Patent classifications
C10L2230/20
Additive compositions and to fuel oils
An additive composition containing a polymer (A) and an anti-static additive (B). The polymer (A) has the following monomer components: (i) one or more compounds of formula (I) ##STR00001##
wherein R.sub.1 is hydrogen or CH.sub.3; and R.sub.2 is a hydrocarbon group having 6 to 30 carbon atoms and is a straight-chain or branched-chain alkyl group, or an aliphatic or aromatic cyclic group;
(ii) one or more compounds of formula (II) ##STR00002##
wherein R.sub.1 has the meaning above and wherein R.sub.3 is hydrogen or C.sub.1-C.sub.22 alkyl; each R.sub.4 is independently hydrogen or C.sub.1-C.sub.22 alkyl; R.sub.5 is hydrogen, a substituted or unsubstituted aliphatic or aromatic cyclic group, or a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms; n=0 or an integer from 1 to 22; and m is an integer from 1 to 30; and
(iii) one or more compounds of formula (III) ##STR00003##
wherein R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are each independently hydrogen, a straight-chain or branched-chain alkyl group having 1 to 20 carbon atoms which may be substituted or unsubstituted, hydroxyl, NH.sub.2, or wherein two or more of R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 may together form an aliphatic or aromatic ring system, which ring system may be substituted or unsubstituted. The anti-static additive (B) is (iv) an olefin polysulfone and (v) a polymeric polyamine reaction product of epichlorohydrin and an aliphatic primary monoamine or an N-aliphatic hydrocarbyl alkylene diamine, or the sulfonic acid salt of the polymeric polyamine reaction product. The weight:weight ratio of the polymer (A) to the anti-static additive (B) in the additive composition is from about 1:1 to about 500:1.
Fuel components from hydroprocessed deasphalted oils
Fuels and/or fuel blending components can be formed from hydroprocessing of high lift deasphalted oil. The high lift deasphalting can correspond to solvent deasphalting to produce a yield of deasphalted oil of at least 50 wt %, or at least 65 wt %, or at least 75 wt %. The resulting fuels and/or fuel blending components formed by hydroprocessing of the deasphalted oil can have unexpectedly high naphthene content and/or density. Additionally or alternately, the resulting fuels and/or fuel blending components can have a clear and bright appearance.
Additive compositions and to fuel oils
An additive composition comprises a polymer (A) and a condensation product (B) wherein Polymer (A) comprises the following monomer components: (i) one or more compounds of formula (I) (ii) one or more compounds of formula (II); and (iii) one or more compounds of formula (III); wherein condensation product (B) comprises the product formed by the reaction of an aliphatic aldehyde or ketone, or a reactive equivalent, with a substituted phenol or mixture of substituted phenols; The weight:weight ratio of the polymer (A) to the condensation product (B) is from 1:20 to 20:1.
Synthesis of guerbet alcohols
A method and system for preparing a mixture of Guerbet alcohols where one or more primary alcohols of the formula RCH.sub.2CH.sub.2OH are provided, with R representing hydrogen or a straight or branched chain alkyl group of 1 to 14 carbon atoms. A base and a catalyst are provided, which are mixed with the primary alcohol(s). The resulting mixture is heated to a process temperature above the boiling point of water under reaction conditions and the water resulting from the thus obtained condensation and dehydration of the primary alcohols is then removed constantly. When the Guerbet reaction has reached a certain stage, at least part of the reaction mixture is removed, followed by a separation of the desired Guerbet alcohols from the removed part of the reaction mixture. The other alcohols are then returned to the reaction mixture for obtaining a higher amount of the desired Guerbet alcohols.
FUEL COMPONENTS FROM HYDROPROCESSED DEASPHALTED OILS
Fuels and/or fuel blending components can be formed from hydroprocessing of high lift deasphalted oil. The high lift deasphalting can correspond to solvent deasphalting to produce a yield of deasphalted oil of at least 50 wt %, or at least 65 wt %, or at least 75 wt %. The resulting fuels and/or fuel blending components formed by hydroprocessing of the deasphalted oil can have unexpectedly high naphthene content and/or density. Additionally or alternately, the resulting fuels and/or fuel blending components can have a clear and bright appearance.
