On molten iron having the P concentration of 2 to 4 mass % and having the Cr concentration of 0.3 to 1.2 mass %, a dechromization treatment is performed by adjusting a basicity (CaO mass %)/(SiO.sub.2 mass %) of slag to greater than 0.1 and 1 or less and supplying an oxygen source with a molten iron temperature falling within a range of 1250 to 1500 C. to manufacture molten iron having the P concentration of 1.9 to 3.8 mass % and having the Cr concentration of less than 0.2 mass %.

On molten iron having the P concentration of 2 to 4 mass % and having the Cr concentration of 0.3 to 1.2 mass %, a dechromization treatment is performed by adjusting a basicity (CaO mass %)/(SiO.sub.2 mass %) of slag to greater than 0.1 and 1 or less and supplying an oxygen source with a molten iron temperature falling within a range of 1250 to 1500 C. to manufacture molten iron having the P concentration of 1.9 to 3.8 mass % and having the Cr concentration of less than 0.2 mass %.

Proposed is a molten iron refining method capable of securing an in-flame staying time period of a heat transfer medium without being influenced by height adjustments of a blowing-purpose oxygen-blowing lance. As far as to a position lower than an upper end inside a converter-type vessel 1, a blowing-purpose oxygen-blowing lance 3 that supplies oxidizing gas and is capable of ascending and descending and at least one burner lance 4 capable of ascending and descending independently of the blowing-purpose oxygen-blowing lance are inserted. From the blowing-purpose oxygen-blowing lance, either oxidizing gas or oxidizing gas and CaO-containing refining agent are blown onto the molten iron. Also, a flame is formed by causing the burner lance to discharge fuel gas and combustion supporting gas. Powder particles discharged from the burner lance are caused to pass through the flame and to be blown onto the molten iron in a heat-transferred state, so that the molten iron is thermally compensated.

Proposed is a molten iron refining method capable of securing an in-flame staying time period of a heat transfer medium without being influenced by height adjustments of a blowing-purpose oxygen-blowing lance. As far as to a position lower than an upper end inside a converter-type vessel 1, a blowing-purpose oxygen-blowing lance 3 that supplies oxidizing gas and is capable of ascending and descending and at least one burner lance 4 capable of ascending and descending independently of the blowing-purpose oxygen-blowing lance are inserted. From the blowing-purpose oxygen-blowing lance, either oxidizing gas or oxidizing gas and CaO-containing refining agent are blown onto the molten iron. Also, a flame is formed by causing the burner lance to discharge fuel gas and combustion supporting gas. Powder particles discharged from the burner lance are caused to pass through the flame and to be blown onto the molten iron in a heat-transferred state, so that the molten iron is thermally compensated.

When supplying oxygen source to molten pig iron inside a converter-type refining furnace and performing desiliconization, dephosphorization, and decarburization refining, one or more of slag removal flow shape, slag removal flow velocity, and slag surface shape while discharging slag through a throat is measured to estimate one or both of a slag removal amount and physical properties of removed slag. When sequentially performing one or both of desiliconization and dephosphorization, an intermediate step of discharging part or all of generated slag through the throat, and the remaining other refining step, in the intermediate step, the method measures one or two of slag removal flow shape, slag removal flow velocity, and slag surface shape, estimates one or both of amount and physical properties of slag removed, estimates remaining slag amount, or remaining slag amount and composition, and determines an auxiliary raw material amount to be fed in the other refining step.

When supplying oxygen source to molten pig iron inside a converter-type refining furnace and performing desiliconization, dephosphorization, and decarburization refining, one or more of slag removal flow shape, slag removal flow velocity, and slag surface shape while discharging slag through a throat is measured to estimate one or both of a slag removal amount and physical properties of removed slag. When sequentially performing one or both of desiliconization and dephosphorization, an intermediate step of discharging part or all of generated slag through the throat, and the remaining other refining step, in the intermediate step, the method measures one or two of slag removal flow shape, slag removal flow velocity, and slag surface shape, estimates one or both of amount and physical properties of slag removed, estimates remaining slag amount, or remaining slag amount and composition, and determines an auxiliary raw material amount to be fed in the other refining step.

A method for ironmaking by smelting reduction in a stir-generated vortex includes: (1) placing a pig iron in an induction furnace, and then heating the pig iron to a molten state to form a molten iron, and maintaining the molten iron to be greater than or equal to 1450 C.; (2) stirring a center of the molten iron to form a vortex with a height-to-diameter ratio of 0.5-2.5, and continuously performing stirring; (3) mixing and grinding on an iron-containing mineral, a reducing agent and a slag-forming agent in a mass ratio of 1:(0.1-0.15):(0.25-0.4) to obtain a powder mixture, spraying and blowing the powder mixture to a center of the vortex, performing a reduction reaction, and stopping the stirring after the molten iron and molten slags are obtained, wherein a waste gas is produced; and (4) discharging the molten iron and the molten slags respectively, and exhausting a treated waste gas.

A method for refining molten iron that can stably produce low-nitrogen steel is proposed. In this method for refining molten iron, untreated molten iron with a carbon concentration [C].sub.i between 0.5 mass % and 3.0 mass %, both inclusive, is placed into a vessel, and oxygen is blown onto the untreated molten iron under atmospheric pressure while a hydrogen gas, a hydrocarbon gas, or a mixture gas of these gases is blown in to perform a decarburization and denitrification treatment of the untreated molten iron. It is preferable, for example, that a nitrogen concentration [N].sub.f in treated molten iron after being subjected to the decarburization and denitrification treatment be 30 mass ppm or lower; that treated molten iron after being subjected to the decarburization and denitrification treatment be further subjected to a vacuum degassing treatment; that the untreated molten iron include molten iron obtained by melting a cold iron source; that the untreated molten iron be a mixture of primary molten iron obtained by melting a cold iron source in a melting furnace and molten pig iron having a carbon concentration of 2.0 mass % or higher; that the cold iron source include reduced iron; and that the vessel be a converter.

There is proposed a method for preliminary treatment of molten iron wherein heat source for dissolving scrap is ensured sufficiently to improve iron yield while decreasing phosphorus concentration efficiently by suppressing the amount of flux solvent used in the process of desiliconization, dephosphorization and decarburization. In the method for preliminary treatment of molten iron by conducting desiliconization and dephosphorization of molten iron with a converter type container, molten iron is first charged into the converter type container to conduct desiliconization and then intermediate slag removal is conducted, and subsequently a lime-based flux solvent is added to the container while blowing oxygen to conduct dephosphorization of the molten iron, and thereafter newly untreated molten iron is charged into the container to conduct desiliconization, and subsequently the above treatments are repeatedly conducted with the same container.

There is proposed a method for preliminary treatment of molten iron wherein heat source for dissolving scrap is ensured sufficiently to improve iron yield while decreasing phosphorus concentration efficiently by suppressing the amount of flux solvent used in the process of desiliconization, dephosphorization and decarburization. In the method for preliminary treatment of molten iron by conducting desiliconization and dephosphorization of molten iron with a converter type container, molten iron is first charged into the converter type container to conduct desiliconization and then intermediate slag removal is conducted, and subsequently a lime-based flux solvent is added to the container while blowing oxygen to conduct dephosphorization of the molten iron, and thereafter newly untreated molten iron is charged into the container to conduct desiliconization, and subsequently the above treatments are repeatedly conducted with the same container.