The present disclosure recognizes a correlation between zeolitic surface area (ZSA) of a catalyst composition and its catalytic activity. Particularly, the disclosure provides catalyst articles for diesel NO.sub.x abatement, including a substrate and a washcoat layer containing metal-promoted molecular sieves, wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m.sup.2/g or greater, the volumetric surface area is about 900 m.sup.2/in.sup.3 or greater, and/or the total zeolitic surface area (tZSA) is about 1200 m.sup.2 or greater. The disclosure further relates to methods for evaluating ZSA, volumetric ZSA, and tZSA, e.g., including the steps of coating a catalyst composition comprising metal-promoted molecular sieves onto a substrate; calcining and aging the catalyst composition; determining the ZSA (or volumetric ZSA or tZSA) thereof; and correlating the ZSA (or volumetric ZSA or tZSA) with catalyst composition NO.sub.x abatement activity to determine whether the catalyst composition is suitable for an intended use.

The present disclosure recognizes a correlation between zeolitic surface area (ZSA) of a catalyst composition and its catalytic activity. Particularly, the disclosure provides catalyst articles for diesel NO.sub.x abatement, including a substrate and a washcoat layer containing metal-promoted molecular sieves, wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m.sup.2/g or greater, the volumetric surface area is about 900 m.sup.2/in.sup.3 or greater, and/or the total zeolitic surface area (tZSA) is about 1200 m.sup.2 or greater. The disclosure further relates to methods for evaluating ZSA, volumetric ZSA, and tZSA, e.g., including the steps of coating a catalyst composition comprising metal-promoted molecular sieves onto a substrate; calcining and aging the catalyst composition; determining the ZSA (or volumetric ZSA or tZSA) thereof; and correlating the ZSA (or volumetric ZSA or tZSA) with catalyst composition NO.sub.x abatement activity to determine whether the catalyst composition is suitable for an intended use.

The present invention relates to a combustion additive comprising a colloidal solution containing dispersed fine metal particles. The present invention also relates to a method for producing the colloid. More particularly the present teaching relates to a combustion additive having a colloid, wherein the colloid comprises metal particles providing in an alkaline aqueous solution, the metal particles being dispersed within that solution and having an average diameter in the range of 30 nm to 30 μm. The colloid can partly/fully substitute water of a water injection system or used as an air humidification component for combustion.

The present invention relates to a combustion additive comprising a colloidal solution containing dispersed fine metal particles. The present invention also relates to a method for producing the colloid. More particularly the present teaching relates to a combustion additive having a colloid, wherein the colloid comprises metal particles providing in an alkaline aqueous solution, the metal particles being dispersed within that solution and having an average diameter in the range of 30 nm to 30 μm. The colloid can partly/fully substitute water of a water injection system or used as an air humidification component for combustion.

A quaternary ammonium salt of formula (I): (I) where in X is a linking group; Y is O, NH or NR.sup.1 wherein R.sup.1 is H or an optionally substituted hydrocarbyl group; Q.sup.+ is a moiety that includes a quaternary ammonium cation; A.sup.− is an anion; R.sup.2 is an optionally substituted alkylene group; R.sup.3 is hydrogen or an optionally substituted hydrocarbyl group; and n is 0 or a positive integer; provided that n is not 0 when R.sup.3 is hydrogen. ##STR00001##

A quaternary ammonium salt of formula (I): (I) where in X is a linking group; Y is O, NH or NR.sup.1 wherein R.sup.1 is H or an optionally substituted hydrocarbyl group; Q.sup.+ is a moiety that includes a quaternary ammonium cation; A.sup.− is an anion; R.sup.2 is an optionally substituted alkylene group; R.sup.3 is hydrogen or an optionally substituted hydrocarbyl group; and n is 0 or a positive integer; provided that n is not 0 when R.sup.3 is hydrogen. ##STR00001##

Provided herein are biodiesel fuel mixtures having improved properties for reducing NOx emissions as well as total particular matter emissions, CO emissions, and total hydrocarbon emissions.

Provided herein are biodiesel fuel mixtures having improved properties for reducing NOx emissions as well as total particular matter emissions, CO emissions, and total hydrocarbon emissions.

A fuel additive composition, including: (a) one or more copolymer(s) including: at least one unit of the following formula (I), where u=0 or 1, E=—O— or —N(Z)—, or —O—CO—, or —CO—O— or —NH—CO— or —CO—NH—, where Z represents H or a C1-C6 alkyl group, G represents a group selected between a C1-C34 alkyl group, aromatic ring, aralkyl including at least one aromatic ring and at least one C1-C34 alkyl group, and at least one unit of the following formula (II), where R1″ is selected between a hydrogen atom and a methyl group, Q is selected between an oxygen atom and a group —NR′—, where R′ is selected between a hydrogen atom and C1-C12 hydrocarbon chains, R includes a C1-C34 hydrocarbon chain substituted with at least one quaternary ammonium, (b) one or more amines substituted with a polyalkenyl group, and (c) at least one carrier oil.

A fuel additive composition, including: (a) one or more copolymer(s) including: at least one unit of the following formula (I), where u=0 or 1, E=—O— or —N(Z)—, or —O—CO—, or —CO—O— or —NH—CO— or —CO—NH—, where Z represents H or a C1-C6 alkyl group, G represents a group selected between a C1-C34 alkyl group, aromatic ring, aralkyl including at least one aromatic ring and at least one C1-C34 alkyl group, and at least one unit of the following formula (II), where R1″ is selected between a hydrogen atom and a methyl group, Q is selected between an oxygen atom and a group —NR′—, where R′ is selected between a hydrogen atom and C1-C12 hydrocarbon chains, R includes a C1-C34 hydrocarbon chain substituted with at least one quaternary ammonium, (b) one or more amines substituted with a polyalkenyl group, and (c) at least one carrier oil.