Patent classifications
C10M107/38
ULTRAVIOLET CURABLE RESIN COMPOSITION AND SLIDING MEMBER
There is provided an ultraviolet curable resin composition for a self-lubricating liner, including: a (meth)acrylate compound having an isocyanuric acid ring; at least one of (meth)acrylate having a phosphoric acid ester group and (meth)acrylate having a silane group: a polythiol compound; and a polytetrafluoroethylene resin as a solid lubricant.
ROLLING BEARING
A rolling bearing is filled with a grease composition that contains a fluorine-based grease including a fluorine-based base oil and a fluorine-based thickener, a non-fluorine-based grease including a non-fluorine-based base oil and a non-fluorine-based thickener, and an additive serving as a dispersant. The non-fluorine-based thickener includes at least one of aliphatic-aromatic urea, alicyclic-aliphatic urea and aliphatic urea. The dispersant includes at least one of polycarboxylic acid metal salt, fluorine-containing group/lipophilic group-containing oligomer, fluorinated ether diamide, and organic acid metal salt.
ROLLING BEARING
A rolling bearing is filled with a grease composition that contains a fluorine-based grease including a fluorine-based base oil and a fluorine-based thickener, a non-fluorine-based grease including a non-fluorine-based base oil and a non-fluorine-based thickener, and an additive serving as a dispersant. The non-fluorine-based thickener includes at least one of aliphatic-aromatic urea, alicyclic-aliphatic urea and aliphatic urea. The dispersant includes at least one of polycarboxylic acid metal salt, fluorine-containing group/lipophilic group-containing oligomer, fluorinated ether diamide, and organic acid metal salt.
COPOLYMERS OF TETRAFLUOROETHYENE OXIDE AND HEXAFLUOROPROPYLENE OXIDE USEFUL AS LUBRICANTS
A copolymer includes 20 mol % to 80 mol % of —CF.sub.2CF.sub.2O— units, 20 mol % to 80 mol % of —CF(CF.sub.3)CF.sub.2O— units, and 0 mol % to 45 mol % of one or more additional perfluoroalkyleneoxy units. The copolymer has a molecular weight M.sub.n of 1,500 to 20,000, a viscosity index of 100 to 220, and an average tetrafluoroethylene oxide (TFEO) run length less than 6. A process of forming a perfluoroalkyl polyether copolymer includes feeding a gas stream containing TFEO and hexafluoropropylene oxide (HFPO) into a reactor containing a fluorinated solvent, a fluoride salt, an ether, and an acid fluoride to form an acid fluoride-containing polymer. The process also includes hydrolyzing the acid fluoride-containing polymer to form a perfluoroalkyl polyether carboxylic acid or carboxylate salt. The process further includes distilling off the fluorinated solvent and treating the perfluoroalkyl polyether carboxylic acid or carboxylate salt with elemental fluorine to obtain the perfluoroalkyl polyether copolymer.
COPOLYMERS OF TETRAFLUOROETHYENE OXIDE AND HEXAFLUOROPROPYLENE OXIDE USEFUL AS LUBRICANTS
A copolymer includes 20 mol % to 80 mol % of —CF.sub.2CF.sub.2O— units, 20 mol % to 80 mol % of —CF(CF.sub.3)CF.sub.2O— units, and 0 mol % to 45 mol % of one or more additional perfluoroalkyleneoxy units. The copolymer has a molecular weight M.sub.n of 1,500 to 20,000, a viscosity index of 100 to 220, and an average tetrafluoroethylene oxide (TFEO) run length less than 6. A process of forming a perfluoroalkyl polyether copolymer includes feeding a gas stream containing TFEO and hexafluoropropylene oxide (HFPO) into a reactor containing a fluorinated solvent, a fluoride salt, an ether, and an acid fluoride to form an acid fluoride-containing polymer. The process also includes hydrolyzing the acid fluoride-containing polymer to form a perfluoroalkyl polyether carboxylic acid or carboxylate salt. The process further includes distilling off the fluorinated solvent and treating the perfluoroalkyl polyether carboxylic acid or carboxylate salt with elemental fluorine to obtain the perfluoroalkyl polyether copolymer.
