An improved atomized powder metal material containing an increased amount of free graphite after heat treatment and/or sintering is provided. The powder metal material is typically a ferrous alloy and includes carbon in an amount of 1.0 wt. % to 6.5 wt. % and silicon in an amount of 0.1 wt. % to 6.0 wt. %, based on the total weight of the powder metal material. The powder metal material can also include various other alloying elements, for example at least one of nickel (Ni), cobalt (Co), copper (Cu), tin (Sn), aluminum (Al), sulfur (S), phosphorous (P), boron (B), nitrogen (N), chromium (Cr), manganese (Mn), molybdenum (Mo), vanadium (V), niobium (Nb), tungsten (W), titanium (Ti), tantalum (Ta) zirconium (Zr), zinc (Zn), strontium (Sr), calcium (Ca), barium (Ba) magnesium (Mg), lithium (Li), sodium (Na), and potassium (K).

A zinc-plated steel sheet of an aspect of the present invention includes a steel sheet having a predetermined chemical composition and a zinc-plated layer. In the steel sheet, steel microstructures in a range of ⅛ thickness to ⅜ thickness, having the center at ¼ thickness from a steel sheet surface, include, by vol %, ferrite: 0% to 10%, bainite: 0% to 20%, tempered martensite: 70% or more, fresh martensite: 0% to 10%, retained austenite: 0% to 10%, and pearlite: 0% to 5%. In the zinc-plated steel sheet, the amount of hydrogen emitted when the steel sheet is heated to 200° C. from a room temperature after removal of the zinc-plated layer is 0.40 ppm or less per mass of the steel sheet, the tensile strength is 1470 MPa or more, and no cracking occurs in a U-shape bending test where a stress equivalent to 1000 MPa is applied for 24 hours.

An R—Fe—B base sintered magnet is provided consisting essentially of R (which is at least two rare earth elements and essentially contains Nd and Pr), M.sub.1 which is at least two of Si, Al, Mn, Ni, Cu, Zn, Ga, Ge, Pd, Ag, Cd, In, Sn, Sb, Pt, Au, Hg, Pb, and Bi, M.sub.2 which is at least one of Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, and W, boron, and the balance of Fe, and containing an intermetallic compound R.sub.2(Fe,(Co)).sub.14B as a main phase. The magnet contains an R—Fe(Co)-M.sub.1 phase as a grain boundary phase, the R—Fe(Co)-M.sub.1 phase contains A phase which is crystalline with crystallites of at least 10 nm formed at grain boundary triple junctions, and B phase which is amorphous and/or nanocrystalline with crystallites of less than 10 nm formed at intergranular grain boundaries and optionally grain boundary triple junctions.

A production method includes producing a rare-earth magnet precursor (S′) by performing first hot working in which, in two side surfaces of a sintered body, which are parallel to a pressing direction and are opposite to each other, one side surface is brought to a constrained state to suppress deformation, and the other side surface is brought to an unconstrained state to permit deformation; and producing a rare-earth magnet by performing second hot working in which, in two side surfaces (S′1, S′2) of the rare-earth magnet precursor (S′), which are parallel to the pressing direction, a side surface (S′2), which is in the unconstrained state in the first hot working, is brought to the constrained state to suppress deformation, and a side surface (S′1), which is in the constrained state in the first hot working, is brought to the unconstrained state to permit deformation.

Provided is steel for nitrocarburizing with excellent surface fatigue strength. The steel has a nitride compound layer with a thickness of 5.0 μm to 30.0 μm and a hardened layer in an order from a steel surface to steel inside, where a thickness of a porous layer on an outermost surface of the compound layer is 3.0 μm or less and 40.0% or less of a compound layer's thickness, the hardened layer has hardness of HV600 or more, HV400 or more and HV250 or more at 50 μm inward from the steel surface, from the steel surface to the steel inside of 400 μm, and from the steel surface to the steel inside of 600 μm, respectively, an unhardened portion excluding the compound and hardened layers has a predetermined chemical composition, and the hardened layer has a chemical composition with a higher N content than the unhardened portion.

