A quench and temper steel alloy is disclosed having the following composition in weight percent. TABLE-US-00001 C 0.1-0.4 Mn 0.1-1.0 Si 0.1-1.2 Cr 9.0-12.5 Ni 3.0-4.3 Mo   1-2 Cu 0.1-1.0 Co   1-4 W  0.2 max. V 0.1-0.6 Ti  0.1 max. Nb up to 0.01 Ta up to 0.01 Al   0-0.25 N 0.1-0.35 Ce 0.006 max. La 0.006 max.
The balance of the alloy is iron and the usual impurities found in similar grades of quench and temper steels intended for similar use or service, including not more than about 0.01% phosphorus and not more than about 0.010% sulfur. A quenched and tempered steel article made from this alloy is also disclosed. Further disclosed is a method of making the alloy.

A steel consists of, in mass %, C: 0.25 to 0.45%, Si: 0.10 to 0.50%, Mn: 0.40 to 0.70%, P: 0.015% or less, S: 0.005% or less, Cr: 0.80 to 1.50%, Mo: 0.17 to 0.30%, V: 0.24 to 0.40%, Al: 0.005 to 0.100%, N: 0.0300% or less, O: 0.0015% or less, and the balance being Fe and impurities, and satisfies Formula (1) to Formula (4) described in the present specification, wherein: its microstructure is composed of ferrite and pearlite having a total area fraction of 5.0 to 100.0%, and a hard phase having a total area fraction of 0 to 95.0%; a proportion of a total area of CaO—CaS—MgO—Al.sub.2O.sub.3 composite oxides with respect to a total area of oxides in the steel is 30.0% or more; and a number density of oxides having an equivalent circle diameter of 20.0 μm or more is 15.0 pieces/mm.sup.2 or less.

A steel sheet including a chemical composition in mass %: C: 0.14-0.60%, Si+Al≤3.00, P 0.030%, S≤0.0050%, N 0.015%, B≤0.0050%, C×Mn≤0.80, Mn+Ni+Cu+1.3Cr+4(Mo+W)≥0.80, 0.003≤Ti+Zr+Hf+V+Nb+Ta+Sc+Y≤0.20, Sn+As+Sb+Bi≤0.020, Mg: 0 to 0.005%, Ca: 0 to 0.005%, REM: 0 to 0.005%, with the balance: Fe and impurities, and satisfying Ms=546 ×exp(−1.362 x C)−11 ×Si−30 ×Mn−18 ×Ni−20 ×Cu−12×Cr −8(Mo+W)≥200.

The steel material according to the present disclosure has a chemical composition consisting of, in mass %, C: more than 0.20 to 0.35%, Si: 0.05 to 1.00%, Mn: 0.02 to 1.00%, P: 0.025% or less, S: 0.0100% or less, Al: 0.005 to 0.100%, Cr: 0.40 to 1.50%, Mo: 0.30 to 1.50%, Ti: 0.002 to 0.050%, B: 0.0001 to 0.0050%, N: 0.0100% or less and O: 0.0100% or less, with the balance being Fe and impurities, and satisfies Formula (1) and Formula (2) described in the description. The yield strength is 862 MPa or more. A numerical proportion of precipitates having an equivalent circular diameter within a range of 20 to 300 nm among precipitates having an equivalent circular diameter of 20 nm or more in the steel material is 0.85 or more.

The martensitic stainless steel material according to the present disclosure consists of C: less than 0.030%, Si: 1.00% or less, Mn: 0.05 to 2.00%, Cr: 11.50 to 14.00%, Ni: 5.00 to 7.50%, Mo: 1.10 to 3.50%, Cu: 0.50 to 3.50%, Co: 0.01 to 0.30%, Al: 0.001 to 0.100%, N: 0.001 to 0.100%, and the balance: Fe and impurities. The microstructure is composed of retained austenite in an amount of 0 to 15 vol%, and ferrite in an amount of 0 to 10 vol%, with the balance being martensite. The yield strength is 862 MPa or more, and a number density of Cu precipitates is 3.0 x 10.sup.21 to 50.0 x 10.sup.21 /m.sup.3.

Heat treatment of an Alloy 282 which has been subjected to an initial solution annealing followed by cooling can be heat treated by heating the Alloy 282 to a temperature between 954° C. and 1010° C. until the gamma prime (γ′) phase is sufficiently dissolved, and cooling the Alloy 282 to a temperature a sufficiently low temperature, and at a sufficiently high cooling rate, to suppress gamma prime precipitation. A component such as a turbine exhaust case and a gas turbine engine made of said alloy can be heat treated in the above manner.

There is provided a precipitation hardening steel with the composition: C: 0.05-0.30 wt %, Ni: 3-9 wt %, Mo: 0.5-1.5 wt %, Al: 1-3 wt %, Cr: 2-14 wt %, V: 0.25-1.5 wt %, Co: 0-0.03 wt %, Mn: 0-0.5 wt %, Si: 0-0.3 wt %, and remaining part up to 100 wt % is Fe and impurity elements, with the additional proviso that the amounts of Al and Ni also fulfil Al=Ni/3±0.5 in wt %. There is the possibility to have very low amounts of cobalt, well below 0.01 wt %. The precipitation hardening steel displays, low segregation, high yield strength at elevated temperatures, high resistance against corrosion, and can also suitably be nitrided. The precipitation hardening steel is more economical to manufacture compared to steel according to the state of the art with the same strength at elevated temperatures.

An improved grinding ball may include a carbon content of 1.1 to 1.4 wt %, a chromium content of 10 to 14 wt %, a manganese content of 0.8 to 1.5 wt %, a silicon content of 0.6 to 1 wt %, a molybdenum content of less than 1 wt %, a nickel content of less than 1 wt %, any impurities with a total content of less than 0.5 wt %, the balance to obtain 100% being iron. The grinding ball includes a discrete distribution of chromium carbides as opposed to a network distribution.

The present disclosure relates to a method for manufacturing a non-oriented electrical steel sheet and the manufactured non-oriented electrical steel sheet, the method including: heating a slab containing, by wt %, 0.005% or less of C, 2.5 to 4.0% or less of Si, 0.1% or less of P, 0.1 to 2.0% of Al, 0.2 to 2.5% of Mn, 0.003% or less of N, 0.005% or less of Ti and Nb, 0.003% or less of S, 0.005 to 0.025% of V, 0.1% or less of Cu, and a balance of Fe and inevitably mixed impurities, and satisfying the following Expression 1; hot-rolling the slab to manufacture a hot-rolled sheet; cold-rolling the hot-rolled sheet to manufacture a cold-rolled sheet; and performing final annealing on the cold-rolled sheet, wherein [Expression 1] is represented by (51*[C])/12−0.002≤[V]≤(51*[C])/12+0.004 (in Expression 1, [C] and [V] represent contents (wt %) of C and V, respectively).

A steel sheet has a tensile strength of 1310 MPa or higher, a specified chemical composition, and a steel microstructure containing martensite at an area ratio of 70% or more, bainite at an area ratio of 30% or less, and ferrite and retained austenite at a total area ratio of 5% or less, in which, at a ¼ thickness position of the steel sheet, a number density of carbides having long axes of 0.5 μm or more is 60000 carbides/mm.sup.2 or less, in a ¼-to-¾ thickness region of the steel sheet, a number density of inclusion grains having equivalent circle diameters of 4.0 μm or more is 10 grains/mm.sup.2 or more and 30 grains/mm.sup.2 or less, and, in a surface-to-¼ thickness region of the steel sheet, a number density of inclusion grains having equivalent circle diameters of 4.0 μm or more is 27 grains/mm.sup.2 or less.