Embodiments herein include coated medical devices and coatings with salt groups. In an embodiment, a coated medical device is included, the coated medical device including a substrate and a polymeric layer disposed over the substrate. The polymeric layer includes a polymer and has an exterior surface. The coated medical device further includes a plurality of salt groups bonded to the polymer of the polymeric layer and disposed on the exterior surface of the polymeric layer. The salt groups can be the reaction product of a reactive group with an acid or base. In an embodiment, a method of making a medical device is included. Other embodiments are also included herein.

Sulfur functionalized polyalphaolefins (PAOs) comprising at least one SCH.sub.2C(R.sub.1R.sub.2)S moiety, wherein R.sub.1 and R.sub.2 are independently selected from linear or branched alkyl, are provided. The sulfur functionalized polyalphaolefins (PAOs) are prepared by contacting PAO with elemental sulfur and are useful as lubricating oil base stocks or co-base stocks. The sulfur functionalized PAOs exhibit high oxidative stability and can be prepared without the need for hydrogenation.

Sulfur functionalized polyalphaolefins (PAOs) comprising at least one SCH.sub.2C(R.sub.1R.sub.2)S moiety, wherein R.sub.1 and R.sub.2 are independently selected from linear or branched alkyl, are provided. The sulfur functionalized polyalphaolefins (PAOs) are prepared by contacting PAO with elemental sulfur and are useful as lubricating oil base stocks or co-base stocks. The sulfur functionalized PAOs exhibit high oxidative stability and can be prepared without the need for hydrogenation.

The invention relates to a copolymer and a substrate having a surface, at least one part of which is coated with an epilame agent comprising at least one compound in the form of a copolymer comprising V units, N units, optionally at least one M unit, and optionally at least one P unit, linked by covalent bonds by their main chains, wherein ##STR00001## wherein W, X, Y, Z are spacer arms, T is a tracer group arranged to determine the concentration of epilame agent in an epilame-coating bath, L is a halogenated, preferably fluorinated, C.sub.1-C.sub.20 carbon moiety, A is a substrate anchoring moiety, Q is H, CH.sub.3, or a hydrocarbon chain different from T. The invention also concerns a method for coating such a substrate with epilame, said method comprising a step of checking the concentration of epilame agent in the epilame-coating bath by means of the tracer group and if necessary, a step of readjusting the concentration of epilame agent in the epilame-coating bath.

The invention relates to a copolymer and a substrate having a surface, at least one part of which is coated with an epilame agent comprising at least one compound in the form of a copolymer comprising V units, N units, optionally at least one M unit, and optionally at least one P unit, linked by covalent bonds by their main chains, wherein ##STR00001## wherein W, X, Y, Z are spacer arms, T is a tracer group arranged to determine the concentration of epilame agent in an epilame-coating bath, L is a halogenated, preferably fluorinated, C.sub.1-C.sub.20 carbon moiety, A is a substrate anchoring moiety, Q is H, CH.sub.3, or a hydrocarbon chain different from T. The invention also concerns a method for coating such a substrate with epilame, said method comprising a step of checking the concentration of epilame agent in the epilame-coating bath by means of the tracer group and if necessary, a step of readjusting the concentration of epilame agent in the epilame-coating bath.

The invention to which this application relates is improvements to the provision of Molybdenum and/or Tungsten containing coatings of the type which can be used to improve certain characteristics of the surface of a substrate to which the coating is applied. In one embodiment the coating also includes Ti to provide the advantages of high adhesion, high humidity and wear resistance of the coating and TiB.sub.2 to promote the formation of a relatively uniform, dense, coating, so strengthening the coating which is formed and improving the high temperature performance of the coatings.

The invention to which this application relates is improvements to the provision of Molybdenum and/or Tungsten containing coatings of the type which can be used to improve certain characteristics of the surface of a substrate to which the coating is applied. In one embodiment the coating also includes Ti to provide the advantages of high adhesion, high humidity and wear resistance of the coating and TiB.sub.2 to promote the formation of a relatively uniform, dense, coating, so strengthening the coating which is formed and improving the high temperature performance of the coatings.

A hydrophilic copolymer that can form a surface lubricious layer exhibiting superior lubricating property and durability (lubrication retaining property), is provided. A hydrophilic copolymer having a good solvent solubility is provided. A hydrophilic copolymer is provided containing: structural units derived from a polymerizable monomer (A) having a sulfobetaine structure; structural units derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (SO.sub.3H), a sulfuric acid group (OSO.sub.3H), a sulfurous acid group (OSO.sub.2H), and groups of salts thereof; and structural units derived from a polymerizable monomer (C) having a photoreactive group.

A hydrophilic copolymer that can form a surface lubricious layer exhibiting superior lubricating property and durability (lubrication retaining property), is provided. A hydrophilic copolymer having a good solvent solubility is provided. A hydrophilic copolymer is provided containing: structural units derived from a polymerizable monomer (A) having a sulfobetaine structure; structural units derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (SO.sub.3H), a sulfuric acid group (OSO.sub.3H), a sulfurous acid group (OSO.sub.2H), and groups of salts thereof; and structural units derived from a polymerizable monomer (C) having a photoreactive group.

A lubricating system includes a machine configured to operate in a first operating state and a second operating state; and a heat activated polymer material applied to at least a part of the machine and to remain solid during the first operating state and to soften upon being heated in the second operating state to lubricate the machine. The heat activated polymer material may soften due to increased friction incurred by the machine in the second operating state. A heating element may be operatively connected to any of the machine and the heat activated polymer material. The heat activated polymer material may soften due to being heated by the heating element in the second operating state. An injector may apply the heat activated polymer material to the machine. A channel may direct a flow of the heat activated polymer material as it softens in the second operating state.