Disclosed herein are polyketone triglyceride compositions containing 8 to 16 ketone carbonyl moieties per triglyceride unit and methods of making. Also disclosed are polyimine triglyceride compositions having has 8 to 16 nitrogen moieties per triglyceride unit and methods of making. Also disclosed are polyamine triglyceride compositions containing 8 to 16 nitrogen moieties per triglyceride unit and methods of making

Disclosed herein are polyketone triglyceride compositions containing 8 to 16 ketone carbonyl moieties per triglyceride unit and methods of making. Also disclosed are polyimine triglyceride compositions having has 8 to 16 nitrogen moieties per triglyceride unit and methods of making. Also disclosed are polyamine triglyceride compositions containing 8 to 16 nitrogen moieties per triglyceride unit and methods of making.

Disclosed herein are polyketone triglyceride compositions containing 8 to 16 ketone carbonyl moieties per triglyceride unit and methods of making. Also disclosed are polyimine triglyceride compositions having has 8 to 16 nitrogen moieties per triglyceride unit and methods of making. Also disclosed are polyamine triglyceride compositions containing 8 to 16 nitrogen moieties per triglyceride unit and methods of making.

A coated sliding member 10 for use under an environment where it is in contact with lubricant, comprising: a base material 12; and a first hard carbon layer 14 having a thickness of 3 m or more formed on a surface of the base material by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon, and a second hard carbon layer 15 formed on a surface of the first hard carbon layer by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon and nitrogen, the film thickness of the second hard carbon layer being 3 to 35% of the film thickness of the first hard carbon layer.

A coated sliding member 10 for use under an environment where it is in contact with lubricant, comprising: a base material 12; and a first hard carbon layer 14 having a thickness of 3 m or more formed on a surface of the base material by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon, and a second hard carbon layer 15 formed on a surface of the first hard carbon layer by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon and nitrogen, the film thickness of the second hard carbon layer being 3 to 35% of the film thickness of the first hard carbon layer.

A method for improving wear control, while maintaining or improving energy efficiency, in an engine or other mechanical component lubricated with a lubricating oil, by using as the lubricating oil a formulated oil. The formulated oil includes at least one lubricating oil base stock having one or more liquid crystals represented by the formula:

R1-(A).sub.m-Y(B).sub.nR2

wherein R1 and R2 are the same or different and are a substituted or unsubstituted, hydrocarbon, alkoxy or alkylthio group having from 2 to 24 carbon atoms; A and B are the same or different and are a cycloaliphatic group or aromatic group, provided at least one of A and B is an aromatic group; Y is a covalent bond, CH2-CH2-, CHCH, OCOO, CO, CSO, CSS, CS, O, S, SO, SO2-, CH2O, OCH2O, NO, ONO2, or CN; and m and n are independently 0, 1, 2 or 3. The lubricating oil base stock has a kinematic viscosity of 2 cSt to 200 cSt at 40 C., and 1 cSt to 25 cSt at 100 C. Also, this disclosure relates to low traction/energy efficient liquid crystal base stocks containing liquid crystals.

A method for improving wear control, while maintaining or improving energy efficiency, in an engine or other mechanical component lubricated with a lubricating oil, by using as the lubricating oil a formulated oil. The formulated oil includes at least one lubricating oil base stock having one or more liquid crystals represented by the formula:

R1-(A).sub.m-Y(B).sub.nR2

wherein R1 and R2 are the same or different and are a substituted or unsubstituted, hydrocarbon, alkoxy or alkylthio group having from 2 to 24 carbon atoms; A and B are the same or different and are a cycloaliphatic group or aromatic group, provided at least one of A and B is an aromatic group; Y is a covalent bond, CH2-CH2-, CHCH, OCOO, CO, CSO, CSS, CS, O, S, SO, SO2-, CH2O, OCH2O, NO, ONO2, or CN; and m and n are independently 0, 1, 2 or 3. The lubricating oil base stock has a kinematic viscosity of 2 cSt to 200 cSt at 40 C., and 1 cSt to 25 cSt at 100 C. Also, this disclosure relates to low traction/energy efficient liquid crystal base stocks containing liquid crystals.

A composition for enhanced heat transfer fluid performance. The composition includes at least one base heat transfer fluid. The at least one base heat transfer fluid undergoes one or more phase changes in a heat transfer process. The heat transfer process includes a heated zone and/or a cooled zone. The one or more phase changes increase heat removal from the heated zone and/or increase heat rejection in the cooled zone, as compared to heat removal from a heated zone and/or heat rejection in a cooled zone of a heat transfer process having a base heat transfer fluid that does not undergo one or more phase changes. The base heat transfer fluids can exhibit liquid crystal behavior (e.g., heat transfer fluids having nematic, smectic or discotic liquid crystals). A method for conducting heat transfer in a heating and/or cooling system using the compositions comprising the base heat transfer fluids.

A composition for enhanced heat transfer fluid performance. The composition includes at least one base heat transfer fluid. The at least one base heat transfer fluid undergoes one or more phase changes in a heat transfer process. The heat transfer process includes a heated zone and/or a cooled zone. The one or more phase changes increase heat removal from the heated zone and/or increase heat rejection in the cooled zone, as compared to heat removal from a heated zone and/or heat rejection in a cooled zone of a heat transfer process having a base heat transfer fluid that does not undergo one or more phase changes. The base heat transfer fluids can exhibit liquid crystal behavior (e.g., heat transfer fluids having nematic, smectic or discotic liquid crystals). A method for conducting heat transfer in a heating and/or cooling system using the compositions comprising the base heat transfer fluids.

A method for improving friction and wear control, while maintaining or improving energy efficiency, in an engine or other mechanical component lubricated with a lubricating oil, by using as the lubricating oil a formulated oil. The formulated oil has a composition including at least one lubricating oil base stock. The at least one lubricating oil base stock includes one or more liquid crystals, wherein the one or more liquid crystals are represented by the formula:

A(R1).sub.n

wherein A is a mono-ring or a multi-ring aromatic group, R1 is the same or different and is a substituted or unsubstituted, hydrocarbon, alkoxy, or alkylthio group having from 2 to 24 carbon atoms, and n is a value from 1 to 12. The lubricating oil base stock has a kinematic viscosity of 2 cSt to 200 cSt at 40 C., as determined according to ASTM D445, and a kinematic viscosity of 1 cSt to 25 cSt at 100 C., as determined according to ASTM D445.