk alkali-promoted molybdenum carbide (A-Mo.sub.2C) catalyst for use in the reverse water-gas shift (RWGS) reaction, and a method of making the same, is presented. In embodiments, a method for forming an unsupported bulk molybdenum carbide (Mo.sub.2C) catalyst promoted with an alkali earth metal includes: generating phase pure molybdenum trioxide (MoO.sub.3) by calcining a molybdate precursor salt; producing non-passivated Mo.sub.2C from carburization of the phase pure MoO.sub.3; passivating the non-passivated Mo.sub.2C to form passivated Mo.sub.2C; and producing an active unsupported alkali metal (A) promoted Mo.sub.2C (A-Mo.sub.2C) catalyst from the passivated Mo.sub.2C and an alkali metal carbonate (A-CO.sub.3).