A filter and a poly-oxygenated aluminum hydroxide material comprising a clathrate containing oxygen gas molecules. The poly-oxygenated aluminum hydroxide material removes NOx from an effluent gas, such as gas emitted from an internal combustion engine. The NOx is held in stasis over a range of temperatures, and may be collected.

The disclosure relates to fuel additive compositions including heavy paraffinic distillates and lighter petroleum distillates, in particular with the heavy paraffinic distillates including a mixture of hydrotreated and/or saturated components and solvent-dewaxed and/or branched components. The disclosure further relates to fuel compositions including the fuel additive composition and a liquid or solid combustible fuel. Related methods include methods of making the fuel compositions and methods of burning the fuel compositions. The resulting fuel compositions have several improved combustion properties such as improved combustion efficiency, improved combustion energy/calorie content, reduced sulfur generation, and reduced ash generation.

Treatment of hydrocarbon streams, and in one non-limiting embodiment refinery distillates, with high pH aqueous reducing agents, such as borohydride, results in reduction of the sulfur compounds such as disulfides, mercaptans and thioethers that are present to give easily removed sulfides. The treatment converts the original sulfur compounds into hydrogen sulfide or low molecular weight mercaptans that can be extracted from the distillate with caustic solutions, hydrogen sulfide or mercaptan scavengers, solid absorbents such as clay or activated carbon or liquid absorbents such as amine-aldehyde condensates and/or aqueous aldehydes.

A composition including poly-oxygenated metal hydroxide material that comprises a clathrate containing oxygen gas (O.sub.2) molecules and a fuel. The poly-oxygenated metal hydroxide material, such as OX66 material, is added to a fuel, such as, but not limited to, fuels such as petrol, alcohol and diesel, which are combustible in engines to create significantly increased horsepower and torque. The OX66 material is added to fuel in different ratios to generate improved performance. The different ratios are based on several factors including the type and design of the engine, the type of fuel, and environmental parameters.

A combustible gas from carbon black production is utilized in a gas engine by adding an oxygen-containing gas to the combustible gas, passing said mixed gas over a selective catalyst, which is active for oxidizing H.sub.2S to SO.sub.2 but substantially inactive for oxidation of CO, H.sub.2 and other hydrocarbons with less than 4 C-atoms, passing the converted gas through an SO.sub.2 removal step, and passing the cleaned gas to a gas engine or to an energy recovery boiler. This way, the tail gas from carbon black production, which is normally combusted in a CO boiler or incinerated, can be utilized to good effect.

A method for making a catalyst composition that includes a reduction catalyst mixture including a first reduction catalyst and a second reduction catalyst, wherein said first reduction catalyst comprises mixed vanadium oxides and phosphorus oxides, wherein said mixed vanadium and antimony oxides comprises V.sub.4Sb.sub.6O.sub.8, and wherein said second reduction catalyst comprises vanadium and antimony oxides; and an oxidation catalyst comprising ferrocene. The method includes selecting an organic petroleum distillate-soluble solvent that is effective to act as a reducing agent; introducing finely ground V.sub.2O.sub.5 and aqueous H.sub.3PO.sub.4 into said selected organic petroleum distillate-soluble solvent to make a first mixture; adding finely ground V/Sb oxide catalyst to said first mixture to make a second mixture; bringing the second mixture to a boil; cooling the second mixture; and adding the ferrocene or other organometallic Fe-source material to the cooled second mixture to make the catalyst composition.

A mobile diesel fuel refinery system comprise a particulate filter adapted to remove particulates from diesel fuel flowing through the diesel fuel conduction system, a water filter adapted to remove water from diesel fuel flowing through the diesel fuel conduction system following its passage through the particulate filter, a magnetic field of sufficient strength to further refine the diesel fuel flowing through the diesel fuel conduction system following its passage through the water filter, a catalyst injector configured to inject the catalyst from a catalyst tank into the diesel fuel flowing through the diesel fuel conduction system following its passage through the magnetic field, a dispensing conduit configured to conduct the diesel fuel from the diesel fuel refinement apparatus following injection of the catalyst.

Disclosed is a catalyst for desulfurization, including (a) an oxide selected from among SiO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, TiO.sub.2, MgO, MnO, CaO, Na.sub.2O, K.sub.2O and P.sub.2O.sub.3, (b) a metal selected from among Li, Cr, Co, Ni, Cu, Zn, Ga, Sr, Cd and Pb, and (c) a liquid compound selected from among sodium tetraborate (Na.sub.2B.sub.4O.sub.7.10H.sub.2O), sodium hydroxide (NaOH), sodium silicate (Na.sub.2SiO.sub.3) and hydrogen peroxide (H.sub.2O.sub.2). The catalyst of the invention has a 2:1 type layered structure in which one octahedral layer is interposed between two tetrahedral layers and which has a net negative charge due to occupation of only two of three positively charged sites in the octahedral layer, and the catalyst for desulfurization is provided in the form of a metal chelate compound through chelation with a metal ion, whereby sulfur oxide (SO.sub.x) can be adsorbed and removed at high efficiency upon combustion of a combustible substance.

The present invention discloses a homogenous cerium (Ce) catalyst composition comprising Ce(IV) complex alone, or Ce(IV) complex in a mixture with Ce(III) complex, that can significantly improve both LPG and soot combustion, resulting in higher flame temperatures, faster heating, reduced cooking time and reduced fuel consumption. The cerium(III) complex is cerium(III) 2-ethylhexanoate and the cerium(IV) complex is aqua(2-N-(2-hydroxyethylimino)-4-pentanoate) dinitrocerium(IV) [Ce(L1)(H.sub.2O)(NO.sub.3).sub.2], wherein L1 is 2-N-(2-hydroxyethylimino)-4-pentanone.

An additive composition for a marine fuel or a heating oil comprising a stabilized colloidal dispersion of catalytic metal particles, a neutral or overbased alkaline earth metal detergent and a carrier fluid miscible with a marine fuel oil, a heavy fuel oil, a marine distillate fuel, and/or a residual fuel oil. Also provided are marine fuel and/or heating oil compositions having the additive composition described above and associated methods and uses.