Friction modifier and compositions containing the friction modifier as a fuel additive are provided. Methods for improving fuel efficiency using these compositions are also provided.

Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

A process for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil (Feedstock), the process involving: mixing a quantity of the Feedstock with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid (Product) components of the Process Mixture from the gaseous components and by-product hydrocarbons of the Process Mixture and, discharging the Product. The Product is compliant with ISO standards for residual marine fuel oils and has a maximum sulfur content between the range of 0.05% wt. to 0.50% wt. The Product can be used as or as a blending stock for compliant, low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.

A multi-stage process for the production of an ISO8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core process under reactive conditions in a Reaction System composed of one or more reaction vessels, wherein one or more of the reaction vessels contains one or more catalysts in the form of a structured catalyst bed and is operated under reactive distillation conditions. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed.

The invention relates to specific copolymers obtainable by co-polymerizing at least the following monomers: at least one bicyclic (meth)acrylate ester at least one lower-alkyl (meth)acrylate optionally, and preferably, at least one aromatic vinyl monomer; and optionally other ethylenically unsaturated monomers, whereby the copolymer has a weight averaged molecular weight of from 100,000 to 10,000,000 D, determined using GPC-MALS techniques for a solution in THF at 40° C., as well as to the way to synthesize such copolymers and the use of such polymers to modify the rheology of a liquid in which they are soluble.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

Fuel compositions that are low sulfur and have adequate combustion quality are disclosed. An example fuel composition that is low sulfur may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the fuel composition; a calculated carbon aromaticity index of about 870 or less; a density at 15° C. of about 900 kg/m.sup.3 to about 1,010 kg/m.sup.3; a kinematic viscosity at 50° C. of about 100 centistokes to about 700 centistokes; and an estimated cetane number of about 7 or greater.

A fuel additive composition includes: (a) one or more copolymers including:

at least one unit of formula (I) below:

##STR00001##

with u=0 or 1, E=—O— or —N(Z)—, or —O—CO—, or —CO—O— or —NH—CO— or —CO—NH—, with Z representing H or a C.sub.1-C.sub.6 alkyl group, G represents a group chosen from a C.sub.1-C.sub.34 alkyl, an aromatic nucleus, an aralkyl including at least one aromatic nucleus and at least one C.sub.1-C.sub.34 alkyl group, and —at least one unit of formula (II) below:

##STR00002##

in which R.sub.1″ is chosen from a hydrogen atom and a methyl group, Q is chosen from an oxygen atom and a group —NR′— with R′ being chosen from a hydrogen atom and C.sub.1 to C.sub.12 hydrocarbon-based chains, R comprises a C.sub.1 to C.sub.34 hydrocarbon-based chain substituted with at least one quaternary ammonium group.

A composition including poly-oxygenated metal hydroxide material that comprises a clathrate containing oxygen gas (O.sub.2) molecules free of chlorine and a fuel, The poly-oxygenated metal hydroxide material, such as OX66™ material, is added to a fuel, such as, but not limited to, fuels such as petrol, alcohol and diesel, which are combustible in engines to create significantly increased horsepower and torque. The OX66™ material is added to fuel in different ratios to generate improved performance. The different ratios are based on several Tractors including the type and design of the engine, the type of fuel, and environmental parameters.