An organometallic chemistry-based compound for preventing coke formation in a hydrocarbon fluid system. The organometallic chemistry-based compound includes a coordination complex that interrupts an autoxidative pathway of coke formation. A component and a system for mitigating coke formation during delivery or circulation of a hydrocarbon fluid. The component includes a contact surface configured to be in contact with the hydrocarbon fluid. The contact surface is functionalized with an inhibitor ligand to form an inhibitor ligand-functionalized surface. The inhibitor ligand-functionalized surface interrupts an autoxidative pathway of coke formation.

The present invention relates to a lubricant composition, in particular for a gas or steam turbine, comprising: at least one base oil; at least one phenylnaphthylamine (PAN) compound, preferably alkylphenyl--naphthylamine (APAN) compound; at least one diphenylamine (DPA) compound, preferably dialkyl-diphenylamine compound; and at least one phosphite ester compound, preferably triaryl phosphite ester compound; in which the ratio by weight between said diphenylamine compound(s) and said phosphite ester compound(s) is strictly greater than 1.0.

Disclosed are solvency enhancer compositions, for example, as additives to lubricating oils and as formulated in lubricating oil compositions and associated methods of preparation and use thereof. The compositions and methods can dissolve at least one of oxidation products and other organic polar compounds, due to lubricant degradation, formed and suspended in oil compositions including adding an effective amount of a solvency enhancer to the oils, wherein the solvency enhancer includes Guerbet alcohols. Further described are methods for dissolving organic deposits in an oil system including adding an effective amount of a solvency enhancer to the oil system, wherein the solvency enhancer includes Guerbet alcohols. Also provided are methods for preventing sludge and varnish formation in in-service oils including adding an effective amount of a solvency enhancer to the oils, wherein the solvency enhancer includes Guerbet alcohols.