Patent classifications
C10M125/22
IMIDAZOLIUM SULFUR-CONTAINING BINUCLEAR MOLYBDATE SALTS AS LUBRICANT ADDITIVES
The present invention relates to a compound of the Formula I:
##STR00001##
and a lubricating composition containing and a method for preparing the same. In Formula I, R.sub.1-R.sub.5 and R.sub.6-R.sub.10 are independently selected from the group consisting of hydrogen, hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from Q.sub.1 and Q.sub.2 is from 6 to 166 carbon atoms, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, and [Mo.sub.2S.sub.10].sup.2.
IMIDAZOLIUM SULFUR-CONTAINING BINUCLEAR MOLYBDATE SALTS AS LUBRICANT ADDITIVES
The present invention relates to a compound of the Formula I:
##STR00001##
and a lubricating composition containing and a method for preparing the same. In Formula I, R.sub.1-R.sub.5 and R.sub.6-R.sub.10 are independently selected from the group consisting of hydrogen, hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from Q.sub.1 and Q.sub.2 is from 6 to 166 carbon atoms, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, and [Mo.sub.2S.sub.10].sup.2.
QUATERNARY AMMONIUM SULFUR-CONTAINING BINUCLEAR MOLYBDATE SALTS AS LUBRICANT ADDITIVES
The present invention relates to lubricating compositions comprising a compound of Formula I:
##STR00001##
wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, [Mo.sub.2S.sub.10].sup.2−, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.
QUATERNARY AMMONIUM SULFUR-CONTAINING BINUCLEAR MOLYBDATE SALTS AS LUBRICANT ADDITIVES
The present invention relates to lubricating compositions comprising a compound of Formula I:
##STR00001##
wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, [Mo.sub.2S.sub.10].sup.2−, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.
SLIDING MEMBER
A sliding member includes a back metal layer and a sliding layer on the back metal layer. The sliding layer includes a synthetic resin matrix and graphite particles dispersed in the matrix in a volume ratio of 5-50% of that of the sliding layer. The graphite particles are composed of spheroidal and flake-like particles. The flake-like particles have a volume ratio of 10-40% of total graphite particles. The spheroidal particles have a cross-sectional structure with a plurality of AB planes of a graphite crystal laminated along a curved particle surface, from the surface toward a center direction. The flake-like graphite particles have a cross-sectional structure with the plurality of AB planes laminated in a thickness direction of the thin plate shape. The spheroidal particles have an average particle size of 3-50 μm, and the flake-like graphite particles have an average particle size of 1-25 μm.
SLIDING MEMBER
A sliding member includes a back metal layer and a sliding layer on the back metal layer. The sliding layer includes a synthetic resin matrix and graphite particles dispersed in the matrix in a volume ratio of 5-50% of that of the sliding layer. The graphite particles are composed of spheroidal and flake-like particles. The flake-like particles have a volume ratio of 10-40% of total graphite particles. The spheroidal particles have a cross-sectional structure with a plurality of AB planes of a graphite crystal laminated along a curved particle surface, from the surface toward a center direction. The flake-like graphite particles have a cross-sectional structure with the plurality of AB planes laminated in a thickness direction of the thin plate shape. The spheroidal particles have an average particle size of 3-50 μm, and the flake-like graphite particles have an average particle size of 1-25 μm.
Lubricating grease composition
A lubricating grease composition for extra heavy duty extreme pressure applications comprises a major amount of a synthetic base oil a lithium complex thickener, at least one extreme pressure agent; and at least 5 wt. % of molybdenum disulfide, based on a total weight of the lubricating grease composition.
Inorganic fullerene-like particles and inorganic tubular-like particles in fluids and lubricants
A lubricant including a fluid medium and at least one intercalation compound of a metal chalcogenide having molecular formula MX.sub.2, where M is a metallic element such as tungsten (W), and X is a chalcogen element such as sulfur (S), wherein the intercalation compound has a fullerene-like hollow structure or tubular-like structure.
Inorganic fullerene-like particles and inorganic tubular-like particles in fluids and lubricants
A lubricant including a fluid medium and at least one intercalation compound of a metal chalcogenide having molecular formula MX.sub.2, where M is a metallic element such as tungsten (W), and X is a chalcogen element such as sulfur (S), wherein the intercalation compound has a fullerene-like hollow structure or tubular-like structure.
Polymeric-inorganic nanoparticle compositions, manufacturing process thereof and their use as lubricant additives
The invention relates to polymeric-inorganic nanoparticle compositions and preparation processes thereof. The invention also relates to an additive and lubricant compositions comprising these polymeric-inorganic nanoparticle compositions, as well as to the use of these polymeric-inorganic nanoparticle compositions in an oil lubricant formulation to improve tribological performance, in particular to improve extreme pressure performance and friction reduction on metal parts.