A stainless steel seamless pipe having high strength and excellent corrosion resistance. The stainless steel seamless pipe has a specified composition in which C, Si, Mn, Cr, Ni, Mo, Cu, and N satisfy a predetermined formula, a microstructure containing at least 25% martensitic phase, at most 65% ferrite phase, and at most 40% retained austenite phase by volume, and a yield strength of 758 MPa or more.

Provided is an ultra-high-strength reinforcing bar and a method for manufacturing the same are disclosed. In an exemplary embodiment, the ultra-high-strength reinforcing bar includes an amount of 0.10 to 0.45 wt % carbon (C), an amount of 0.5 to 1.0 wt % silicon (Si), an amount of 0.40 to 1.80 wt % manganese (Mn), an amount of 0.10 to 1.0 wt % chromium (Cr), an amount greater than 0 and less than or equal to 0.2 wt % vanadium (V), an amount greater than 0 and less than or equal to 0.4 wt % copper (Cu), an amount greater than 0 and less than or equal to 0.5 wt % molybdenum (Mo), an amount of 0.015 to 0.070 wt % aluminum (Al), an amount greater than 0 and less than or equal to 0.25 wt % nickel (Ni), an amount greater than 0 and less than or equal to 0.1 wt % tin (Sn), an amount greater than 0 and less than or equal to 0.05 wt % phosphorus (P), an amount greater than 0 and less than or equal to 0.03 wt % sulfur (S), an amount of 0.005 to 0.02 wt % nitrogen (N), and the remainder being iron (Fe) and other inevitable impurities.

A martensitic stainless steel sheet has a composition containing, (mass %), from 0.10 to 0.15% of C, from 0.05 to 0.80% of Si, from 0.05 to 2.00% of Mn, 0.040% or less of P, 0.003% or less of S, from 0.05 to 0.50% of Ni, from 11.0 to 15.0% of Cr, from 0.02 to 0.50% of Cu, from 0.005 to 0.06% of N, from 0.001 to 0.20% of Al, from 0 to 1.00% of Mo, from 0 to 0.50% of V, from 0 to 0.01% of B, balance Fe and unavoidable impurities. An M value=420C−11.5Si+7Mn+23Ni−11.5Cr−12Mo−10V+9Cu−52Al+470N+189 is 100 or more. A carbonitride number density having a circle equivalent diameter of 1.0 μm or more is 15.0 or less per 0.01 mm.sup.2. 0.2% yield strength is 1,100 N/mm.sup.2 or more.

An improved atomized powder metal material containing an increased amount of free graphite after heat treatment and/or sintering is provided. The powder metal material is typically a ferrous alloy and includes carbon in an amount of 1.0 wt. % to 6.5 wt. % and silicon in an amount of 0.1 wt. % to 6.0 wt. %, based on the total weight of the powder metal material. The powder metal material can also include various other alloying elements, for example at least one of nickel (Ni), cobalt (Co), copper (Cu), tin (Sn), aluminum (Al), sulfur (S), phosphorous (P), boron (B), nitrogen (N), chromium (Cr), manganese (Mn), molybdenum (Mo), vanadium (V), niobium (Nb), tungsten (W), titanium (Ti), tantalum (Ta) zirconium (Zr), zinc (Zn), strontium (Sr), calcium (Ca), barium (Ba) magnesium (Mg), lithium (Li), sodium (Na), and potassium (K).

This hot-rolled steel sheet has a predetermined chemical composition, in which in a case where the thickness is denoted by t, a metallographic structure at a t/4 position from the surface includes, by area fraction, 77.0% to 97.0% of bainite or tempered martensite, 0% to 5.0% of ferrite, 0% to 5.0% of pearlite, 3.0% or more of residual austenite, and 0% to 10.0% of martensite, in the metallographic structure, the average grain size excluding the residual austenite is 7.0 μm or less, the average number density of iron-based carbides having a diameter of 20 nm or more is 1.0×10.sup.6 carbides/mm.sup.2 or more, a tensile strength is 980 MPa or more, and an average Ni concentration on the surface is 7.0% or more.

