Ti, N, Al, Mg, and Ca concentrations are controlled in order to prevent aggregation of TiN inclusions. Furthermore, not only is a Fe—Cr—Ni alloy having superior surface property provided, but also a method is proposed in which the Fe—Cr—Ni alloy is produced at low cost using commonly used equipment. The Fe—Cr—Ni alloy includes C≤0.05%, Si: 0.1 to 0.8%, Mn: 0.2 to 0.8%, P≤0.03%, S≤0.001%, Ni:16 to 35%, Cr: 18 to 25%, Al: 0.2 to 0.4%, Ti: 0.25 to 0.4%, N≤0.016%, Mg: 0.0015 to 0.008%, Ca≤0.005%, O: 0.0002 to 0.005%, freely selected Mo: 0.5 to 2.5% in mass % and Fe and inevitable impurities as the remainder, wherein Ti and N satisfy % N×% Ti≤0.0045 and the number of TiN inclusions not smaller than 5 μm is 20 to 200 pieces/cm.sup.2 at a freely selected cross section.

Ti, N, Al, Mg, and Ca concentrations are controlled in order to prevent aggregation of TiN inclusions. Furthermore, not only is a Fe—Cr—Ni alloy having superior surface property provided, but also a method is proposed in which the Fe—Cr—Ni alloy is produced at low cost using commonly used equipment. The Fe—Cr—Ni alloy includes C≤0.05%, Si: 0.1 to 0.8%, Mn: 0.2 to 0.8%, P≤0.03%, S≤0.001%, Ni:16 to 35%, Cr: 18 to 25%, Al: 0.2 to 0.4%, Ti: 0.25 to 0.4%, N≤0.016%, Mg: 0.0015 to 0.008%, Ca≤0.005%, O: 0.0002 to 0.005%, freely selected Mo: 0.5 to 2.5% in mass % and Fe and inevitable impurities as the remainder, wherein Ti and N satisfy % N×% Ti≤0.0045 and the number of TiN inclusions not smaller than 5 μm is 20 to 200 pieces/cm.sup.2 at a freely selected cross section.

A non-heat treated steel bar according to the present disclosure has a chemical composition consisting of, in mass percent, C: 0.39 to 0.55%, Si: 0.10 to 1.00%, Mn: 0.50 to 1.50%, P: 0.010 to 0.100%, S: 0.040 to 0.130%, Cr: 0.05 to 0.50%, V: 0.05 to 0.40%, Ti: 0.10% to 0.25%, Al: 0.003 to 0.100%, and N: 0.020% or less, with the balance being Fe and impurities, and satisfying Formula (1). A number density of Al.sub.2O.sub.3-based inclusions in each of which Al.sub.2O.sub.3 is contained at 70.0% or more in mass % and √AREA is not less than 3 μm is 0.05 to 1.00/mm.sup.2.
0.60≤C+0.2Mn+0.25Cr+0.75V+0.81Mo≤1.00  (1)

A non-heat treated steel bar according to the present disclosure has a chemical composition consisting of, in mass percent, C: 0.39 to 0.55%, Si: 0.10 to 1.00%, Mn: 0.50 to 1.50%, P: 0.010 to 0.100%, S: 0.040 to 0.130%, Cr: 0.05 to 0.50%, V: 0.05 to 0.40%, Ti: 0.10% to 0.25%, Al: 0.003 to 0.100%, and N: 0.020% or less, with the balance being Fe and impurities, and satisfying Formula (1). A number density of Al.sub.2O.sub.3-based inclusions in each of which Al.sub.2O.sub.3 is contained at 70.0% or more in mass % and √AREA is not less than 3 μm is 0.05 to 1.00/mm.sup.2.
0.60≤C+0.2Mn+0.25Cr+0.75V+0.81Mo≤1.00  (1)

A sulfur additive is added to molten steel. At that time, the yield of sulfur in the molten steel is stabilized and nozzle blockage at the time of continuous casting due to impurities is prevented. A sulfur additive used for molten steel which contains iron sulfide ore particles with a particle size of 5.0 to 37.5 mm in 85 mass % or more with respect to the total mass % of the sulfur additive is used to produce Al deoxidized resulfurized steel containing S: 0.012 to 0.100 mass %.

