A method of storing gas comprises providing a recipient for receiving the gas and providing a porous gas storage material. The gas storage material comprises a cross-linked polymeric framework and a plurality of pores for gas sorption. The cross-linked polymeric framework comprises aromatic ring-containing monomeric units comprising at least two aromatic rings. The aromatic ring-containing monomeric units are linked by covalent cross-linking between aromatic rings to form a stable, rigid nanoporous material for storing the gas at pressures significantly greater than the atmospheric pressure, for example in excess of 100 bar. A possible application is the storage and transportation of compressed natural gas.

A mixed phase pressurized unstabilized hydrocarbon stream is fed into a stabilizer column at a feed pressure. A liquid phase of stabilized hydrocarbon condensate is discharged from a bottom end of the stabilizer column, while a vapor phase of volatile components from the pressurized unstabilized hydrocarbon condensate stream is discharged from a top end of the stabilizer column. The vapor phase being discharged from the top end of the stabilizer column is compressed and subsequently passed through an ambient heat exchanger wherein partial condensation takes place. The resulting partially condensed overhead stream is separated in an overhead separator into a vapor effluent stream and an overhead liquid stream. After discharging the overhead liquid stream from the overhead separator, it is selectively divided into a liquid reflux stream and a liquid effluent stream. The liquid reflux stream is expanded to the feed pressure and fed into the stabilizer column.

A mixed phase pressurized unstabilized hydrocarbon stream is fed into a stabilizer column at a feed pressure. A liquid phase of stabilized hydrocarbon condensate is discharged from a bottom end of the stabilizer column, while a vapor phase of volatile components from the pressurized unstabilized hydrocarbon condensate stream is discharged from a top end of the stabilizer column. The vapor phase being discharged from the top end of the stabilizer column is compressed and subsequently passed through an ambient heat exchanger wherein partial condensation takes place. The resulting partially condensed overhead stream is separated in an overhead separator into a vapor effluent stream and an overhead liquid stream. After discharging the overhead liquid stream from the overhead separator, it is selectively divided into a liquid reflux stream and a liquid effluent stream. The liquid reflux stream is expanded to the feed pressure and fed into the stabilizer column.

A mixed phase unstabilized hydrocarbon stream is created by partially evaporating an unstabilized hydrocarbon condensate stream, including indirectly heat exchanging the unstabilized hydrocarbon condensate stream against an effluent stream in a feed-effluent heat exchanger. The mixed phase unstabilized hydrocarbon stream is fed into a stabilizer column. A liquid phase of stabilized hydrocarbon condensate is discharged from a bottom end, while an overhead vapor stream consisting of a vapor phase comprising volatile components from the unstabilized hydrocarbon condensate stream is discharged from a top end of the stabilizer column. The overhead vapor stream is passed through an overhead condenser. The resulting partially condensed overhead stream is separated in an overhead separator into a vapor effluent stream and an overhead liquid stream. The effluent stream against which the unstabilized hydrocarbon condensate stream is heat exchanged in the feed-effluent heat exchanger comprises the vapor effluent stream.

A mixed phase unstabilized hydrocarbon stream is created by partially evaporating an unstabilized hydrocarbon condensate stream, including indirectly heat exchanging the unstabilized hydrocarbon condensate stream against an effluent stream in a feed-effluent heat exchanger. The mixed phase unstabilized hydrocarbon stream is fed into a stabilizer column. A liquid phase of stabilized hydrocarbon condensate is discharged from a bottom end, while an overhead vapor stream consisting of a vapor phase comprising volatile components from the unstabilized hydrocarbon condensate stream is discharged from a top end of the stabilizer column. The overhead vapor stream is passed through an overhead condenser. The resulting partially condensed overhead stream is separated in an overhead separator into a vapor effluent stream and an overhead liquid stream. The effluent stream against which the unstabilized hydrocarbon condensate stream is heat exchanged in the feed-effluent heat exchanger comprises the vapor effluent stream.

Metal Organic Framework (MOF) materials and methods of making MOF materials. The methods include grinding of mixtures of metal hydroxide(s) and ligand(s). The MOF materials may have at least two different ligands. The MOF materials may have open metal sites. The MOF materials can be used in gas storage applications.

Metal Organic Framework (MOF) materials and methods of making MOF materials. The methods include grinding of mixtures of metal hydroxide(s) and ligand(s). The MOF materials may have at least two different ligands. The MOF materials may have open metal sites. The MOF materials can be used in gas storage applications.

The present invention relates generally to processes for hydromethanating a carbonaceous feedstock in a hydromethanation reactor to a methane-enriched raw product stream, and more specifically to processing of solid char by-product removed from the hydromethanation reactor to improve the carbon utilization and thermal efficiency of the overall process and thereby lower the net costs of the end-product pipeline quality substitute natural gas.

Embodiments provide a method of storing a compound using a metal organic framework (MOF). The method includes contacting one or more MOFs with a fluid and sorbing one or more compounds, such as O2 and CH4. O2 and CH4 can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF, wherein M can include aluminum, iron, gallium, indium, vanadium, chromium, titanium, or scandium.

Disclosed are methods and systems for removing a highly reactive polymer precursor such as carbonyls from a liquid hydrocarbon stream. Embodiments may disclose a method for removal of carbonyls from a liquid hydrocarbon stream comprising the steps of providing a liquid hydrocarbon stream containing carbonyls, providing a liquid bisulfite stream comprising an alkali metal bisulfite, and contacting the liquid hydrocarbon stream and the liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the alkali metal bisulfite to form a solid adduct that is soluble in the bisulfite solution.