Provided is a method for manufacturing a grain-oriented electrical steel sheet. The method comprises: hot rolling a slab to obtain a hot rolled sheet; subjecting the hot rolled sheet to hot band annealing as necessary; subjecting the hot rolled sheet to cold rolling; subjecting the cold rolled sheet to decarburization annealing; applying an annealing separator having MgO as a main component onto a surface of the decarburization annealed sheet and subjecting the decarburization annealed sheet to final annealing to form the forsterite film; and applying an insulating coating treatment liquid onto the final annealed sheet and subjecting the final annealed sheet to flattening annealing to form a tension-applying insulating coating. A difference in total tensions between one and opposite surfaces of the sheet is less than 0.5 MPa. A difference in tensions between the forsterite films in one and opposite surfaces of the sheet is 0.5 MPa or more.

A steel sheet includes a predetermined chemical composition and a metal structure represented by, in area fraction, ferrite: 50% to 95%, granular bainite: 5% to 48%, martensite: 2% to 30%, and upper bainite, lower bainite, tempered martensite, retained austenite, and pearlite: 5% or less in total.

A cold rolled and heat treated steel sheet having a composition with the following elements, expressed in percentage by weight: 0.10%≤Carbon≤0.5%,1%≤Manganese≤3.4%, 0.5%≤Silicon≤2.5%, 0.03%≤Aluminum≤1.5%, 0%≤Sulfur≤0.003% 0.002%≤Phosphorus≤0.02%, 0%≤Nitrogen≤0.01% and can contain one or more of the following optional elements 0.05%≤Chromium≤1%, 0.001%≤Molybdenum≤0.5%, 0.001%≤Niobium≤0.1%, 0.001%≤Titanium≤0.1%, 0.01%≤Copper≤2%, 0.01%≤Nickel≤3%, 0.0001%≤Calcium≤0.005%, 0%≤Vanadium≤0.1%, 0%≤Boron≤0.003%, 0%≤Cerium≤0.1%, 0%≤Magnesium≤0.010%, 0%≤Zirconium≤0.010% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of the steel sheet having in area fraction, 10 to 30% Residual Austenite, 10 to 40% Bainite, 5% to 50% Annealed Martensite, 1% to 20% Quenched Martensite and less than 30% Tempered Martensite, wherein the cumulated amounts of Bainite and Residual Austenite is more than or equal to 25%.

Disclosed is a hot-rolled steel strip having a tensile strength greater than 875 MPa and containing in mass-%: C 0.06-0.12, Si 0-0.5, Mn 0.70-2.20, Nb 0.005-0.100, Ti 0.01-0.10, V 0.11-0.40, whereby the total amount of V+Nb+Ti is 0.20-0.40 Al 0.005-0.150, B 0-0.0008, Cr 0-1.0, whereby the total amount of Mn+Cr is 0.9-2.5, Mo 0-0.5, Cu 0-0.5, Ni 0-1.0, P 0-0.05, S 0-0.01, Zr 0-0.1 Co 0-0.1 W 0-0.1 Ca 0-0.005, N 0-0.01, balance Fe and unavoidable impurities, and having a microstructure at ¼ thickness that is: at least 90% martensite and bainite with island-shaped martensite-austenite (MA) constituents, the remainder being: less than 5% polygonal ferrite and quasi-polygonal ferrite, less than 5% pearlite, less than 5% austenite, so that the total area percentage is 100%.

A structural steel having excellent brittle crack propagation resistance, according to one aspect of the present invention, comprises, by wt %, 0.02-0.12% of C, 0.01-0.8% of Si, 1.7-2.5% of Mn, 0.005-0.5% of Al, and the balance of Fe and inevitable impurities, wherein an outer surface part and an inner center part thereof are microstructurally distinguished in the thickness direction, and the surface part comprises tempered bainite as a base structure, comprises fresh martensite as a second structure and can comprise austenite as a residual structure.