An adsorption storage tank for a natural gas includes a pressurizable tank disposed on a vehicle to contain the natural gas. A natural gas adsorbent is disposed in the tank. The natural gas is a mixture of constituents having a constituent statistical distribution of molecule lengths and kinetic diameters. The adsorbent has a pore size statistical distribution of pore sizes to adsorb and desorb the mixture of constituents.

An adsorption storage tank for a natural gas includes a pressurizable tank disposed on a vehicle to contain the natural gas. A natural gas adsorbent is disposed in the tank. The natural gas is a mixture of constituents having a constituent statistical distribution of molecule lengths and kinetic diameters. The adsorbent has a pore size statistical distribution of pore sizes to adsorb and desorb the mixture of constituents.

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 m to 20 m.

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 m to 20 m.

Non-condensable gas is used as an alternate to steam at hydrocarbon processing facilities removing any steam requirements thereby reducing greenhouse gas emissions, and improving profitability through capital and operating cost reductions. The non-condensable gas serves at least two functions sequentially in heavy hydrocarbon processing; firstly, providing the non-condensable gas as a stripping medium to evolve lighter hydrocarbons from the heavy hydrocarbon feedstock followed by secondly directing the same non-condensable gas and any evolved non-condensable gas at operating conditions for use as at least one of heat through combustion or power through electricity generation.

Disclosed are methods, systems, and computer-readable mediums for determining the composition of gaseous fuel. An initial gaseous fuel stream is provided that includes methane, non-methane hydrocarbons, and inert gases. Air is mixed into the initial fuel stream upstream of a first catalyst. The first catalyst oxidizes only the non-methane hydrocarbons of the initial fuel stream to produce a resultant fuel stream comprising methane and inert gases. Air is mixed into the resultant fuel stream downstream of the first catalyst and upstream of a second catalyst. The second catalyst oxidizes only the methane hydrocarbons of the resultant fuel stream to produce an output fuel stream. Mole ratios of the methane, the non-methane hydrocarbons, and the inert gases of the initial fuel stream are each determined.

Disclosed are methods, systems, and computer-readable mediums for determining the composition of gaseous fuel. An initial gaseous fuel stream is provided that includes methane, non-methane hydrocarbons, and inert gases. Air is mixed into the initial fuel stream upstream of a first catalyst. The first catalyst oxidizes only the non-methane hydrocarbons of the initial fuel stream to produce a resultant fuel stream comprising methane and inert gases. Air is mixed into the resultant fuel stream downstream of the first catalyst and upstream of a second catalyst. The second catalyst oxidizes only the methane hydrocarbons of the resultant fuel stream to produce an output fuel stream. Mole ratios of the methane, the non-methane hydrocarbons, and the inert gases of the initial fuel stream are each determined.

Systems and methods to provide low carbon intensity (CI) ethanol through one or more targeted reductions of carbon emissions based upon an analysis of carbon emissions associated with a combination of various options for feedstock procurement, feedstock refining, processing, or transformation, and ethanol distribution pathways to end users. Such options are selected to maintain the total CI (carbon emissions per unit energy) of the ethanol below a pre-selected threshold that defines an upper limit of CI for the ethanol.

Systems and methods to provide low carbon intensity (CI) ethanol through one or more targeted reductions of carbon emissions based upon an analysis of carbon emissions associated with a combination of various options for feedstock procurement, feedstock refining, processing, or transformation, and ethanol distribution pathways to end users. Such options are selected to maintain the total CI (carbon emissions per unit energy) of the ethanol below a pre-selected threshold that defines an upper limit of CI for the ethanol.

A method of storing gas comprises providing a recipient for receiving the gas and providing a porous gas storage material. The gas storage material comprises a cross-linked polymeric framework and a plurality of pores for gas sorption. The cross-linked polymeric framework comprises aromatic ring-containing monomeric units comprising at least two aromatic rings. The aromatic ring-containing monomeric units are linked by covalent cross-linking between aromatic rings to form a stable, rigid nanoporous material for storing the gas at pressures significantly greater than the atmospheric pressure, for example in excess of 100 bar. A possible application is the storage and transportation of compressed natural gas.