The present invention provides a lubricant material for assisting machining process comprising a high molecular weight compound (A) having a weight average molecular weight of 5?10.sup.4 or higher and 1?10.sup.6 or lower, a medium molecular weight compound (B) having a weight average molecular weight of 1?10.sup.3 or higher and lower than 5?10.sup.4, and a carbon (C) having an average particle size of 100 ?m or larger.

The disclosure provides a fluoropolyether compound represented by formula (1):
R.sup.1CH.sub.2R.sup.2CH.sub.2R.sup.3
wherein R.sup.1 is C.sub.1-C.sub.10 alkoxy; R.sup.2 is (CF.sub.2).sub.pO(CF.sub.2O).sub.x(CF.sub.2CF.sub.2O).sub.y(CF.sub.2CF.sub.2CF.sub.2O).sub.z(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.w(CF.sub.2).sub.p; x and y are each a real number of 0 to 30; z is a real number of 0 to 30; w is a real number of 0 to 20; p is an integer of 1 to 3; R.sup.3 is OCH.sub.2CH(OH)CH.sub.2OH, OCH.sub.2CH(OH)CH.sub.2OCH.sub.2CH(OH)CH.sub.2OH, O(CH.sub.2).sub.mOH, or OCH.sub.2(OH)CHCH.sub.2OC.sub.6H.sub.4R.sup.4; m is an integer of 2 to 8; and R.sup.4 is hydrogen, C.sub.1-C.sub.4 alkoxy, amino, or an amide residue; and also provides a lubricant having the compound and a magnetic disk.

A fluorine-containing ether monocarboxylic acid aminoalkyl ester represented by the general formula:
C.sub.nF.sub.2n+1O[CF(CF.sub.3)CF.sub.2O].sub.aCF(CF.sub.3)COO(CH.sub.2).sub.bNR.sup.1R.sup.2
(wherein R.sup.1 is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an aryl group, or an aralkyl group, preferably an alkyl group having 1 to 6 carbon atoms or an aryl group; R.sup.2 is an alkyl group having 1 to 12 carbon atoms, an aryl group, or an aralkyl group, preferably an alkyl group having 1 to 6 carbon atoms or an aryl group; n is an integer of 1 to 3; a is an integer of 2 to 20, preferably an integer of 4 to 10; and b is an integer of 1 to 12, preferably an integer of 1 to 3). Such a fluorine-containing ether monocarboxylic acid ester having an amino group at the end of the ester group is produced by reacting a perfluoroether carboxylic acid fluoride compound C.sub.nF.sub.2n+1O[CF(CF.sub.3)CF.sub.2O].sub.aCF(CF.sub.3)COF and a hydroxyalkyl amine compound HO(CH.sub.2).sub.bNR.sup.1R.sup.2 in the presence of an alkali metal fluoride.

A fluorine-containing ether monocarboxylic acid aminoalkyl ester represented by the general formula:

C.sub.nF.sub.2n+1O[CF(CF.sub.3)CF.sub.2O].sub.aCF(CF.sub.3)COO(CH.sub.2).sub.bNR.sup.1R.sup.2

(wherein R.sup.1 is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an aryl group, or an aralkyl group, preferably an alkyl group having 1to 6 carbon atoms or an aryl group; R.sup.2 is an alkyl group having 1 to 12 carbon atoms, an aryl group, or an aralkyl group, preferably an alkyl group having 1to 6 carbon atoms or an aryl group; n is an integer of 1 to 3; a is an integer of 2 to 20, preferably an integer of 4 to 10; and b is an integer of 1 to 12, preferably an integer of 1 to 3). Such a fluorine-containing ether monocarboxylic acid ester having an amino group at the end of the ester group is produced by reacting a perfluoroether carboxylic acid fluoride compound C.sub.nF.sub.2n+1O[CF(CF.sub.3)CF.sub.2O].sub.1CF(CF.sub.3)COF and a hydroxyalkyl amine compound HO(CH.sub.2).sub.bNR.sup.1R.sup.2 in the presence of an alkali metal fluoride.

[Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).

