A material for high carburizing steel and a method for producing a gear using the material are provided. The material includes C of about 0.13 to 0.3 wt %, Si 0.7 to 1.3 wt %, Mn of about 0.3 to 1 wt %, P of about 0.02 wt % or less, S of about 0.03 wt % or less, Cr of about 2.2 to 3.0 wt %, Mo of about 0.2 to 0.7 wt %, Cu of about 0.3 wt % or less, Nb of about 0.03 to 0.06 wt %, V of about 0.1 to 0.3 wt %, Ti of about 0.001 to 0.003 wt %, a balance of Fe and other inevitable.

In the present invention, a press-formed product is manufactured by heating a steel sheet for hot pressing use to a temperature of 900 C. or above and 1,100 C. or below, the steel sheet for hot pressing use having a predetermined chemical component composition, some of Ti-containing precipitates contained in the steel sheet, each of which having an equivalent circle diameter of 30 nm or less, having an average equivalent circle diameter of 6 nm or less, and the precipitated Ti amount and the total Ti amount in the steel fulfilling the relationship represented by formula (1) shown below, thereafter starting press-forming, and holding at the bottom dead point and cooling to a temperature lower than the martensite transformation starting temperature Ms while securing the average cooling rate of 20 C./s or more within a tool.
Precipitated Ti amount(mass %)3.4[N]<0.5[total Ti amount (mass %)3.4[N]](1)
(In the formula (1), [N] represents the content (mass %) of N in the steel.).

In the present invention, a press-formed product is manufactured by heating a steel sheet for hot pressing use to a temperature of 900 C. or above and 1,100 C. or below, the steel sheet for hot pressing use having a predetermined chemical component composition, some of Ti-containing precipitates contained in the steel sheet, each of which having an equivalent circle diameter of 30 nm or less, having an average equivalent circle diameter of 6 nm or less, and the precipitated Ti amount and the total Ti amount in the steel fulfilling the relationship represented by formula (1) shown below, thereafter starting press-forming, and holding at the bottom dead point and cooling to a temperature lower than the martensite transformation starting temperature Ms while securing the average cooling rate of 20 C./s or more within a tool.
Precipitated Ti amount(mass %)3.4[N]<0.5[total Ti amount (mass %)3.4[N]](1)
(In the formula (1), [N] represents the content (mass %) of N in the steel.).

[Summary]

[Assignment] A precipitation hardening martensitic stainless steel having superior strength and improved welding properties.

[Solution] In mass %, C: 0.030 to 0.065%, Si: 1.0 to 2.0%, Mn: 0.51 to 1.50%, P: not more than 0.04%, S: not more than 0.0020%, Ni: 4.0 to 10.0%, Cr: 11.0 to 18.0%, Mo: 0.1 to 1.50%, Cu: 0.30 to 6.0%, Al: 0.005 to 0.2%, Sn: 0.003 to 0.030%, N: 0.001 to 0.015%, Ti: 0.15 to 0.45%, Nb: 0.15 to 0.55%, Ca: not more than 0.0025%, Mg: 0.0001 to 0.0150%, O: not more than 0.01% and Fe and inevitable impurities as a remainder, and satisfying the following formula (1). and cal. (vol. %) defined by the formula (2) is in a range of 1.0 to 9.0.

Sn+0.009Cu0.06(1)

cal. (vol. %)=4.3(1.3Si+Cr+Mo+2.2Al+Ti+Nb)3.9(30C+30N+Ni+0.8Mn+0.3Cu)31.5(2)

[Summary]

[Assignment] A precipitation hardening martensitic stainless steel having superior strength and improved welding properties.

[Solution] In mass %, C: 0.030 to 0.065%, Si: 1.0 to 2.0%, Mn: 0.51 to 1.50%, P: not more than 0.04%, S: not more than 0.0020%, Ni: 4.0 to 10.0%, Cr: 11.0 to 18.0%, Mo: 0.1 to 1.50%, Cu: 0.30 to 6.0%, Al: 0.005 to 0.2%, Sn: 0.003 to 0.030%, N: 0.001 to 0.015%, Ti: 0.15 to 0.45%, Nb: 0.15 to 0.55%, Ca: not more than 0.0025%, Mg: 0.0001 to 0.0150%, O: not more than 0.01% and Fe and inevitable impurities as a remainder, and satisfying the following formula (1). and cal. (vol. %) defined by the formula (2) is in a range of 1.0 to 9.0.