In a steel sheet according to the present embodiment, a Ti content and a N content satisfy Ti−3.5×N≥0.003, at a sheet thickness ¼ position, a metallographic structure includes 90% or more of martensite in terms of volume fraction, at the sheet thickness ¼ position, a number density of TiC having a circle equivalent diameter of 1 to 500 nm is 3.5×10.sup.4 particles/mm.sup.2 or more, at the sheet, thickness ¼ position, a value of a median value of a Mn concentration+3σ is 5.00% or less, and a hardness measured at the sheet thickness ¼ position is 1.30 times or more a hardness measured at a position 50 μm deep from a surface of the steel sheet.

Disclosed is a mar aging steel containing, in combination in mass percent, C in a content from greater than 0% to 0.02%, Mn in a content from greater than 0% to 0.3%, Si in a content from greater than 0% to 0.3%, Ni in a content of 10% to 13%, Mo in a content of 0.5% to 3.5%, Co in a content of 9% to 12%, Cr in a content of 1.5% to 4.5%, Ti in a content of 1.5% to 4.5%, and Al in a content of 0.01% to 0.2%, where the total content of Mo and Ti is 5.0 mass percent or less, and the ratio ([Mo]/[Ti]) of the Mo content [Mo] to the Ti content [Ti] is 1.0 or less, with the remainder consisting of iron and inevitable impurities.

A method for fabricating an article includes forming a billet consisting essentially of a stainless steel composition of manganese 2.00 wt. %-24.00 wt. % chromium 19.00 wt. %-30 wt. % molybdenum 0.50 wt. %-4.0 wt. % nitrogen 0.25 wt. %-1.10 wt. % carbon ≤1 wt. % phosphorus ≤0.03 wt. % sulfur ≤1 wt. % nickel <22 wt. % cobalt <0.10 wt. % silicon ≤1 wt. % niobium ≤0.80 wt. % oxygen ≤1 wt. % copper ≤0.25 wt. % balance iron.
The billet is annealed and cold worked to form an article. Without annealing of the article, the article is subsequently case hardened at a single case hardening temperature to form a surface layer on a top surface thereof. Articles formed with the indicated stainless steel composition with case hardened surface layers are also provided.

This steel sheet has a predetermined chemical composition, in which a steel structure of an inside of the steel sheet contains, by volume fraction, soft ferrite: 0% to 30%, retained austenite: 3% to 40%, fresh martensite: 0% to 30%, a sum of pearlite and cementite: 0% to 10%, and a remainder includes hard ferrite, a number proportion of the retained austenite having an aspect ratio of 2.0 or more in the total retained austenite is 50% or more, a soft layer having a thickness of 1 to 100 μm from a surface in a sheet thickness direction is present, in ferrite contained in the soft layer, a volume fraction of grains having an aspect ratio of 3.0 or more is 50% or more, a volume fraction of retained austenite in the soft layer is 80% or less of the volume fraction of the retained austenite in the inside of the steel sheet, and a peak of an emission intensity at a wavelength indicating Si appears in a range of more than 0.2 μm and 10.0 μm or less from the surface.

An ultra-high strength maraging stainless steel with nominal composition (in mass) of C≤0.03%, Cr: 13.0-14.0%, Ni: 5.5-7.0%, Co: 5.5-7.5%, Mo: 3.0-5.0%, Ti: 1.9-2.5%, Si: ≤0.1%, Mn: ≤0.1%, P: ≤0.01%, S: ≤0.01%, and Fe: balance. The developed ultra-high strength maraging stainless steel combines ultra-high strength (with σb≥2000 MPa, σ0.2≥1700 MPa, δ≥8% and ψ≥40%), high toughness (KIC≥83 MPa.Math.m½) and superior salt-water corrosion resistance (with pitting potential Epit≥0.15 (vs SCE)). Therefore, this steel is suitable to make structural parts that are used in harsh corrosive environments like marine environment containing chloride ions, etc.