Disclosed is a method of lubrication including a step of lubricating a machine with a lubricating composition, the lubricating composition including 20-100% ionic liquid or of a mixture of several ionic liquids. The ionic liquid or the mixture is selected from at least: an anion A.sup.− chosen from sulfonylimides, the substituent(s) of which is (are) independently chosen from a fluoroalkyl, fluoroether, perfluorinated alkyl or perfluoroether group; and a cation C.sup.+ including a nitrogen-containing heterocycle or a quaternary ammonium, the substituent(s) of which is (are) independently chosen from: a hydrogen atom or alkyl, alkoxy, fluorinated alkyl, perfluorinated alkyl, alkylsilane, alkyl alcohol, vinyl, alkyl allyl, ether or polyether groups having a linear or branched chain having 1-3 carbon atoms. The deposition start temperature in thin film of the ionic liquid or of the mixture of ionic liquids is at least equal to 330° C. The lubricating composition reduces deposits formed in the machine.

The invention relates to a food-grade high-temperature lubricant, more particularly a high-temperature oil and a high-temperature grease, comprising the following components: a) at least one oil selected from a trimellitic ester or a mixture of different trimellitic esters, alkylaromatics, preferably an aliphatically substituted naphthalene, or estolides; b) a hydrogenated or fully hydrogenated polyisobutylene or a mixture of hydrogenated or fully hydrogenated polyisobutylene; and c) additives individually or in combination.

In the case of the high-temperature grease, a thickener is added.

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, calcium, nitrogen, molybdenum and boron. The weight ratio of Ca:N (ppm/ppm) in the lubricating oil composition is greater than 1.3 to less than 3.0, the weight ratio of Ca:Mo (ppm/ppm) in the lubricating oil composition is greater than 6.7 to less than 56.3, and the weight ratio of Ca:B (ppm/ppm) in the lubricating oil composition is greater than 5.0 to less than 9.8. The lubricating oil composition does not contain added magnesium from a magnesium-containing detergent. The lubricating oil composition is resistant to deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors dexos1® Turbocharger Coking Test.

The present invention provides a process for preparing a polymer, employing the steps of: (1) contacting a free radical initiator; a chain transfer agent containing a thiocarbonyl thio group and a free radical leaving group; and a radically polymerizable monomer, to form a polymer chain; and (2) contacting the polymer chain of step (1) with at least one of a polyvalent coupling agent, a polymerization inhibitor, a grafting acylating agent, an amine and an oil of lubricating viscosity. The invention further provides compositions and uses for the polymer.

A quaternary ammonium compound of formula (I): ##STR00001##
wherein R.sup.0, R.sup.1, R.sup.2 and R.sup.3 is each independently an optionally substituted hydrocarbyl group, X is a linking group, R.sup.4 is an optionally substituted alkylene group, R.sup.5 is hydrogen or an optionally substituted alkyl, alkenyl or aryl group, and n is 0 or a positive integer, provided that n is not 0 when R.sup.5 is hydrogen.

Use of a guanidinium-based ionic liquid as detergent in a lubricant composition, notably for lubricating marine engines. A lubricant composition including a guanidinium-based ionic liquid.

Provided is a lubricating oil composition containing a base oil (A) and an amine-based antioxidant (B), wherein the component (B) contains a phenyl-naphthylamine (B1), an alkylphenyl-naphthylamine (B2) and a di(alkylphenyl)amine (B3), the content of the component (B1) is 2.0 to 10.0% by mass relative to 100% by mass of the total amount of the component (B), the content of the component (B2) is 40.0 to 90.0% by mass relative to 100% by mass of the total amount of the component (B), and the content of the component (B3) is 8.0 to 50.0% by mass relative to 100% by mass of the total amount of the component (B). The lubricating oil composition maintains excellent oxidation stability even in long-term use in high-temperature environments, and has an excellent lifetime and is excellent also in a sludge preventing effect.

A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c):
—N(COR.sup.1)(CH.sub.2).sub.x—  (a)
—NH(CH.sub.2).sub.y—  (b)
—N(CH.sub.2CH.sub.2-k(CH.sub.3).sub.kCOOR.sup.2)(CH.sub.2).sub.z   (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.

A lubricating oil composition including: a lubricant base oil; (A) a calcium salicylate detergent in an amount of 0.005 to 0.03 mass % in terms of calcium on the basis of the total mass of the composition; and (B) a phosphite ester compound represented by the following general formula (1) in an amount of 0.01 to 0.06 mass % in terms of phosphorus on the basis of the total mass of the composition:

##STR00001##

wherein in the general formula (1), R.sup.1 and R.sup.2 are each independently a C5-20 group represented by the following general formula (2):

##STR00002##

wherein in the general formula (2), R.sup.3 is a C2-17 linear chain hydrocarbon group, and R.sup.4 is a C3-17 linear chain hydrocarbon group, and X.sup.1 is an oxygen atom or a sulfur atom.

The invention relates to polymeric-inorganic nanoparticle compositions and preparation processes thereof. The invention also relates to an additive and lubricant compositions comprising these polymeric-inorganic nanoparticle compositions, as well as to the use of these polymeric-inorganic nanoparticle compositions in an oil lubricant formulation to improve tribological performance, in particular to improve extreme pressure performance and friction reduction on metal parts.