A martensitic stainless steel sheet comprises a chemical composition containing, in mass %, C: 0.035% to 0.090%, Si: 0.01% to 1.0%, Mn: 0.01% to 0.90%, P: 0.050% or less, S: 0.050% or less, Cr: 10.0% to 14.0%, Ni: 0.01% to 0.40%, Al: 0.001% to 0.50%, V: 0.05% to 0.50%, and N: 0.050% to 0.20%, with the balance being Fe and inevitable impurities, wherein a content of C and a content of N in the chemical composition satisfy C %+N % 0.10% and N % C %, the number of precipitates with a major axis length of 200 nm or more in a surface layer of the martensitic stainless steel sheet is 25 or less per 100 μm.sup.2, and the martensitic stainless steel sheet has a tensile strength of 1300 MPa or more, a proof stress of 1100 MPa or more, and an elongation of 8.0% or more.

A steel material has a chemical composition which consists of, in mass %, C: 0.15 to 0.30%, Si: 0.02 to 1.00%, Mn: 0.20 to 0.80%, P: 0.020% or less, S: 0.028% or less, Cr: 0.80 to 1.50%, Mo: 0.08 to 0.40%, V: 0.10 to 0.40%, Al: 0.005 to 0.060%, N: 0.0150% or less, O: 0.0030% or less, and the balance: Fe and impurities, and satisfies Formulae (1) and (2), in which, at a cross section parallel to the axial direction of the steel material for a steel piston, the number of Mn sulfides is 100.0 per mm.sup.2 or less, the number of coarse Mn sulfides having an equivalent circular diameter of 3.0 μm or more is in a range of 1.0 to 10.0 per mm.sup.2, and the number of oxides is 15.0 per mm.sup.2 or less.

0.42≤Mo+3V≤1.50  (1)

V/Mo≥0.50  (2)

A steel material has a chemical composition which consists of, in mass %, C: 0.15 to 0.30%, Si: 0.02 to 1.00%, Mn: 0.20 to 0.80%, P: 0.020% or less, S: 0.028% or less, Cr: 0.80 to 1.50%, Mo: 0.08 to 0.40%, V: 0.10 to 0.40%, Al: 0.005 to 0.060%, N: 0.0150% or less, O: 0.0030% or less, and the balance: Fe and impurities, and satisfies Formulae (1) and (2), in which, at a cross section parallel to the axial direction of the steel material for a steel piston, the number of Mn sulfides is 100.0 per mm.sup.2 or less, the number of coarse Mn sulfides having an equivalent circular diameter of 3.0 μm or more is in a range of 1.0 to 10.0 per mm.sup.2, and the number of oxides is 15.0 per mm.sup.2 or less.

0.42≤Mo+3V≤1.50  (1)

V/Mo≥0.50  (2)

A method for desulfurizing molten steel comprising taking a sample out from molten steel after tapping from a converter or during secondary refining and analyzing the sample rapidly with high accuracy by a method comprising a high frequency induction heating step wherein the sample is combusted and oxidized under the high frequency induction heating in an oxygen atmosphere having an oxygen purity of 99.5 vol % or more to convert S in the sample into SO.sub.2 and an analyzing step wherein SO.sub.2-containing gas produced in the high frequency induction heating step is analyzed through an ultraviolet fluorescence method to quantify S concentration of the sample.

A method for desulfurizing molten steel comprising taking a sample out from molten steel after tapping from a converter or during secondary refining and analyzing the sample rapidly with high accuracy by a method comprising a high frequency induction heating step wherein the sample is combusted and oxidized under the high frequency induction heating in an oxygen atmosphere having an oxygen purity of 99.5 vol % or more to convert S in the sample into SO.sub.2 and an analyzing step wherein SO.sub.2-containing gas produced in the high frequency induction heating step is analyzed through an ultraviolet fluorescence method to quantify S concentration of the sample.