POLYAMIDE RESIN COMPOSITION AND SLIDING MEMBER
The present invention provides a polyamide resin composition (nylon composition) and a sliding member using this, which have excellent moldability and sliding properties. The polyamide resin composition contains, as additives, polyethylene resin of 5 to 20% by mass, polytetrafluoroethylene resin of 5 to 30% by mass, modified polyolefin resin of 0.5 to 5% by mass, and phosphate of 1 to 5% by mass, in addition to polyamide resin that is a main component. The sliding member is produced by molding this polyamide resin composition.
POLYAMIDE RESIN COMPOSITION AND SLIDING MEMBER
The present invention provides a polyamide resin composition (nylon composition) and a sliding member using this, which have excellent moldability and sliding properties. The polyamide resin composition contains, as additives, polyethylene resin of 5 to 20% by mass, polytetrafluoroethylene resin of 5 to 30% by mass, modified polyolefin resin of 0.5 to 5% by mass, and phosphate of 1 to 5% by mass, in addition to polyamide resin that is a main component. The sliding member is produced by molding this polyamide resin composition.
WATER-BASED COMPOSITION COMPRISING A FLUORINATED POLYMER
This invention provides for a composition particularly useful in a method comprising applying the composition to a surface to be lubricated, said composition comprising: at least one polymer (P) comprising a partially or fully fluorinated, straight or branched, polyoxyalkylene chain (R.sub.f) having two chain ends, wherein one or both chain end(s) bear(s) a hydroxy-, alkoxy- or acyl-oxy-terminated polyoxyalkylene chain free from fluorine atoms (R.sub.a), said chain comprising from 4 to 50 fluorine-free oxyalkylene units, said units being the same or different from one another and being selected from —CH.sub.2CH.sub.2O— and —CH.sub.2CH(O)O—, wherein J is independently straight or branched alkyl or aryl, preferably methyl, ethyl or phenyl and water.
WATER-BASED COMPOSITION COMPRISING A FLUORINATED POLYMER
This invention provides for a composition particularly useful in a method comprising applying the composition to a surface to be lubricated, said composition comprising: at least one polymer (P) comprising a partially or fully fluorinated, straight or branched, polyoxyalkylene chain (R.sub.f) having two chain ends, wherein one or both chain end(s) bear(s) a hydroxy-, alkoxy- or acyl-oxy-terminated polyoxyalkylene chain free from fluorine atoms (R.sub.a), said chain comprising from 4 to 50 fluorine-free oxyalkylene units, said units being the same or different from one another and being selected from —CH.sub.2CH.sub.2O— and —CH.sub.2CH(O)O—, wherein J is independently straight or branched alkyl or aryl, preferably methyl, ethyl or phenyl and water.
MAGNETIC RECORDING MEDIUM AND MAGNETIC RECORDING/REPRODUCING APPARATUS
The present invention relates to a magnetic recording medium in which a lubricant layer contains a compound A represented by general formula (1) and a compound B represented by general formula (2), satisfying (A/B)=0.2 to 3.0, and has an average thickness of 0.8 nm to 2 nm. R.sup.1—C.sub.6H.sub.4OCH.sub.2CH(OH)CH.sub.2OCH.sub.2—R.sup.2—CH.sub.2OCH.sub.2CH(OH)CH.sub.2OH . . . (1) (R.sup.1 is an alkoxy group having 1 to 4 carbon atoms. R.sup.2 is —CF.sub.2O(CF.sub.2CF.sub.2O).sub.x(CF.sub.2O).sub.yCF.sub.2— (x, y=0 to 15), —CF.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.zCF.sub.2CF.sub.2— (z=1 to 15), —CF.sub.2CF.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2).sub.nCF.sub.2CF.sub.2CF.sub.2— (n=0 to 4). HOCH.sub.2CF.sub.2CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.mCF.sub.2CF.sub.2CH.sub.2OCH.sub.2CH(OH)CH.sub.2OH . . . (2) (m is an integer).