With the present invention, sustainable systems for corrosion, inhibition in the processing of metals (in particular iron, aluminum and magnesium) are made available. These systems being in full accordance with the principles of green chemistry comprise an amino acid as neutralizing component for an acidic corrosion inhibitor, whereby the amino acid is used in deprotonated form. The resulting metalworking fluids may be water- or oil-based or semi synthetic formulations. The neutralization of acidic corrosion inhibitors with the claimed system comprising an amino acid consistently achieves convincing results and, together with acidic corrosion inhibitors from corresponding sources, completely renewable systems for corrosion inhibition are provided.

Embodiments of the present disclosure directed towards synthetic lubricant compositions. In various embodiments, the present disclosure provides a synthetic lubricant compositions including an aromatic amine antioxidant comprising 0.25 to 5 weight percent of a total weight of the synthetic lubricant composition, dithiocarbamate antioxidant comprising 0.25 to 5 weight percent of the total weight of the synthetic lubricant composition, and a polyalkylene glycol PAG comprising 99.25 to 85 weight percent of the total weight of the synthetic lubricant composition, where the synthetic lubricant composition has a total acidic number (TAN) increase of 2 milligrams of potassium hydroxide per gram of the synthetic lubricant composition over 27 days or greater as measured in accordance with modified ASTM D-664, and where the synthetic lubricant composition does not include any of a Group I, II, III, IV base oil.

The present disclosure describes lubricant compositions effective to minimize average engine sludge through selection of lubricant additives that control the total nitrogen as well as the origin of the nitrogen in the lubricant composition. In aspects, the lubricant compositions herein include at least a base oil of lubricating viscosity, a dispersant system, and at least one antioxidant.

A grease composition which contains a base oil (A), a urea-based thickener (B), a sarcosine derivative (C), and a fatty acid zinc salt (D), wherein particles containing the urea-based thickener (B) in the grease composition satisfies Requirement (I). The base oil (A) is a blended base oil containing a high viscosity hydrocarbon-based synthetic oil having a specific kinematic viscosity (A1). A low viscosity hydrocarbon-based synthetic oil having a specific kinematic viscosity (A2). An ultra-high viscosity hydrocarbon-based synthetic oil has a number average molecular weight (Mn) of 2,500 to 4,500 and a specific kinematic viscosity (A3). A 40° C. kinematic viscosity of the base oil (A) is 500 mm.sup.2/s to 1,500 mm.sup.2/s. A viscosity index of the base oil (A) is 140 or more. A content of the fatty acid zinc salt (D) is 10 mass % to 20 mass % based on a total amount of the grease composition.

A grease composition which contains a base oil (A), a urea-based thickener (B), a sarcosine derivative (C), and a fatty acid zinc salt (D), wherein particles containing the urea-based thickener (B) in the grease composition satisfies Requirement (I). The base oil (A) is a blended base oil containing a high viscosity hydrocarbon-based synthetic oil having a specific kinematic viscosity (A1). A low viscosity hydrocarbon-based synthetic oil having a specific kinematic viscosity (A2). An ultra-high viscosity hydrocarbon-based synthetic oil has a number average molecular weight (Mn) of 2,500 to 4,500 and a specific kinematic viscosity (A3). A 40° C. kinematic viscosity of the base oil (A) is 500 mm.sup.2/s to 1,500 mm.sup.2/s. A viscosity index of the base oil (A) is 140 or more. A content of the fatty acid zinc salt (D) is 10 mass % to 20 mass % based on a total amount of the grease composition.

A lubricating oil composition may be capable of satisfactorily exhibiting sludge prevention properties and wear resistance evaluated by scoring resistance and seizure resistance over a long period of time. Such a lubricating oil composition may contain: a base oil (A); a hindered phenol-based antioxidant (B); one or more imide compounds (C) selected from the group consisting of a monoimide compound (C1) and a bisimide compound (C2); and an extreme pressure agent (D), in which the hindered phenol-based antioxidant (B) is 2,6-di-tert-butylphenol, the monoimide compound (C1) is one or more selected from the group consisting of an alkenyl succinic monoimide compound and an alkyl succinic monoimide compound, and the bisimide compound (C2) is one or more selected from the group consisting of an alkenyl succinic bisimide compound and an alkyl succinic bisimide compound.

The present invention provides a water-glycol hydraulic fluid composition comprising an alkanolamine compound according to the general formula (1), wherein the water-glycol hydraulic fluid composition comprises 20-60% by mass water, 20-60% by mass glycol, 0.6-1.2% by mass fatty acid lubricant, and 0.01-0.06% by mass alkaline hydroxide compound selected from potassium hydroxide and/or sodium hydroxide, and has an alkali reserve of 10-25, wherein R.sub.1 and R.sub.2 are hydrocarbon groups having from 1 to 8 carbon atoms, and R.sub.3 is a hydrocarbon group having 2 or more carbon atoms.

##STR00001##

The present invention provides a water-glycol hydraulic fluid composition comprising an alkanolamine compound according to the general formula (1), wherein the water-glycol hydraulic fluid composition comprises 20-60% by mass water, 20-60% by mass glycol, 0.6-1.2% by mass fatty acid lubricant, and 0.01-0.06% by mass alkaline hydroxide compound selected from potassium hydroxide and/or sodium hydroxide, and has an alkali reserve of 10-25, wherein R.sub.1 and R.sub.2 are hydrocarbon groups having from 1 to 8 carbon atoms, and R.sub.3 is a hydrocarbon group having 2 or more carbon atoms.

##STR00001##

The lubricating oil composition according to the present invention is one including a base oil, (A) a substituted hydroxy aromatic carboxylic acid ester derivative represented by at least one of the general formula (I) and the general formula (II), and (B) a heterocyclic compound represented by the general formula (III) or (IV) blended therein, wherein a phosphorus content is 0.06 mass % or less on the basis of a total amount of the composition, and a sulfated ash content is 1.2 mass % or less on the basis of a total amount of the composition. The lubricating oil composition is capable of maintaining high-temperature detergency and acid neutralizing properties, even when amounts of a phosphorus component-containing additive and a metallic detergent are reduced.

The lubricating oil composition according to the present invention is one including a base oil, (A) a substituted hydroxy aromatic carboxylic acid ester derivative represented by at least one of the general formula (I) and the general formula (II), and (B) a heterocyclic compound represented by the general formula (III) or (IV) blended therein, wherein a phosphorus content is 0.06 mass % or less on the basis of a total amount of the composition, and a sulfated ash content is 1.2 mass % or less on the basis of a total amount of the composition. The lubricating oil composition is capable of maintaining high-temperature detergency and acid neutralizing properties, even when amounts of a phosphorus component-containing additive and a metallic detergent are reduced.