The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

A lubricant made from vegetable oil that can form a friction film when used. The lubricant has 86-99 wt % of vegetable oil that contains double bonds and bis-allylic protons, 10-0.5 wt % trans FAT, 3.6-0.3 wt % surfactant, and 0.4-0.2 wt % antioxidant. Additionally, the weight percentages of surfactant are 3.6˜0.3 wt %, and the weight percentages of antioxidant are 0.4˜0.2 wt %.

A lubricant made from vegetable oil that can form a friction film when used. The lubricant has 86-99 wt % of vegetable oil that contains double bonds and bis-allylic protons, 10-0.5 wt % trans FAT, 3.6-0.3 wt % surfactant, and 0.4-0.2 wt % antioxidant. Additionally, the weight percentages of surfactant are 3.6˜0.3 wt %, and the weight percentages of antioxidant are 0.4˜0.2 wt %.

Herein is provided a process for combined renewable 1-decene and renewable carboxylic diacid production from a fatty acid ester containing feedstock, wherein the feedstock is first subjected to metathesis reaction conditions, recovery of 1-decene and then to microbial oxidation to yield diacids in a fermentation broth. Diacids of unusual carbon chains lengths are thereby obtainable.

Herein is provided a process for combined renewable 1-decene and renewable carboxylic diacid production from a fatty acid ester containing feedstock, wherein the feedstock is first subjected to metathesis reaction conditions, recovery of 1-decene and then to microbial oxidation to yield diacids in a fermentation broth. Diacids of unusual carbon chains lengths are thereby obtainable.

A lubricant base oil of the present invention includes an ester compound including: a structural moiety (A) that is derived from an alcohol compound (A); and a structural moiety (B) that is derived from a carboxylic acid, the structural moiety B including: a structural moiety (B1) that is derived from a monocarboxylic acid (B1); and a structural moiety (B2) that is derived from an aliphatic monocarboxylic acid (B2) having 4 or more and 18 or less carbon atoms. According to the present invention, it is possible to provide a lubricant base oil having excellent low-temperature stability and high heat resistance while maintaining torque-lowering properties.

A lubricant base oil of the present invention includes an ester compound including: a structural moiety (A) that is derived from an alcohol compound (A); and a structural moiety (B) that is derived from a carboxylic acid, the structural moiety B including: a structural moiety (B1) that is derived from a monocarboxylic acid (B1); and a structural moiety (B2) that is derived from an aliphatic monocarboxylic acid (B2) having 4 or more and 18 or less carbon atoms. According to the present invention, it is possible to provide a lubricant base oil having excellent low-temperature stability and high heat resistance while maintaining torque-lowering properties.

A lubricant additive may be synthesized by forming a nanohybrid of a transition metal dichalcogenide and a metal borate, forming a base oil, and then dispersing the transition metal dichalcogenide into the base oil. An exemplary nanohybrid may be synthesized by forming a first solution by adding a borax solution to an aqueous solution of a metal source, forming a second solution by adding ethanol to the first solution, forming a mixture by mixing the transition metal dichalcogenide with the second solution, and heating the mixture at a temperature of 180° C. to 230° C. and a pressure of 5 to 20 bar under a nitrogen atmosphere.

A lubricant additive may be synthesized by forming a nanohybrid of a transition metal dichalcogenide and a metal borate, forming a base oil, and then dispersing the transition metal dichalcogenide into the base oil. An exemplary nanohybrid may be synthesized by forming a first solution by adding a borax solution to an aqueous solution of a metal source, forming a second solution by adding ethanol to the first solution, forming a mixture by mixing the transition metal dichalcogenide with the second solution, and heating the mixture at a temperature of 180° C. to 230° C. and a pressure of 5 to 20 bar under a nitrogen atmosphere.

The present invention is directed to a composition comprising a synthetic ester having a fatty acid mixture including: oleic acid in amount of at least about 85 wt % of the fatty acid mixture; linoleic acid in an amount of about 3 wt % of the fatty acid mixture or less; and linolenic acid in an amount of about 0.5 wt % of the fatty acid mixture or less.