A refrigerator oil composition with a base oil (A), and a first phosphorus compound (B). The first phosphorus compound (B) is a first phosphite ester (B1) represented by formula (1) and a second phosphite ester (B2) represented by formula (2):

(R.sup.11—O—).sub.n—PO—R.sup.12).sub.3-n   (1)

##STR00001##

A method of producing a refrigerator oil composition by mixing a base oil (A) with a first phosphorus compound (B). A refrigerator mixture composition includes the refrigerator oil composition and a refrigerant.

The present disclosure describes lubricant compositions effective to minimize average engine sludge through selection of lubricant additives that control the total nitrogen as well as the origin of the nitrogen in the lubricant composition. In aspects, the lubricant compositions herein include at least a base oil of lubricating viscosity, a dispersant system, and at least one antioxidant.

An ionic liquid comprising: a cation (or conjugate acid), wherein the cation (or conjugate acid) is represented by General Formula (A) below or General Formula (B) below or General Formula (C) or General Formula (D) below or General Formula (E) below: ##STR00001## wherein R.sub.1 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7, or an alkyl chain CH.sub.3, or CH.sub.2OH, or CH.sub.2CH.sub.2OH; R.sub.2 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7, or a hydrogen atom H, or CH.sub.2OH, or CH.sub.2CH.sub.2OH; and R.sub.3 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7.

A lubricating oil composition including a base oil (X) having a tertiary carbon atom at a content of 8.0 at % or more based on the total carbon of hydrocarbons and an antioxidant (Y) having an amine-based antioxidant (A), a phenol-based antioxidant (B), and a phosphor-based antioxidant (C). The amine-based antioxidant (A) includes a diphenylamine compound (A1) represented by the following general formula (a1):

##STR00001##

where R.sup.a1 and R.sup.a2, na1 and na2 are defined in the disclosure.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I): ##STR00001##
wherein each instance of R.sup.1 is independently ##STR00002##
wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is ##STR00003##
of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

An additive composition for limiting the chemical degradation of hydrocarbonaceous liquids due to nitrogen dioxide contamination at elevated temperature comprises the combination of an ionic liquid composed of a cation and a boron- and halogen-free, multi-functional anion and a detergent additive, the combination of ionic liquid and detergent serving to inhibit the nitration of hydrocarbonaceous liquid components that initiates degradation.

An ionic liquid composed of nitrogen-free cations and aromatic halogen- and boron-free anions is useful as an additive to prolong the service life of hydrocarbonaceous liquids exposed to nitrogen dioxide contamination, and to provide friction and wear reduction.

The disclosed technology relates to lubricants for compression ignition internal combustion engines, particularly those demonstrating at least one of improved seals performance, reduced deposit formation, and excellent durability. The present invention provides a low zinc lubricating composition comprising (a) an oil of lubricating viscosity, (b) a borated dispersant, and (c) a metal-free organo-phosphorus anti-wear additive, wherein the lubricating composition is substantially free of a metal containing sulfur coupled alkyl phenol compound. Further, the low zinc lubricating composition contains zinc in an amount less than 600 ppm by weight of the composition.

Lubricating composition comprising (i) base oil and (ii) a metal-free phosphonate compound having the general formula P(═O)(R.sup.1)(OR.sup.2)(OR.sup.3) wherein R.sup.1, R.sup.2 and R.sup.3 are the same or different and each independently selected from a straight chain or branched, saturated or unsaturated, C.sub.4-C.sub.22 alkyl group. The lubricating composition of the present invention provides improved engine durability, improved wear and friction reduction, improved fuel economy and excellent oxidative stability.

The present invention relates to a lubricant composition, and more particularly to a lubricant composition, which includes an ethylene-alphaolefin oligomer and an alkylated phosphonium compound, thus realizing energy reduction and an increased endurance life, and which is thus suitable for use in gear oil. The lubricant composition of the present invention includes a base oil, a liquid olefin copolymer, and an alkylated phosphonium compound.