Fuel composition for preventing or reducing low speed pre-ignition events in a spark-ignited internal combustion engine is provided. The fuel composition includes a hydrocarbon fuel boiling the gasoline or diesel range and a primary additive having a structure given by

##STR00001##

or a salt thereof. A is a ring moiety; R.sub.1 and R.sub.2 are independently H, C.sub.1-C.sub.20 hydrocarbyl group, carboxyl group, ether, or hydroxyl group. R 3 and R 4 are independently H, C.sub.1-C.sub.20 hydrocarbyl group, carboxyl group, ether, amino, or hydroxyl group or wherein R 3 and R 4 are part of a cyclic group. R.sub.5 is C.sub.1-C.sub.100 hydrocarbyl group, carboxyl group, ether, or hydroxyl group; and p is 0 to 2, n is 1 to 3, m is 1 to 3, and p+n+m is less than 5.

Fuel composition for preventing or reducing low speed pre-ignition events in a spark-ignited internal combustion engine is provided. The fuel composition includes a hydrocarbon fuel boiling the gasoline or diesel range and a primary additive having a structure given by

##STR00001##

or a salt thereof. A is a ring moiety; R.sub.1 and R.sub.2 are independently H, C.sub.1-C.sub.20 hydrocarbyl group, carboxyl group, ether, or hydroxyl group. R 3 and R 4 are independently H, C.sub.1-C.sub.20 hydrocarbyl group, carboxyl group, ether, amino, or hydroxyl group or wherein R 3 and R 4 are part of a cyclic group. R.sub.5 is C.sub.1-C.sub.100 hydrocarbyl group, carboxyl group, ether, or hydroxyl group; and p is 0 to 2, n is 1 to 3, m is 1 to 3, and p+n+m is less than 5.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

The present disclosure provides a method of producing a solid carbon material. The method comprises providing a carbon-containing material formed through the heat treatment of carbonaceous feedstock. The carbon-containing material is capable of undergoing polymerisation. The method further comprises mixing the carbon-containing material with a polymerisation agent to form a material mixture. In addition, the method comprises heating the material mixture to a temperature at which polymerisation of the material mixture occurs so as to produce the solid carbon material. The method also comprises adding a further material into the material mixture before polymerisation.

The present disclosure provides a method of producing a solid carbon material. The method comprises providing a carbon-containing material formed through the heat treatment of carbonaceous feedstock. The carbon-containing material is capable of undergoing polymerisation. The method further comprises mixing the carbon-containing material with a polymerisation agent to form a material mixture. In addition, the method comprises heating the material mixture to a temperature at which polymerisation of the material mixture occurs so as to produce the solid carbon material. The method also comprises adding a further material into the material mixture before polymerisation.

A method of purification of carbonizate resulting from the thermal recycling process of rubber waste consists in that the carbonizate is mixed with sodium bicarbonate, then deionized water having increased temperature and strong mineral acid and/or mixture of mineral acids are introduced into the obtained mixture, and next the whole is stirred at increased temperature, and filtered at decreased pressure while washing with deionized water having increased temperature, the filtrate is discarded, the solution of a strong base is introduced into the solid residue, and the whole is stirred at increased temperature, then the obtained suspension is filtered at decreased pressure, and washed with deionized water having increased temperature, and next the filtrate is discarded, and the solid residue is dried.

Some embodiments are directed to a method to avoid the negative effect of both sulphur and vanadium presence contained in solid fuel used in cement clinker manufacturing line (build-up, kiln rings, etc.). Some embodiments are methods to prepare, dose and use a fuel additive based on an alkaline earth metal to allow the combination of vanadium and sulphur with said added alkaline earth metal, so that corrosion, build-up, crusts and ring formation in cement pre-heaters and kilns due to the presence of those components are avoided.

A method for making a catalyst composition that includes a reduction catalyst mixture including a first reduction catalyst and a second reduction catalyst, wherein said first reduction catalyst comprises mixed vanadium oxides and phosphorus oxides, wherein said mixed vanadium and antimony oxides comprises V.sub.4Sb.sub.6O.sub.8, and wherein said second reduction catalyst comprises vanadium and antimony oxides; and an oxidation catalyst comprising ferrocene. The method includes selecting an organic petroleum distillate-soluble solvent that is effective to act as a reducing agent; introducing finely ground V.sub.2O.sub.5 and aqueous H.sub.3PO.sub.4 into said selected organic petroleum distillate-soluble solvent to make a first mixture; adding finely ground V/Sb oxide catalyst to said first mixture to make a second mixture; bringing the second mixture to a boil; cooling the second mixture; and adding the ferrocene or other organometallic Fe-source material to the cooled second mixture to make the catalyst composition.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.