In some variations, the invention provides a biocarbon pellet comprising: 35 wt % to 99 wt % of a biogenic reagent, wherein the biogenic reagent comprises, on a dry basis, at least 60 wt % carbon; 0 wt % to 35 wt % water moisture; and 1 wt % to 30 wt % of a binder, wherein the biocarbon pellet is characterized by an adjustable Hardgrove Grindability Index (HGI) from about 30 to about 120, as shown in the Examples. The pellet HGI is adjustable by controlling process conditions and the pellet binder. The binder can be an organic binder or an inorganic binder. The carbon is renewable as determined from a measurement of the .sup.14C/.sup.12C isotopic ratio. Many processes of making and using the biocarbon pellets are described. Applications of the biocarbon pellets include pulverized coal boilers, furnaces for making metals such as iron or silicon, and gasifiers for producing reducing gas.

In some variations, the invention provides a biocarbon pellet comprising: 35 wt % to 99 wt % of a biogenic reagent, wherein the biogenic reagent comprises, on a dry basis, at least 60 wt % carbon; 0 wt % to 35 wt % water moisture; and 1 wt % to 30 wt % of a binder, wherein the biocarbon pellet is characterized by an adjustable Hardgrove Grindability Index (HGI) from about 30 to about 120, as shown in the Examples. The pellet HGI is adjustable by controlling process conditions and the pellet binder. The binder can be an organic binder or an inorganic binder. The carbon is renewable as determined from a measurement of the .sup.14C/.sup.12C isotopic ratio. Many processes of making and using the biocarbon pellets are described. Applications of the biocarbon pellets include pulverized coal boilers, furnaces for making metals such as iron or silicon, and gasifiers for producing reducing gas.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

Provided herein are novel devices, systems, and methods of using the same, that enable plasma-enhanced gasification of biogenic hydrocarbon waste material comprising: a geometrically designed reactor having a biochar carbon catalyst bed, together with a gas inlet system disposed around a lower section of the apparatus to supply oxidant gas generated by an integrated oxygen absorber system; to enhance the partial oxidation of biogenic hydrocarbon waste materials using exothermic heat generated by an oxidation reaction created in part by the integrated oxygen absorber system into the apparatus, in order to optimize the quantity and quality of hydrogen production in the synthetic gas produced therein.

An oxygen injection system for a direct reduction process, including: a common circumferential gas injection header adapted to be coupled to an oxygen source and an enrichment natural gas source and adapted to deliver oxygen from the oxygen source and enrichment natural gas from the enrichment natural gas source to a reducing gas stream flowing through a conduit axially disposed within the common circumferential gas injection header through a plurality of circumferentially disposed ports to form a bustle gas stream; wherein the common circumferential gas injection header includes a circumferential oxygen injection header adapted to deliver the oxygen from the oxygen source to the reducing gas stream through the plurality of circumferentially disposed ports and a circumferential enrichment natural gas injection header adapted to deliver the enrichment natural gas from the enrichment natural gas source to the reducing gas stream through the plurality of circumferentially disposed ports.

The present invention provides a novel method for supplying a reducing gas to the shaft part of a blast furnace with which a large amount of reducing gas containing hydrogen at a high concentration can be supplied to a deeper position in the blast furnace (location of the blast furnace closer to the center axis in the radial direction) and with which it is possible to reduce the total generated amount of CO.sub.2 of the CO.sub.2 amount that is reduced by conducting hydrogen smelting in the blast furnace and the CO.sub.2 amount that is generated during production of the reducing gas supplied to the blast furnace. The method for supplying a reducing gas to the shaft part of a blast furnace according to the present invention is characterized by reforming coke oven gas by increasing the temperature thereof to 1200 to 1800 C. in a reactor in which an oxygen-containing gas is supplied to preheated coke oven gas to generate reformed gas in which hydrogen gas is enriched; mixing the reformed gas with CO-containing gas in the reactor so that the hydrogen concentration of the reducing gas is adjusted to 15-35 vol % (wet); and supplying the resultant reducing gas to the shaft part of the blast furnace under a condition of a ratio of a flow rate of reducing gas blown into shaft part/flow rate of reducing gas blown into tuyere >0.42.

The present invention discloses a device and method for measuring the softening and melting performances of iron ore in blast furnace under a reducing condition. The device includes a high temperature furnace, a gas supply system, a loading system and a weighing system, where the high temperature furnace is provided with a hearth, which is provided therein with a graphite crucible and a temperature acquisition device; the gas supply system is used to inject a reducing gas including N.sub.2, H.sub.2, CO.sub.2 and CO into the hearth; the gas supply system includes a gas storage device and a gas mixing device; the loading system includes a loading rod; an upper end of the loading rod is connected with a loading device and a displacement sensor, and a lower end of the loading rod is provided with a loading head; the weighing system is used to weigh a droplet and iron ore specimen.