Sn+0.009Cu0.06(1)

cal. (vol. %)=4.3(1.3Si+Cr+Mo+2.2Al+Ti+Nb)3.9(30C+30N+Ni+0.8Mn+0.3Cu)31.5(2)

A steel material has a chemical composition which consists of, in mass %, C: 0.15 to 0.30%, Si: 0.02 to 1.00%, Mn: 0.20 to 0.80%, P: 0.020% or less, S: 0.028% or less, Cr: 0.80 to 1.50%, Mo: 0.08 to 0.40%, V: 0.10 to 0.40%, Al: 0.005 to 0.060%, N: 0.0150% or less, O: 0.0030% or less, and the balance: Fe and impurities, and satisfies Formulae (1) and (2), in which, at a cross section parallel to the axial direction of the steel material for a steel piston, the number of Mn sulfides is 100.0 per mm.sup.2 or less, the number of coarse Mn sulfides having an equivalent circular diameter of 3.0 m or more is in a range of 1.0 to 10.0 per mm.sup.2, and the number of oxides is 15.0 per mm.sup.2 or less.
0.42Mo+3V1.50(1)
V/Mo0.50(2)

An iron-based alloy includes (in weight percent) carbon from about 1 to about 2 percent; manganese up to about 1 percent; silicon up to about 1 percent; nickel up to about 4 percent; chromium from about 10 to about 25 percent; molybdenum from about 5 to about 20 percent; tungsten up to about 4 percent; cobalt from about 17 to about 23 percent; vanadium up to about 1.5 percent; boron up to about 0.2 percent; sulfur up to about 0.03 percent; nitrogen up to about 0.4 percent; phosphorus up to about 0.06 percent; niobium up to about 4 percent; iron from about 35 to about 55 percent; and incidental impurities. The chromium/molybdenum ratio of the iron-based alloy is from about 1 to about 2.5. The alloy is suitable for use in elevated temperature applications, such as valve seat inserts for combustion engines.

An iron-based alloy includes (in weight percent) carbon from about 1 to about 2 percent; manganese up to about 1 percent; silicon up to about 1 percent; nickel up to about 4 percent; chromium from about 10 to about 25 percent; molybdenum from about 5 to about 20 percent; tungsten up to about 4 percent; cobalt from about 17 to about 23 percent; vanadium up to about 1.5 percent; boron up to about 0.2 percent; sulfur up to about 0.03 percent; nitrogen up to about 0.4 percent; phosphorus up to about 0.06 percent; niobium up to about 4 percent; iron from about 35 to about 55 percent; and incidental impurities. The chromium/molybdenum ratio of the iron-based alloy is from about 1 to about 2.5. The alloy is suitable for use in elevated temperature applications, such as valve seat inserts for combustion engines.

Disclosed is a steel composition including specified ranges of Ni; Mo; Co; Mo+Co+Si+Mn+Cu+W+V+Nb+Zr+Ta+Cr+C; Co+Mo; Ni+Co+Mo; and traces of Al; Ti; N; Si; Mn; C; S; P; B; H; O; Cr; Cu; W; Zr; Ca; Mg; Nb; V; and Ta in specified ranges; the remainder being iron and impurities. The inclusion population, as observed by image analysis over a polished surface measuring 650 mm.sup.2 if hot-formed or hot-rolled; and measuring 800 mm.sup.2 if cold-rolled, does not contain non-metallic inclusions of diameter >10 ?m, and, in the case of a hot-rolled sheet, does not contain more than four non-metallic inclusions of diameter 5-10 ?m over 100 mm.sup.2, the observation being performed by image analysis over a polished surface measuring 650 mm.sup.2.

Embodiments of multi-process hardened golf club heads and methods of multi-process hardening of golf club heads are generally described herein. Other embodiments and methods may be described and claimed.