A method for desulfurizing molten steel comprising taking a sample out from molten steel after tapping from a converter or during secondary refining and analyzing the sample rapidly with high accuracy by a method comprising a high frequency induction heating step wherein the sample is combusted and oxidized under the high frequency induction heating in an oxygen atmosphere having an oxygen purity of 99.5 vol % or more to convert S in the sample into SO.sub.2 and an analyzing step wherein SO.sub.2-containing gas produced in the high frequency induction heating step is analyzed through an ultraviolet fluorescence method to quantify S concentration of the sample.

Provided in the present application are a rare-earth microalloyed steel and a control process. The steel has a special microstructure, and the microstructure comprises a rare earth-rich nanocluster having a diameter of 1-50 nm. The nanocluster has the same crystal structure type as a matrix. The rare earth-rich nanocluster inhibits the segregation of the elements S, P and As on a grain boundary, and obviously improves the fatigue life of the steel. In addition, a rare-earth solid solution also directly affects a phase change dynamics process so that the diffusion-type phase change starting temperature in the steel changes at least to 2° C., and even changes to 40-60° C. in some kinds of steel, thereby greatly improving the mechanical properties thereof, and providing a foundation for the development of more kinds of high-performance steel.

A method of manufacture to provide an efficient and economical steel deoxidizer aluminum matrix composite material that is near fully dense, free of brittle intermetallic compounds and allows for deep penetration of aluminum into molten steel thus cutting unnecessary losses of this valuable metal to parasitic oxidation reactions with slag and atmosphere.

The present disclosure provides a method for producing a high nitrogen steel by a duplex melting process of a pressurized ladle refining and a pressurized electroslag remelting, which relates to the technical field of high nitrogen steel melting. In the present disclosure, the molten steel is subjected in sequence to a nitrogen alloying, a deep deoxidation and a deep desulfurization by adding a nickel-magnesium alloy and rare earth in the pressurized ladle furnace, and a combination of a blowing nitrogen from the bottom of the pressurized ladle and a pressurized nitriding at the interface of gas and the molten steel is used to achieve a high-efficiency nitrogen alloying, a uniform nitrogen distribution, and a decreased impurity content in the ingot; then the ingot is subjected to a pressurized electroslag remelting to obtain a high nitrogen steel.

A charged material containing alloy iron of at least one of ferrochrome containing metallic Si or ferrosilicon, and unreduced slag containing Cr oxide generated by oxidative refining, is charged into an electric furnace as a mixture in which a mass ratio of a metallic Si amount to a Cr oxide amount is from 0.30 to 0.40, and a C concentration is in a range of from 2.0% by mass to a saturation concentration, and molten iron containing Cr obtained due to the Cr oxide undergoing reduction processing is produced, such that, when the charged material is heated and melted in the electric furnace, an attainment temperature is set to from 1400° C. to 1700° C., a maximum average heating rate in any 80° C. interval from 1300° C. to the attainment temperature is set to 15.0° C./min or less, and a minimum average heating rate in any 80° C. interval from 1300° C. to the attainment temperature is set to 3.0° C./min or greater.

A charged material containing a metal raw material of at least one of ferrochromium containing metal Si or ferrosilicon and unreduced slag containing Cr oxide generated by oxidation refining is charged into an AC electric furnace including three electrodes, a mass ratio of a metal Si amount to a Cr oxide amount being from 0.30 to 0.40, and a C concentration being from 2.0% by mass to a saturation concentration, and operation is performed under a condition where a diameter PCD (m) of a circle passing through the centers of the three electrodes viewed in a plan view from a central axis direction of the electric furnace, an average electrode height H.sub.e (m) that is a vertical distance from a tip of each electrode to a molten metal surface, a furnace inner diameter D.sub.f (m), a molten slag thickness H.sub.s (m), a spreading diameter D.sub.arc (m) of an arc on the molten metal surface, and a deflection angle θ (deg) of the arc satisfy the following relationships to produce molten iron containing Cr.

D.sub.arc=PCD+2H.sub.e.Math.tan θ

θ=52.5−75.Math.(PCD/D.sub.f)

0.22≤D.sub.arc/D.sub.f≤0.30

0.35≤H.sub.e/H.sub.s≤1.50

Disclosed are processes for recycling chromium oxide and producing chromium-alloy steel. Chromium oxide is reduced to metallic chromium and metallic chromium is mixed with steel to form chromium-alloy steel.

The present disclosure provides a method for producing a high nitrogen steel by a duplex melting process of a pressurized ladle refining and a pressurized electroslag remelting, which relates to the technical field of high nitrogen steel melting. In the present disclosure, the molten steel is subjected in sequence to a nitrogen alloying, a deep deoxidation and a deep desulfurization by adding a nickel-magnesium alloy and rare earth in the pressurized ladle furnace, and a combination of a blowing nitrogen from the bottom of the pressurized ladle and a pressurized nitriding at the interface of gas and the molten steel is used to achieve a high-efficiency nitrogen alloying, a uniform nitrogen distribution, and a decreased impurity content in the ingot; then the ingot is subjected to a pressurized electroslag remelting to obtain a high nitrogen steel.

A production apparatus and method for electric arc furnace steelmaking with a fully continuous ultra-short process are provided. A continuous adding, melting, smelting and continuous casting of a metal material are integrated, and a metallurgy process is completed in a flowing of a molten steel, to realize a continuous production of ingot blanks. The production apparatus includes four operation sites of an electric arc furnace for melting and primary refining, a sealed tapping chute for molten steel flowing, a refinement storage bed for molten-steel desulfurization and alloying and a conticaster for continuous casting A material flow, an energy flow and a time stream in the four operation sites are in a dynamic equilibrium. The production apparatus and method realize a molten-steel casting is started within 120 minutes after the metal material is started to be continuously added, and an uninterrupted continuous production is maintained for above 80 hours.

Provided is a method for determining a quantity of a calcium line fed into molten steel based on a minimum Gibbs free energy principle, which relates to an calcium treatment process of molten steel refining for iron and steel metallurgy. The method includes: establishing a connection with a database to read composition information and a temperature of the molten steel in an actual production process; calculating contents of inclusions in the molten steel according to the read composition information; calculating a required quantity of calcium of the molten steel to control the inclusions in a target area under a current condition; and calculating a length of the fed calcium line according to parameter information of the calcium treatment process and the required quantity of calcium of the molten steel. With the method, a scientific and reasonable guidance is provided for the calcium treatment process in the actual production process.