The disclosure provides a fluoropolyether compound represented by formula (1):

R.sup.1CH.sub.2R.sup.2CH.sub.2R.sup.3

wherein R.sup.1 is C.sub.1-C.sub.10 alkoxy; R.sup.2 is (CF.sub.2).sub.pO(CF.sub.2O).sub.x(CF.sub.2CF.sub.2O).sub.y(CF.sub.2CF.sub.2CF.sub.2O).sub.z(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.w(CF.sub.2).sub.p; x and y are each a real number of 0 to 30; z is a real number of 0 to 30; w is a real number of 0 to 20; p is an integer of 1 to 3; R.sup.3 is OCH.sub.2CH(OH)CH.sub.2OH, OCH.sub.2CH(OH)CH.sub.2OCH.sub.2CH(OH)CH.sub.2OH, O(CH.sub.2).sub.mOH, or OCH.sub.2(OH)CHCH.sub.2OC.sub.6H.sub.4R.sup.4; m is an integer of 2 to 8; and R.sup.4 is hydrogen, C.sub.1-C.sub.4 alkoxy, amino, or an amide residue; and also provides a lubricant having the compound and a magnetic disk.

To provide a fluorinated polyether compound capable of forming a film excellent in lubricity, a lubricant and a liquid composition, as well as an article having a film excellent in lubricity, on a substrate. A fluorinated polyether compound represented by {XO[(CF.sub.2CF.sub.2O).sub.a(CF.sub.2CF.sub.2CF.sub.2CF.sub.2O).sub.b]}.sub.mY{[(OCF.sub.2CF.sub.2).sub.c(OCF.sub.2CF.sub.2CF.sub.2CF.sub.2).sub.d]OZ}.sub.n is used. X is a group having a hydroxy group, a carboxy group, an ester group or an aryl group, Y is an (m+n) valent linking group, Z is a group having a haloalkyl group, each of m and n is an integer of from 1 to 10, m+n is an integer of from 2 to 20, and each of a, b, c and d is an integer of from 1 to 100.

Hydrogenated polymers with a radial structure having a core made up of calixarenes of the general formula (I), to the core of which is linked a number P of hydrogenated linear polymer segments selected from: hydrogenated homopolymers or copolymers of conjugated dienes; or hydrogenated copolymers of said conjugated dienes and monoalkenyl arenes, and mixtures thereof said formula (I) in which: R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from hydrogen; a group containing carbon and hydrogen; a group also containing heteroatoms in addition to carbon and hydrogen; a group also containing silicon in addition to carbon, hydrogen and heteroatoms; one of the two substituents R.sub.5 and R.sub.6 is hydrogen, while the other may be hydrogen or alkyl, with a number of carbon atoms between 1 and 6, preferably methyl and ethyl; n is an integer in the range between 4 and 16.

##STR00001##

Hydrogenated polymers with a radial structure having a core made up of calixarenes of the general formula (I), to the core of which is linked a number P of hydrogenated linear polymer segments selected from: hydrogenated homopolymers or copolymers of conjugated dienes; or hydrogenated copolymers of said conjugated dienes and monoalkenyl arenes, and mixtures thereof said formula (I) in which: R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from hydrogen; a group containing carbon and hydrogen; a group also containing heteroatoms in addition to carbon and hydrogen; a group also containing silicon in addition to carbon, hydrogen and heteroatoms; one of the two substituents R.sub.5 and R.sub.6 is hydrogen, while the other may be hydrogen or alkyl, with a number of carbon atoms between 1 and 6, preferably methyl and ethyl; n is an integer in the range between 4 and 16.

##STR00001##

The invention concerns a threaded tubular component for drilling or working hydrocarbon wells, said tubular component having at one of its ends (1; 2) a threaded zone (3; 4) produced on its outer or inner peripheral surface depending on whether the threaded end is male or female in type, characterized in that at least a portion of the end (1; 2) is coated with a lubricating dry film (12) the matrix (13) of which comprises at least one migrating sliding agent (9) belonging to the oils or waxes family and principally distributed at the surface of the lubricating dry film (12) such that the coefficient of friction of the film (12) is less than 0.07 at loads of less than 40 N while the coefficient of friction of the film (12) is more than 0.1 at loads of more than 200 N.