An embodiment of the present invention relates to a paste which includes a perfluoropolyether (A) having two or more ethylenically unsaturated bonds in the molecule, a polysiloxane (B) having two or more ethylenically unsaturated bonds in the molecule, and a radical initiator (C).

A copolymer includes 20 mol % to 80 mol % of —CF.sub.2CF.sub.2O— units, 20 mol % to 80 mol % of —CF(CF.sub.3)CF.sub.2O— units, and 0 mol % to 45 mol % of one or more additional perfluoroalkyleneoxy units. The copolymer has a molecular weight M.sub.n of 1,500 to 20,000, a viscosity index of 100 to 220, and an average tetrafluoroethylene oxide (TFEO) run length less than 6. A process of forming a perfluoroalkyl polyether copolymer includes feeding a gas stream containing TFEO and hexafluoropropylene oxide (HFPO) into a reactor containing a fluorinated solvent, a fluoride salt, an ether, and an acid fluoride to form an acid fluoride-containing polymer. The process also includes hydrolyzing the acid fluoride-containing polymer to form a perfluoroalkyl polyether carboxylic acid or carboxylate salt. The process further includes distilling off the fluorinated solvent and treating the perfluoroalkyl polyether carboxylic acid or carboxylate salt with elemental fluorine to obtain the perfluoroalkyl polyether copolymer.

The fluorine-containing ether compound is represented by the following formula (1): R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4. In the formula (1), R.sup.1 is represented by the following formula (2), R.sup.2 is represented by the following formula (3), R.sup.3 is a perfluoropolyether chain, and R.sup.4 is an organic end group different from R.sup.1—R.sup.2— and contains two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to one another via a linking group containing a carbon atom to which the polar group is not bonded. In the formula (2), R.sup.5 is an alkoxy group selected from the group consisting of a methoxy, an ethoxy and a propoxy group. In the formula (3), w is 2 or 3.

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A lubrication method comprising applying to a surface to be lubricated a polymer comprising a partially or fully fluorinated, straight or branched, polyoxyalkylene chain (chain R.sub.f) having two chain ends, wherein one or both chain end(s) bear(s) a hydroxy- or alkoxy-terminated polyoxyalkylene chain free from fluorine atoms (chain R.sub.a), said chain comprising from 4 to 50 fluorine-free oxyalkylene units, said units being the same or different from one another and being selected from —CH.sub.2CH.sub.2O— and —CH.sub.2CH(J)O—, wherein J is independently straight or branched alkyl or aryl, with the proviso that, if both chain ends bear a hydroxy-terminated chain Ra comprising only —CH.sub.2CH.sub.2O— units, chain Rf does not consist only of —CF.sub.2CF.sub.2O-units. Lubricant compositions containing the polymer and methods for preparing the polymer are also herein disclosed.

A lubrication method comprising applying to a surface to be lubricated a polymer comprising a partially or fully fluorinated, straight or branched, polyoxyalkylene chain (chain R.sub.f) having two chain ends, wherein one or both chain end(s) bear(s) a hydroxy- or alkoxy-terminated polyoxyalkylene chain free from fluorine atoms (chain R.sub.a), said chain comprising from 4 to 50 fluorine-free oxyalkylene units, said units being the same or different from one another and being selected from —CH.sub.2CH.sub.2O— and —CH.sub.2CH(J)O—, wherein J is independently straight or branched alkyl or aryl, with the proviso that, if both chain ends bear a hydroxy-terminated chain Ra comprising only —CH.sub.2CH.sub.2O— units, chain Rf does not consist only of —CF.sub.2CF.sub.2O-units. Lubricant compositions containing the polymer and methods for preparing the polymer are also herein disclosed.

The invention relates to polymeric-inorganic nanoparticle compositions and preparation processes thereof. The invention also relates to an additive and lubricant compositions comprising these polymeric-inorganic nanoparticle compositions, as well as to the use of these polymeric-inorganic nanoparticle compositions in an oil lubricant formulation to improve tribological performance, in particular to improve extreme pressure performance and friction reduction on metal parts.

The invention relates to polymeric-inorganic nanoparticle compositions and preparation processes thereof. The invention also relates to an additive and lubricant compositions comprising these polymeric-inorganic nanoparticle compositions, as well as to the use of these polymeric-inorganic nanoparticle compositions in an oil lubricant formulation to improve tribological performance, in particular to improve extreme pressure performance and friction reduction on metal parts.

The invention provides a lubricating composition comprising an oil of lubricating viscosity and synergistic mixture of a functionalized ethylene-α-olefin copolymer, a poly(meth)acrylate block polymer having a substantially oil soluble block and a substantially oil insoluble block. The invention also provides a method of lubricating a mechanical device using such a lubricating composition.

A multidentate lubricant comprising an anchoring moiety Ra attached to a plurality of sidechain moieties —(Rb—Re) according to the general formula: Ra—(Rb—Re).sub.x; wherein Ra is a multivalent radical of valance x; and each sidechain includes a perfluoroethyl ether moiety. The lubricant can be used in conjunction with a magnetic recording medium and/or a magnetic data storage system.

There is disclosed an antifoam component for a mechanical device which includes a poly(acrylate) copolymer. The antifoam component has improved foam performance in finished fluids utilizing dibutyl hydrogen phosphite compounds, such as driveline fluids. A lubricating composition comprising a) at least one oil of lubricating viscosity; and b) an antifoam component comprising a poly(acrylate) copolymer. The poly(acrylate) copolymer, b) may include (i) from about 30 wt % up to about 99 wt % of a (meth)acrylate monomer having C.sub.1 to C.sub.4 alkyl esters of (meth)acrylic acid; and (ii) from about 1 wt % up to about 70 wt % of a fluorinated (meth)acrylate monomer.