A mixture of polymers with lubricating properties is provided. The polymer can be used to produce a lubricating fluid. They can also be born on a surface or embedded in a porous material. This mixture of polymers comprises (a) a pharmaceutically acceptable bottle-brush polymer comprising a backbone with polymeric pendant chains, and (b) a pharmaceutically acceptable linear polymer. In the lubricating fluid, the bottle-brush polymer and the linear polymer are dissolved together in a pharmaceutically acceptable solvent.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I):

##STR00001##

wherein each instance of R.sup.1 is independently —H or

##STR00002##

wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is

##STR00003##

of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I):

##STR00001##

wherein each instance of R.sup.1 is independently —H or

##STR00002##

wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is

##STR00003##

of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I): ##STR00001##
wherein each instance of R.sup.1 is independently —H or ##STR00002##
wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is ##STR00003##
of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I): ##STR00001##
wherein each instance of R.sup.1 is independently —H or ##STR00002##
wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is ##STR00003##
of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

Process for preparing water-soluble polymers in powder form by polymerization of water-soluble monoethylenically unsaturated monomers comprising the successive steps: a) Spraying on the inner wall of a polymerization vessel, the lubricant composition LC1: alkyl oleate/polyoxyethylene oleyl ether phosphate/sorbitan monolaurate, b) Polymerizing in aqueous solution in the presence of polymerization initiators at least one water-soluble monounsaturated ethylenic monomer, c) Discharging the polymer gel, d) Granulating the polymer gel thus obtained in a granulator, in presence of a lubricant composition LC2: alkyl oleate/polyxoyethylene oleyl ether phosphate/sorbitan monolaurate, e) Drying the polymer gel to obtain a polymer in powder form, f) Grinding and sifting the powder.

Process for preparing water-soluble polymers in powder form by polymerization of water-soluble monoethylenically unsaturated monomers comprising the successive steps: a) Spraying on the inner wall of a polymerization vessel, the lubricant composition LC1: alkyl oleate/polyoxyethylene oleyl ether phosphate/sorbitan monolaurate, b) Polymerizing in aqueous solution in the presence of polymerization initiators at least one water-soluble monounsaturated ethylenic monomer, c) Discharging the polymer gel, d) Granulating the polymer gel thus obtained in a granulator, in presence of a lubricant composition LC2: alkyl oleate/polyxoyethylene oleyl ether phosphate/sorbitan monolaurate, e) Drying the polymer gel to obtain a polymer in powder form, f) Grinding and sifting the powder.

The present disclosure relates to polysiloxanes, processes for preparing polysiloxanes, and hydraulic fluids comprising polysiloxanes. This disclosure also relates to hydraulic fluids comprising one or more polysiloxane compounds and diphosphonate compounds, and to the use of diphosphonate compounds in hydraulic fluids or as additives or components in various compositions, for example to provide fire retardant properties to a fluid or composition. This disclosure also relates to use of the compositions as hydraulic fluids, which may be used in various machines, vehicles and craft, including aircraft.

A hydrophilic copolymer that can form a surface lubricious layer exhibiting superior lubricating property and durability (lubrication retaining property), is provided. A hydrophilic copolymer having a good solvent solubility is provided. A hydrophilic copolymer is provided containing: structural units derived from a polymerizable monomer (A) having a sulfobetaine structure; structural units derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (—SO.sub.3H), a sulfuric acid group (—OSO.sub.3H), a sulfurous acid group (—OSO.sub.2H), and groups of salts thereof; and structural units derived from a polymerizable monomer (C) having a photoreactive group.

A hydrophilic copolymer that can form a surface lubricious layer exhibiting superior lubricating property and durability (lubrication retaining property), is provided. A hydrophilic copolymer having a good solvent solubility is provided. A hydrophilic copolymer is provided containing: structural units derived from a polymerizable monomer (A) having a sulfobetaine structure; structural units derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (—SO.sub.3H), a sulfuric acid group (—OSO.sub.3H), a sulfurous acid group (—OSO.sub.2H), and groups of salts thereof; and structural units derived from a polymerizable monomer (C) having a photoreactive group.