Provided are: a useful bed medium for a fluidized bed with good fluidity, the bed medium being usable in a fluidized bed furnace using biomass material and coal material as fuel; and a useful bed medium for a fluidized bed with good durability, the bed medium not easily forming an agglomerate of its particles, and being resistant to collapsing. The bed medium for a fluidized bed in a fluidized bed furnace for combusting or gasifying the fuel is formed of artificially-produced spherical refractory particles containing not less than 40% by weight of Al2O3 and not more than 60% by weight of SiO2 and having an apparent porosity of not more than 5%, and a ratio by weight of agglomerated particles in the bed medium is not more than 20% after three heat treatment tests on the bed medium at 900° C. for 2 hours under coexistence with the fuel.

An article for magnetic heat exchange comprising a magnetocalorically active phase with a NaZn.sub.13-type crystal structure is provided by hydrogenating a bulk precursor article. The bulk precursor article is heated from a temperature of less than 50° C. to at least 300° C. in an inert atmosphere and hydrogen gas only introduced when a temperature of at least 300° C. is reached. The bulk precursor article is maintained in a hydrogen containing atmosphere at a temperature in the range 300° C. to 700° C. for a selected duration of time, and then cooled to a temperature of less than 50° C.

An article for magnetic heat exchange comprising a magnetocalorically active phase with a NaZn.sub.13-type crystal structure is provided by hydrogenating a bulk precursor article. The bulk precursor article is heated from a temperature of less than 50° C. to at least 300° C. in an inert atmosphere and hydrogen gas only introduced when a temperature of at least 300° C. is reached. The bulk precursor article is maintained in a hydrogen containing atmosphere at a temperature in the range 300° C. to 700° C. for a selected duration of time, and then cooled to a temperature of less than 50° C.

A finish heat treatment apparatus for an iron powder. Raw iron powder is placed on a continuous moving hearth and continuously charged into the apparatus. In a pretreatment zone, the raw iron powder is subjected to a pretreatment of heating the raw iron powder in an atmosphere of hydrogen gas and/or inert gas at 450 to 1100° C. In decarburization, deoxidation, and denitrification zones, the pretreated iron powder is subsequently subjected to at least two treatments of decarburization, deoxidation, and denitrification. In the pretreatment zone, a hydrogen gas and/or an inert gas serving as a pretreatment ambient gas is introduced separately from an ambient gas used in the at least two treatments is introduced from the upstream side of the pretreatment zone and released from the downstream side so as to flow in the same direction as a moving direction of the moving hearth.

A finish heat treatment apparatus for an iron powder. Raw iron powder is placed on a continuous moving hearth and continuously charged into the apparatus. In a pretreatment zone, the raw iron powder is subjected to a pretreatment of heating the raw iron powder in an atmosphere of hydrogen gas and/or inert gas at 450 to 1100° C. In decarburization, deoxidation, and denitrification zones, the pretreated iron powder is subsequently subjected to at least two treatments of decarburization, deoxidation, and denitrification. In the pretreatment zone, a hydrogen gas and/or an inert gas serving as a pretreatment ambient gas is introduced separately from an ambient gas used in the at least two treatments is introduced from the upstream side of the pretreatment zone and released from the downstream side so as to flow in the same direction as a moving direction of the moving hearth.

A process gas preparation device for an industrial furnace system is disclosed. The gas preparation device includes a preparation reactor having a catalyst. A gas feed line and a gas return line are connected between the industrial furnace and the preparation reactor to form a closed loop. A compressor is situated upstream from the preparation reactor in the feed line. The preparation reactor is also connected with supply lines for hydrocarbon gas and air to be supplied to the preparation reactor. The process gas preparation device also includes a control device with which process gas preparation and return can be regulated and controlled. The gas feed line also has a shut-off valve. The control device can check the functional state of the catalyst by measuring the pressure differential across the catalyst and can initiate a burn-out process therein to clear clogging of the catalyst.

A process gas preparation device for an industrial furnace system is disclosed. The gas preparation device includes a preparation reactor having a catalyst. A gas feed line and a gas return line are connected between the industrial furnace and the preparation reactor to form a closed loop. A compressor is situated upstream from the preparation reactor in the feed line. The preparation reactor is also connected with supply lines for hydrocarbon gas and air to be supplied to the preparation reactor. The process gas preparation device also includes a control device with which process gas preparation and return can be regulated and controlled. The gas feed line also has a shut-off valve. The control device can check the functional state of the catalyst by measuring the pressure differential across the catalyst and can initiate a burn-out process therein to clear clogging of the catalyst.

A cold-rolled sheet is provided. The cold-rolled sheet includes a steel substrate with a carbon content C.sub.0 between 0.07% and 0.5%, expressed by weight, and a metal pre-coating on at least the two principal faces of the steel substrate. The substrate has a decarburized area on the surface of each of the two principal faces. The depth p.sub.50% of the decarburized area is between 6 and 30 micrometers, and p.sub.50% is the depth at which the carbon content is equal to 50% of the content C.sub.0. The sheet does not contain a layer of iron oxide between the substrate and the metal pre-coating.

A continuous annealing furnace for annealing steel strips that is a vertical-type annealing furnace is configured so that part of gas inside the furnace is drawn and introduced to a refiner disposed outside the furnace including an oxygen removing apparatus and a dehumidifying apparatus, oxygen and moisture contained in the gas are removed to lower the dew point of the gas, and the gas having a lowered dew point is put back into the furnace. At least one gas inlet through which gas is drawn from the furnace into the refiner is disposed in the vicinity of the entry side of the furnace at a distance of 6 m or less in the vertical direction and 3 m or less in the furnace-length direction from the steel-strip-introduction section located at the lower part of the heating zone.

A continuous annealing furnace for annealing steel strips that is a vertical-type annealing furnace is configured so that part of gas inside the furnace is drawn and introduced to a refiner disposed outside the furnace including an oxygen removing apparatus and a dehumidifying apparatus, oxygen and moisture contained in the gas are removed to lower the dew point of the gas, and the gas having a lowered dew point is put back into the furnace. At least one gas inlet through which gas is drawn from the furnace into the refiner is disposed in the vicinity of the entry side of the furnace at a distance of 6 m or less in the vertical direction and 3 m or less in the furnace-length direction from the steel-strip-introduction section located at the lower part of the heating zone.