A lubricating system includes a machine configured to operate in a first operating state and a second operating state; and a heat activated polymer material applied to at least a part of the machine and to remain solid during the first operating state and to soften upon being heated in the second operating state to lubricate the machine. The heat activated polymer material may soften due to increased friction incurred by the machine in the second operating state. A heating element may be operatively connected to any of the machine and the heat activated polymer material. The heat activated polymer material may soften due to being heated by the heating element in the second operating state. An injector may apply the heat activated polymer material to the machine. A channel may direct a flow of the heat activated polymer material as it softens in the second operating state.

A lubricating system includes a machine configured to operate in a first operating state and a second operating state; and a heat activated polymer material applied to at least a part of the machine and to remain solid during the first operating state and to soften upon being heated in the second operating state to lubricate the machine. The heat activated polymer material may soften due to increased friction incurred by the machine in the second operating state. A heating element may be operatively connected to any of the machine and the heat activated polymer material. The heat activated polymer material may soften due to being heated by the heating element in the second operating state. An injector may apply the heat activated polymer material to the machine. A channel may direct a flow of the heat activated polymer material as it softens in the second operating state.

To provide a surface treatment agent capable of imparting excellent water/oil repellency, fingerprint stain removability, abrasion resistance and lubricity to the surface of a substrate. A surface treatment agent for a substrate, comprising a perfluoropolyether group-containing phosphate compound, a coating agent comprising the surface treatment agent and a liquid medium, and a substrate having a surface layer formed from the surface treatment agent or the coating agent.

To provide a surface treatment agent capable of imparting excellent water/oil repellency, fingerprint stain removability, abrasion resistance and lubricity to the surface of a substrate. A surface treatment agent for a substrate, comprising a perfluoropolyether group-containing phosphate compound, a coating agent comprising the surface treatment agent and a liquid medium, and a substrate having a surface layer formed from the surface treatment agent or the coating agent.

Provided is a lubricity-imparting agent that can impart durable lubricity (in particular, lubricity at the time of wetting) to a substrate. It has been found that a lubricity-imparting agent including a copolymer containing a constitutional unit (A) based on 2-methacryloyloxyethyl phosphorylcholine and a constitutional unit (B) based on a photoreactive functional group-containing monomer, or a copolymer containing a constitutional unit (A) based on 2-methacryloyloxyethyl phosphorylcholine, a constitutional unit (B) based on a photoreactive functional group-containing monomer, and a constitutional unit (C) based on a hydrophobic group-containing monomer can impart durable lubricity to a substrate surface through a simple approach called photoirradiation.

Provided is a lubricity-imparting agent that can impart durable lubricity (in particular, lubricity at the time of wetting) to a substrate. It has been found that a lubricity-imparting agent including a copolymer containing a constitutional unit (A) based on 2-methacryloyloxyethyl phosphorylcholine and a constitutional unit (B) based on a photoreactive functional group-containing monomer, or a copolymer containing a constitutional unit (A) based on 2-methacryloyloxyethyl phosphorylcholine, a constitutional unit (B) based on a photoreactive functional group-containing monomer, and a constitutional unit (C) based on a hydrophobic group-containing monomer can impart durable lubricity to a substrate surface through a simple approach called photoirradiation.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I):

##STR00001##

wherein each instance of R.sup.1 is independently H or

##STR00002##

wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is

##STR00003##

of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I):

##STR00001##

wherein each instance of R.sup.1 is independently H or

##STR00002##

wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is

##STR00003##

of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

A lubricant adheres to a magnetic recording medium via at least one of chemisorption or bonding, and contains a perfluorinated polyether attached to or terminated with a functional group that is phosphonic acid, silanol or carboxylic acid, and may be:

R.sub.1R.sub.fR.sub.1 where R.sub.f is CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.n, CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2, CF.sub.2O[CF(CF.sub.3)CF.sub.2O].sub.nCF.sub.2, CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2, CF.sub.2O(CF.sub.2CF.sub.2O).sub.nCF.sub.2, n, m is from 1 to 100 and R.sub.1 is the functional group. A lubricant is formed from a multiple ether segments according to formula:

Re.sup.1Rb.sup.1-Ri-Rc-Ri-Rb.sup.2Re.sup.2; where Rc includes perfluoroalkyl ether, Rb.sup.1 and Rb.sup.2 are, independently, a sidechain segment including a perfluoroalkyl ether, optional Ri independently is a divalent linking segment including a functional group including elements from periodic table Group 13-17, and of Re.sup.1 and Re.sup.2 are phosphonic acid, silanol or carboxylic acid. Lubricant synthesis includes reacting a perfluorinated polyether with a halogenated functional group, selected from phosphonic acid, silanol or carboxylic acid.

A lubricant adheres to a magnetic recording medium via at least one of chemisorption or bonding, and contains a perfluorinated polyether attached to or terminated with a functional group that is phosphonic acid, silanol or carboxylic acid, and may be:

R.sub.1R.sub.fR.sub.1 where R.sub.f is CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.n, CF.sub.2O(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2, CF.sub.2O[CF(CF.sub.3)CF.sub.2O].sub.nCF.sub.2, CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2, CF.sub.2O(CF.sub.2CF.sub.2O).sub.nCF.sub.2, n, m is from 1 to 100 and R.sub.1 is the functional group. A lubricant is formed from a multiple ether segments according to formula:

Re.sup.1Rb.sup.1-Ri-Rc-Ri-Rb.sup.2Re.sup.2; where Rc includes perfluoroalkyl ether, Rb.sup.1 and Rb.sup.2 are, independently, a sidechain segment including a perfluoroalkyl ether, optional Ri independently is a divalent linking segment including a functional group including elements from periodic table Group 13-17, and of Re.sup.1 and Re.sup.2 are phosphonic acid, silanol or carboxylic acid. Lubricant synthesis includes reacting a perfluorinated polyether with a halogenated functional group, selected from phosphonic acid, silanol or carboxylic acid.