Systems, methods, and materials for pyrolyzing vegetable oil feedstocks to obtain high yields of various products are described.

Systems, methods, and materials for pyrolyzing vegetable oil feedstocks to obtain high yields of various products are described.

A process for extraction of crude oil from distillers dried grain solubles and/or distillers dried grains and producing corn distillers meal that may be used as a livestock supplement is disclosed. For example, the corn distillers meal may be used as a crude protein supplement for use in a livestock feed diet or a poultry feed diet. The solvent extracted crude oil may be suitable for oleochemical processing for personal care and home care products, biodiesel production, and/or renewable diesel production from hydro-treating the extracted oil to make green diesel fuel.

Described herein is a polymerized biorenewable, petroleum based, previously modified, or functionalized oil, comprising a polymeric distribution ranging from about 2 to about 80 wt % oligomer content, a hydroxyl value ranging from about 0 to about 400, and an iodine value ranging from about 0 to about 200. Methods of manufacturing the polymerized oil as well as its incorporation into asphalt paving, roofing, and coating applications are also described.

A method for squalene extraction from a seed oil includes converting fatty acids of the seed oil into soap by subjecting the seed oil to a saponification reaction to obtain a saponified product, and adsorbing the fatty acids of the seed oil on surfaces of iron oxide nanoparticles to obtain iron oxide nanoparticles coated with fatty acids. The method may further include washing the iron oxide nanoparticles coated with fatty acids with a polar solvent to obtain a third mixture including a polar phase and the iron oxide nanoparticles coated with fatty acids, separating the iron oxide nanoparticles coated with fatty acids from the third mixture by a magnetic field, mixing the polar phase with a non-polar solvent and distilled water to obtain a two-phase solution, the two-phase solution including a non-polar phase and an aqueous phase, and separating and drying the non-polar phase to obtain squalene.

An all-natural, moisturizing soap composition that allow for high vegetable butter fat content while also being capable of processing for high quality bar soap (moisturizing properties without sticky pellets, brittleness, cracking, and/or inhibition of lather formation) and a method for making the same and other soaps is provided. The soap composition may contain up to 50% vegetable butter fat(s). The semi-continuous process for saponification provides a fast and energy efficient alternative to prior art methods, while also allowing for high quality bar soap that contains a high content (up to 50%) of vegetable butter fat(s).

The present invention generally provides a process for treating a soapstock. The present invention more particularly provides systems and methods for treating a soapstock to generate free fatty acids and/or fatty acid derivatives, e.g. fatty acid alkyl esters. The present invention more particularly provides systems and methods for realizing the full fatty acid yield of a soapstock by first converting substantially all of the saponifiable material in a soapstock to salts of fatty acids (soaps) and acidulating the soaps to generate free fatty acids and/or fatty acid derivatives, e.g. fatty acid alkyl esters, wherein the soapstock comprises soaps and saponifiable lipids, e.g. glycerides and/or phospholipids, and the generating of free fatty acids and/or fatty acid is achieved without the use of a mineral acid.

The present disclosure provides an efficient process for separating components of tall oil fatty acids (TOFA) and for purifying TOFA from rosin. The process includes mixing TOFA with a novel solvent system containing urea to form urea clathrates, resulting in separation of saturated fatty acids from unsaturated ones and rosin from TOFA by utilizing proper urea to TOFA ratio.

The present disclosure provides an efficient process for separating components of tall oil fatty acids (TOFA) and for purifying TOFA from rosin. The process includes mixing TOFA with a novel solvent system containing urea to form urea clathrates, resulting in separation of saturated fatty acids from unsaturated ones and rosin from TOFA by utilizing proper urea to TOFA ratio.

A method for production of renewable hydrocarbons, including alpha olefins, renewable diesel, synthetic gasoline, and acyl-glycerides, from renewable oils is described herein. Also included is a method for production comprising (a) blending a specific renewable oil mixture with the proper free fatty acid character; (b) acid hydrolysis of the free fatty acids and subsequent purification of the unsaturated and saturated chains; (c) converting the saturated portion into renewable diesel; and (d) reacting the unsaturated free fatty acids via ethenolysis to form alpha olefins, then converting the remaining free fatty acids into either synthetic gasoline or into an acyl-glycerol via glycerolysis.