Provided is a graphene additive, having a viscosity between 1000 and 40000 cps and a grind fineness not greater than 15 μm, and comprising: nano-graphene sheets and a silane coupling agent, wherein a weight ratio of the nano-graphene sheets to the silane coupling agent is 0.1-15:99.9-85, and carbon atoms on a surface of the nano-graphene sheets form chemical bonds Si—O—C with oxygen substituents of the silane coupling agent. The present application further provides a method of preparing the graphene additive.

Provided is a graphene additive, having a viscosity between 1000 and 40000 cps and a grind fineness not greater than 15 μm, and comprising: nano-graphene sheets and a silane coupling agent, wherein a weight ratio of the nano-graphene sheets to the silane coupling agent is 0.1-15:99.9-85, and carbon atoms on a surface of the nano-graphene sheets form chemical bonds Si—O—C with oxygen substituents of the silane coupling agent. The present application further provides a method of preparing the graphene additive.

A lubricating oil composition including a major amount of a base oil, one or more calcium-containing detergents to provide at least 1000 ppmw of calcium, and one or more silicon-containing compound(s) to provide at least 50 ppmw of silicon to the lubricating oil composition, all based on the total weight of the lubricating oil composition, wherein a ratio of ppmw of silicon provided by the one or more silicon-containing compound(s) to the lubricating oil composition to the ppmw of calcium provided by the one or more calcium-containing detergent(s) to the lubricating oil composition is from 0.02 to 1. Methods of using these compositions and silicon-containing detergents are also described.

A lubricating oil composition including a major amount of a base oil, one or more calcium-containing detergents to provide at least 1000 ppmw of calcium, and one or more silicon-containing compound(s) to provide at least 50 ppmw of silicon to the lubricating oil composition, all based on the total weight of the lubricating oil composition, wherein a ratio of ppmw of silicon provided by the one or more silicon-containing compound(s) to the lubricating oil composition to the ppmw of calcium provided by the one or more calcium-containing detergent(s) to the lubricating oil composition is from 0.02 to 1. Methods of using these compositions and silicon-containing detergents are also described.

Compositions for treating a substrate to provide increased lubricity to portions of the substrate surface that come into contact with the surface of a mating component are provided. The treated substrates provide improved lubricity, while maintaining adhesion between the surface of the substrate and an overlying polymer coating and imparting corrosion resistance to the substrate surface. The compositions include a silanol coupling agent in combination with lubricating particles, and an acid, which are dissolved or dispersed in a mixture of organic solvent and water.

Compositions for treating a substrate to provide increased lubricity to portions of the substrate surface that come into contact with the surface of a mating component are provided. The treated substrates provide improved lubricity, while maintaining adhesion between the surface of the substrate and an overlying polymer coating and imparting corrosion resistance to the substrate surface. The compositions include a silanol coupling agent in combination with lubricating particles, and an acid, which are dissolved or dispersed in a mixture of organic solvent and water.

Provided herein is a composition for treating aluminum containing surfaces, wherein the composition includes a reaction product of at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and at least one fatty acid, wherein the molar ratio of the amino group/s of the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and of the at least one fatty acid is 1.2:1 to 1:2, and wherein the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof is linked to the at least one fatty acid by at least one carboxylic acid/amine salt bond and/or at least one amide bond.

Provided herein is a composition for treating aluminum containing surfaces, wherein the composition includes a reaction product of at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and at least one fatty acid, wherein the molar ratio of the amino group/s of the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and of the at least one fatty acid is 1.2:1 to 1:2, and wherein the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof is linked to the at least one fatty acid by at least one carboxylic acid/amine salt bond and/or at least one amide bond.

A composition treating a metal surface, especially a metalworking fluid, includes the reaction product of at least one amine-functionalized organosilane and at least one organophosphate and/or at least one oligomer or polymer of the reaction product, wherein the molar ratio of the amino group/s of the at least one amine-functionalized and of the at least one organophosphate is 1.0:0.4 to 1.0:1.2, and wherein the at least one amine-functionalized organosilane is linked to the at least one organophosphate by at least one phosphoric acid/amine salt bond. Also described herein is method for producing such a composition, the use of the composition, and a method for treating a metal surface.

A composition treating a metal surface, especially a metalworking fluid, includes the reaction product of at least one amine-functionalized organosilane and at least one organophosphate and/or at least one oligomer or polymer of the reaction product, wherein the molar ratio of the amino group/s of the at least one amine-functionalized and of the at least one organophosphate is 1.0:0.4 to 1.0:1.2, and wherein the at least one amine-functionalized organosilane is linked to the at least one organophosphate by at least one phosphoric acid/amine salt bond. Also described herein is method for producing such a composition, the use of the composition, and a method for treating a metal surface.