The use of nanoparticles of a metal melting below 400° C., preferably bismuth, dispersed in a lubricant for providing a low coefficient of friction coating to interacting surfaces of machinery, such as a powertrain of a motor vehicle.

Provided is a one-pack type ultraviolet-thickable thermally conductive silicone grease composition which, at the initial stage, has a low viscosity (is easy to apply) but has high shape retentivity and which, after curing, is pliable (has low hardness). The ultraviolet-thickable thermally conductive silicone grease composition comprises, as essential components, (A) an organopolysiloxane having a viscosity at 25° C. of 50-100,000 mPa.Math.s and containing at least one alkenyl group in the molecule, (B) a liquid organohydrogenpolysiloxane which has a viscosity at 25° C. of 100 mPa.Math.s or less, contains 2-10 silicon-atom-bonded hydrogen atoms in the molecule and contains at least one alkoxy and/or epoxy group bonded to a silicon atom through an alkylene group and in which the polysiloxane has a degree of polymerization of 15 or less and the skeleton of the polysiloxane includes a cyclic structure, (C) a photoactivable platinum complex curing catalyst, and (D) a thermally conductive filler having a thermal conductivity of 10 W/m.Math.° C. or greater.

A method for producing a lubricant in producing an overbased calcium sulfonate, which is converted from the vaterite form into the calcite form and, finally, a calcium sulfonate grease is produced by heating the mixture. A lubricant may comprise at least one ester composition, calcium carbonate and at least one overbased alkylbenzene sulfonate. The basicity of the mixture is limited during the preparation of the overbased calcium sulfonate to a TBN of at most 550 mg KOH/g and during the conversion of the calcium sulfonate to a TBN of at most 450 mg KOH/g. Both the calcium sulfonate and the grease containing said calcium sulfonate may be produced exclusively on an ester basis, so that the end product does not contain any mineral oil and is therefore easily and completely biodegradable.

The present invention provides a grease composition or a lubricating oil composition which is capable of effectively preventing hydrogen brittleness-caused peeling from occurring on a rolling surface of a rolling bearing, is excellent in durability in a high temperature and speed operation, and can be used for a long time. A grease-packed bearing (1) has an inner ring (2), an outer ring (3), and a plurality of rolling elements (4). A sealing member (6) for sealing a grease composition (7) is provided at openings (8a) and (8b) disposed at both axial ends of the inner ring (2) and the outer ring (3). The grease composition (7) includes a base grease composed of a base oil and a thickener and an additive added to the base grease. The additive contains at least one compound selected from among plant-derived polyphenolic compounds and compounds formed by decomposition thereof. The above-described compounds include tannin, gallic acid, ellagic acid, chlorogenic acid, caffeic acid, curcumin, quercetin, and quinic acid.

A method of making an overbased calcium sulfonate or calcium magnesium sulfonate grease using one or more delay periods between the addition of at least a portion of a facilitating acid, such as DDBSA, and at least a portion of the next subsequently added ingredient. The delay period may be a temperature adjustment delay or a holding delay period. An overbased calcium sulfonate or calcium magnesium sulfonate grease composition comprises 0.5%-5% of a facilitating acid, allows for a reduced amount of overbased calcium sulfonate below 22%, and allows for a reduced amount of calcium hydroxyapatite to provide 10-25% of hydroxide equivalent basicity of the total hydroxide equivalent basicity due to calcium hydroxyapatite and added calcium hydroxide, while maintaining a high dropping point.

An overbased calcium magnesium sulfonate grease composition and method of making such grease without using any conventional non-aqueous converting agents, such as hexylene glycol, as a pre-conversion ingredient. The addition of magnesium sulfonate as an ingredient prior to conversion appears to act as a new, non-conventional converting agent, resulting in greases with improved thickener yield and excellent dropping point.

An overbased calcium magnesium sulfonate grease composition and method of manufacture comprising both overbased calcium sulfonate and overbased magnesium sulfonate in a ratio range of 60:40 to 100:1. The grease is made according to any known method for making an overbased calcium sulfonate grease by using the overbased magnesium sulfonate in addition to the overbased calcium sulfonate. A portion of the magnesium sulfonate may be added prior to conversion and another portion after conversion, with or without one or more delay periods between the addition of water or other reactive ingredient and the addition of magnesium sulfonate. The grease can be made using calcium hydroxyapatite and/or added calcium carbonate as calcium containing bases for reacting with complexing acids, a non-aqueous converting agent delay method, added alkali metal hydroxide, or any combination thereof. The grease has a high dropping point and reduced thickener yield.

An overbased sulfonate modified lithium carboxylate grease composition and method of manufacture comprising overbased calcium sulfonate, overbased magnesium sulfonate, or both added to a source of lithium hydroxide, base oil, and optionally one or more acids when a complex grease is desired. When overbased sulfonate is added, the amount of dicarboxylic acid relative monocarboxylic acid may be reduced. Additionally, the amount of lithium hydroxide added may be less than stoichiometrically needed to react with the acids. A sulfonate modified lithium grease with improved thickener yield and dropping point may be made without multiple heating and cooling cycles or using a pressurized kettle.

The present invention relates to a grease composition containing a base oil (A), a thickener (B), and an additive (C) composed of at least two selected from a sarcosine derivative (C1), an amine compound (C2), and an amide compound (C3), wherein the content of the component (C) is 0.1 to 10.0% by mass on a basis of the total amount of the grease composition.

The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphite ester (B-2), and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), and the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A).