Modular firestarter assembly
A modular firestarter assembly. The modular firestarter assembly includes a number of modular components configured to be able to join to one another to form the firestarter assembly. The modular components can be broken down to save space. The modular firestarter assembly can be formed from a number of different combinations of the modular components to hold fuel sources and assist in starting a fire.
POLYETHYLENEAMINE SALTS OF SULPHONYL OLEIC ACID AND DUAL FUNCTIONAL HYDROCARBON FUEL ADDITIVE COMPOSITION THEREOF
The present invention discloses polyethyleneamine salts of sulphonyl oleic acid and a 5 hydrocarbon fuel additive composition comprising the same. The said polyethyleneamine salts of sulphonyl oleic acid is made by mixing a sulphonyl oleic acid with at least one polyethyleneamine. Wherein, the sulphonyl oleic acid is selected from at least one of (9Z)-8-sulfo-octadec-9-enoic acid or (9Z)-11-sulfo-octadec-9-enoic acid. The at least one polyethyleneamine is selected from triethylenetetramine (TETA), or diethylenetriamine 0 (DETA), pentamethyldiethylenetriamine, tetraethylenepentamine, 1,4,7-triazacyclononane, 1,1,1-Tris(aminomethyl)ethane, or cyclen. The hydrocarbon fuel additive composition is made of polyethyleneamine salts of sulphonyl oleic acid and a cosolvent system consisting of sulphonyl oleic acid and dioxane. Wherein, the said hydrocarbon fuel additive composition acts as a dual functional additive and synergistically improves the conductivity as well as 5 lubricity of a hydrotreated diesel fuel.
Composition for surface voltage reduction in distillate fuel
Additive composition mixtures and methods for synergistically maintaining low surface voltages of distillate fuels that include a synergistic conductivity improver additive composition for a distillate fuel. The additive composition includes: A) a mixture of (i) alkenyl polysulfone polymer, (ii) C16-C24 substituted maleic/polyamine copolymer, (iii) sulfonic acid, and (iv) aromatic solvent; and B) a mixture of (i) alkenyl polysulfone polymer, (v) polymeric reaction product of a C8-C18 aliphatic amine or diamine with epichlorohydrin; (iii) sulfonic acid, (iv) aromatic solvent; and optionally (vi) a quaternary ammonium compound. The additive composition contains from 30 to 60 wt. % component (A) and from 30 to 60 wt. % component (B) based on a total weight of the additive composition.
ADDITIVE COMPOSITIONS AND TO FUEL OILS
The invention relates to fuel oil compositions comprising an ester of an alkyl neo-monocarboxylic acid having a total number of from 5 to 30 carbon atoms and an aliphatic acyclic (C2 to C18) alkanol having a total number of from 2 to 18 carbon atoms and a total number of from 2 to 8 hydroxyl groups, wherein the aliphatic acyclic (C2 to C18) alkanol includes one or more alkyl chain(s) and each of said one or more alkyl chain(s) may optionally be interrupted by one or more oxygen atom(s), and to associated fuel additive compositions and uses of fuel additives.
Polyethyleneamine salts of sulphonyl oleic acid and dual functional hydrocarbon fuel additive composition thereof
The present invention discloses polyethyleneamine salts of sulphonyl oleic acid and a 5 hydrocarbon fuel additive composition comprising the same. The said polyethyleneamine salts of sulphonyl oleic acid is made by mixing a sulphonyl oleic acid with at least one polyethyleneamine. Wherein, the sulphonyl oleic acid is selected from at least one of (9Z)-8-sulfo-octadec-9-enoic acid or (9Z)-11-sulfo-octadec-9-enoic acid. The at least one polyethyleneamine is selected from triethylenetetramine (TETA), or diethylenetriamine 0 (DETA), pentamethyldiethylenetriamine, tetraethylenepentamine, 1,4,7-triazacyclononane, 1,1,1-Tris(aminomethyl)ethane, or cyclen. The hydrocarbon fuel additive composition is made of polyethyleneamine salts of sulphonyl oleic acid and a cosolvent system consisting of sulphonyl oleic acid and dioxane. Wherein, the said hydrocarbon fuel additive composition acts as a dual functional additive and synergistically improves the conductivity as well as 5 lubricity of a hydrotreated diesel fuel.