A heat-rolled steel plate has a chemical composition that contains, in mass %, C, Si, Mn, P, S, Al, N and Ti, and that satisfies Formula (1); and a microstructure containing bainite and ferrite. In the interior of the steel plate an average value of pole densities of an orientation group {100}<011> to {223}<110> is 4 or less, and a pole density of a {332}<113> crystal orientation is 4.8 or less. In an outer layer of the steel plate, a pole density of a {110}<001> crystal orientation is 2.5 or more. Furthermore, among Ti carbo-nitrides in the steel plate, the number density of fine Ti carbo-nitrides having a particle diameter of 10 nm or less is 1.010.sup.17 per cm.sup.3 or less, and a bake hardening amount is 15 MPa or more.

[Ti]48/14[N]48/32[S]0(1)

The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, copper, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650 C.

A high-temperature piping product is configured from a plurality of primary pipe members and a welding material. The primary pipe members are each made from an Ni-based forged alloy containing: Ni, Al, and at least one of Mo and W. The total content of the Mo and the W being 3-8 mass %. The Ni-based forged alloy exhibiting a -phase dissolution temperature of from 920 to 970 C., and the phase being precipitated in 30 volume % or more in a temperature range of from 700 to 800 C. The welding material is made from an Ni-based cast alloy having a cast structure formed by welding. The Ni-based cast alloy containing: Ni, Al, and at least one of Mo and W, the total content of the Mo and the W being 9-15 mass %, the Ni-based cast alloy exhibiting a -phase dissolution temperature of from 850 to 900 C.

A high-temperature piping product is configured from a plurality of primary pipe members and a welding material. The primary pipe members are each made from an Ni-based forged alloy containing: Ni, Al, and at least one of Mo and W. The total content of the Mo and the W being 3-8 mass %. The Ni-based forged alloy exhibiting a -phase dissolution temperature of from 920 to 970 C., and the phase being precipitated in 30 volume % or more in a temperature range of from 700 to 800 C. The welding material is made from an Ni-based cast alloy having a cast structure formed by welding. The Ni-based cast alloy containing: Ni, Al, and at least one of Mo and W, the total content of the Mo and the W being 9-15 mass %, the Ni-based cast alloy exhibiting a -phase dissolution temperature of from 850 to 900 C.

Provided are a material for hot stamping, wherein the material includes: a steel sheet including carbon (C) in an amount of 0.19 wt % to 0.25 wt %, silicon (Si) in an amount of 0.1 wt % to 0.6 wt %, manganese (Mn) in an amount of 0.8 wt % to 1.6 wt %, phosphorus (P) in an amount less than or equal to 0.03 wt %, sulfur (S) in an amount less than or equal to 0.015 wt %, chromium (Cr) in an amount of 0.1 wt % to 0.6 wt %, boron (B) in an amount of 0.001 wt % to 0.005 wt %, an additive in an amount less than or equal to 0.1 wt %, balance iron (Fe), and other inevitable impurities; and fine precipitates distributed within the steel sheet. The additive includes at least one of titanium (Ti), niobium (Nb), and vanadium (V), and the fine precipitates include nitride or carbide of at least one of titanium (Ti), niobium (Nb), and vanadium (V) and trap hydrogen.

Provided are a material for hot stamping, wherein the material includes: a steel sheet including carbon (C) in an amount of 0.19 wt % to 0.25 wt %, silicon (Si) in an amount of 0.1 wt % to 0.6 wt %, manganese (Mn) in an amount of 0.8 wt % to 1.6 wt %, phosphorus (P) in an amount less than or equal to 0.03 wt %, sulfur (S) in an amount less than or equal to 0.015 wt %, chromium (Cr) in an amount of 0.1 wt % to 0.6 wt %, boron (B) in an amount of 0.001 wt % to 0.005 wt %, an additive in an amount less than or equal to 0.1 wt %, balance iron (Fe), and other inevitable impurities; and fine precipitates distributed within the steel sheet. The additive includes at least one of titanium (Ti), niobium (Nb), and vanadium (V), and the fine precipitates include nitride or carbide of at least one of titanium (Ti), niobium (Nb), and vanadium (V) and trap hydrogen.

Provided are a material for hot stamping, wherein the material includes: a steel sheet including carbon (C) in an amount of 0.19 wt % to 0.25 wt %, silicon (Si) in an amount of 0.1 wt % to 0.6 wt %, manganese (Mn) in an amount of 0.8 wt % to 1.6 wt %, phosphorus (P) in an amount less than or equal to 0.03 wt %, sulfur (S) in an amount less than or equal to 0.015 wt %, chromium (Cr) in an amount of 0.1 wt % to 0.6 wt %, boron (B) in an amount of 0.001 wt % to 0.005 wt %, an additive in an amount less than or equal to 0.1 wt %, balance iron (Fe), and other inevitable impurities; and fine precipitates distributed within the steel sheet. The additive includes at least one of titanium (Ti), niobium (Nb), and vanadium (V), and the fine precipitates include nitride or carbide of at least one of titanium (Ti), niobium (Nb), and vanadium (V) and trap hydrogen.

Provided are a material for hot stamping, wherein the material includes: a steel sheet including carbon (C) in an amount of 0.19 wt % to 0.25 wt %, silicon (Si) in an amount of 0.1 wt % to 0.6 wt %, manganese (Mn) in an amount of 0.8 wt % to 1.6 wt %, phosphorus (P) in an amount less than or equal to 0.03 wt %, sulfur (S) in an amount less than or equal to 0.015 wt %, chromium (Cr) in an amount of 0.1 wt % to 0.6 wt %, boron (B) in an amount of 0.001 wt % to 0.005 wt %, an additive in an amount less than or equal to 0.1 wt %, balance iron (Fe), and other inevitable impurities; and fine precipitates distributed within the steel sheet. The additive includes at least one of titanium (Ti), niobium (Nb), and vanadium (V), and the fine precipitates include nitride or carbide of at least one of titanium (Ti), niobium (Nb), and vanadium (V) and trap hydrogen.

A metal powder for additive manufacturing including, in wt %, Ni 9.0-12.0, Cr 2.0-4.5, Mo 3.5-4.5 and Ti 0.1-1.0; and, if present, Si up to 0.5, Mn up to 0.5, Al up to 0.1, Co up to 0.1, N up to 0.05 and/or C up to 0.07; the balance being Fe and usual impurities. A use of the metal powder for additive manufacturing is also provided, as well as a process for producing an object by additive manufacturing, including building an object by iteratively melting particles of the metal powder and solidifying the melt, and subsequently aging the built object without any preceding solution annealing thereof.

Disclosed is a ferritic stainless steel with improved high temperature creep resistance. The disclosed ferritic stainless steel comprises by weight %: 0.005 to 0.03% of C, 0.005 to 0.03% of N, 0.05 to 0.9% of Si, 0.05 to 0.9% of Mn, 14.0 to 19.0% of Cr, 0.1 to 0.6% of Ti, 0.1 to 0.6% of Nb, 0.1 to 0.6% of Cu, 0.01 to 0.04% of P, 0.01% or less (excluding 0) of S, and the balance of iron (Fe) and inevitable impurities, and is characterized by satisfying Expressions (1) and (2) below.
0.5Nb/Cu3Expression (1)
20[2Nb+Ti]/[C+N]Expression (2) wherein Nb, Cu, Ti, C, and N denote contents (wt %) of each element.