There is disclosed an antifoam component for a mechanical device which includes a poly(acrylate) copolymer. The antifoam component has improved foam performance in finished fluids utilizing dibutyl hydrogen phosphite compounds, such as driveline fluids. A lubricating composition comprising a) at least one oil of lubricating viscosity; and b) an antifoam component comprising a poly(acrylate) copolymer. The poly(acrylate) copolymer, b) may include (i) from about 30 wt % up to about 99 wt % of a (meth)acrylate monomer having C.sub.1 to C.sub.4 alkyl esters of (meth)acrylic acid; and (ii) from about 1 wt % up to about 70 wt % of a fluorinated (meth)acrylate monomer.

There is disclosed an antifoam component for a mechanical device which includes a poly(acrylate) copolymer. The antifoam component has improved foam performance in finished fluids utilizing dibutyl hydrogen phosphite compounds, such as driveline fluids. A lubricating composition comprising a) at least one oil of lubricating viscosity; and b) an antifoam component comprising a poly(acrylate) copolymer. The poly(acrylate) copolymer, b) may include (i) from about 30 wt % up to about 99 wt % of a (meth)acrylate monomer having C.sub.1 to C.sub.4 alkyl esters of (meth)acrylic acid; and (ii) from about 1 wt % up to about 70 wt % of a fluorinated (meth)acrylate monomer.

The object of the present invention is to provide a foreign substance removing lubricant composition having high foreign substance removing effects and being capable of improving the lubricating properties as compared to conventional lubricant compositions, a foreign substance removing lubricant composition applied member, and a method for using the foreign substance removing lubricant composition. The foreign substance removing lubricant composition of the present invention comprises a perfluoroalkyl group containing compound (S) having a perfluoroalkyl group or a fluoropolyether containing compound. As a result, foreign substance removing effects can be enhanced, and the lubricating properties can be improved as compared to the conventional lubricant compositions.

The object of the present invention is to provide a foreign substance removing lubricant composition having high foreign substance removing effects and being capable of improving the lubricating properties as compared to conventional lubricant compositions, a foreign substance removing lubricant composition applied member, and a method for using the foreign substance removing lubricant composition. The foreign substance removing lubricant composition of the present invention comprises a perfluoroalkyl group containing compound (S) having a perfluoroalkyl group or a fluoropolyether containing compound. As a result, foreign substance removing effects can be enhanced, and the lubricating properties can be improved as compared to the conventional lubricant compositions.

A fluorine-containing ether compound of the present invention is represented by Formula (1).
R.sup.1CH.sub.2R.sup.2CH.sub.2R.sup.3(1) (In Formula (1), R.sup.1 is an organic end group having 3 or more carbon atoms which includes two or more polar groups with each polar group being bonded to different carbon atoms and the carbon atoms to which the polar groups are bonded being bonded to each other via a linking group including the carbon atoms which are not bonded to the polar groups, R.sup.2 includes a perfluoropolyether chain represented by Formula (3), and R.sup.3 is a hydroxyl group or R.sup.1)
(CF.sub.2).sub.y1O((CF.sub.2).sub.yO).sub.z(CF.sub.2).sub.y1(3) (In Formula (3), y represents an integer of 2 to 4, and z represents an integer of 1 to 30).

A fluorine-containing ether compound of the present invention is represented by Formula (1).
R.sup.1CH.sub.2R.sup.2CH.sub.2R.sup.3(1) (In Formula (1), R.sup.1 is an organic end group having 3 or more carbon atoms which includes two or more polar groups with each polar group being bonded to different carbon atoms and the carbon atoms to which the polar groups are bonded being bonded to each other via a linking group including the carbon atoms which are not bonded to the polar groups, R.sup.2 includes a perfluoropolyether chain represented by Formula (3), and R.sup.3 is a hydroxyl group or R.sup.1)
(CF.sub.2).sub.y1O((CF.sub.2).sub.yO).sub.z(CF.sub.2).sub.y1(3) (In Formula (3), y represents an integer of 2 to 4, and z represents an integer of 1 to 30).

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m.sup.2 to about 50 mJ/m.sup.2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (,)-hydroxyl-terminated and/or (,)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH.sub.2CH.sub.2O)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2(OCH.sub.2CH.sub.2).sub.p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m.sup.2 to about 50 mJ/m.sup.2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (,)-hydroxyl-terminated and/or (,)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH.sub.2CH.sub.2O)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2(OCH.sub.2CH.sub.2).sub.p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m.sup.2 to about 50 mJ/m.sup.2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (,)-hydroxyl-terminated and/or (,)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH.sub.2CH.sub.2O)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2(OCH.sub.2CH.sub.2).sub.p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m.sup.2 to about 50 mJ/m.sup.2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (,)-hydroxyl-terminated and/or (,)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH.sub.2CH.sub.2O)CH.sub.2CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2CH.sub.2(OCH.sub.2CH.sub.2).sub.p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.