A graphite steel available as a material for mechanical parts of industrial machines or automobiles, and more particularly, a steel wire for graphitization heat treatment and a graphite steel and methods of manufacturing the same. The graphite steel includes, in percent by weight (wt %), 0.6 to 0.9% of carbon (C), 2.0 to 2.5% of silicon (Si), 0.1 to 0.6% of manganese (Mn), 0.015% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.01 to 0.05% of aluminum (Al), 0.01 to 0.02% of titanium (Ti), 0.0005 to 0.002% of boron (B), 0.003 to 0.015% of nitrogen (N), 0.005% or less of oxygen (O), and the remainder of iron (Fe) and inevitable impurities, and satisfying Equation (1) below: wherein graphite grains are distributed in a ferrite base as a microstructure and a graphitization rate is 100%, (1) −0.003<[N]−[Ti]/3.43−[B]/0.77<0.003, wherein in Equation (1), [Ti], [N], and [B] are wt % of titanium, nitrogen, and boron, respectively.

Provided are a non-quenched and tempered wire rod having excellent drawability and impact toughness suitable for materials for automobiles or mechanical parts and a method of manufacturing the same. According to an embodiment of the present disclosure, the non-quenched and tempered wire rod includes, in percent by weight (wt %), 0.05 to 0.35% of carbon (C), 0.05 to 0.5% of silicon (Si), 0.5 to 2.0% of manganese (Mn), 1.0% or less of chromium (Cr), 0.03% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.01 to 0.07% of soluble aluminum (sol.Al), 0.01% or less of nitrogen (N), at least one of 0.1% or less of niobium (Nb), 0.5% or less of vanadium (V), and 0.1% or less of titanium (Ti), and the remainder of iron (Fe) and inevitable impurities, and includes a ferrite-pearlite layered structure, as a microstructure, in a rolling direction.

A free-cutting and non-quenched and tempered steel, comprising the following chemical elements by mass percentages: C: 0.35-0.45%, Si: 0.45-0.0.65%, Mn: 1.35-1.65%, S: 0.025-0.065%, V: 0.07-0.15%, Ti: 0.01-0.018%, N: 0.012-0.017%, Al: 0.015-0.035%, Ca: 0.0008-0.0025%, with the remaining being iron and other unavoidable impurities, wherein the S and Ca elements satisfy the relationship S/Ca=20-60. A manufacturing method of the free-cutting and non-quenched and tempered steel, comprising the following steps: (1) smelting and refining; (2) casting; (3) rolling; (4) forging; and (5) two-stage cooling.

A method to manufacture a steel wire spring core for a mattress or for seating is described, which comprises the steps of providing a carrier comprising steel wire; repeatedly cold coiling a steel wire spring from steel wire taken from the carrier; and connecting a series of the coiled steel wire springs to each other. The steel wire has a diameter d between 0.8 and 4.5 mm; and has a drawn pearlitic microstructure. The steel wire comprises a steel alloy having a carbon content between 0.35 wt % and 0.85 wt %. The steel wire on the carrier has a ratio—expressed as a percentage—of the yield strength R.sub.po 2 (in MPa) over the tensile strength R.sub.m (in MPa) higher than 85%.

The present disclosure relates to a steel wire rod enabling the omission of softening heat treatment and a method of manufacturing same. An embodiment of the present disclosure provides a steel wire rod enabling the omission of softening heat treatment and a method of manufacturing same, the steel wire rod comprising, in weight %, 0.2-0.45% of C, 0.02-0.4% of Si, 0.3-1.5% of Mn, 0.01-1.5% of Cr, 0.02-0.05% of Al, 0.01-0.5% of Mo, 0.01% or less of N, and the balance Fe and other unavoidable impurities, wherein the microstructure of the steel wire rod is a composite structure of proeutectoid ferrite+perlite as a main phase; the steel wire rod contains 10 area % or less (including 0%) of at least one of bainite or martensite; and the average colony size of the perlite is 5 μm or less.

According to one aspect of the present invention, what is provided is a rail including, by mass %: C: 0.75% to 1.20%; Si: 0.10% to 2.00%; Mn: 0.10% to 2.00%; Cr: 0.10% to 1.20%; V: 0.010% to 0.200%; N: 0.0030% to 0.0200%; P≤0.0250%; S≤0.0250%; Mo: 0% to 0.50%, Co: 0% to 1.00%; B: 0% to 0.0050%; Cu: 0% to 1.00%; Ni: 0% to 1.00%; Nb: 0% to 0.0500%; Ti: 0% to 0.0500%; Mg: 0% to 0.0200%; Ca: 0% to 0.0200%; REM: 0% to 0.0500%; Zr: 0% to 0.0200%; Al: 0% to 1.00%; and a remainder consisting of Fe and impurities, in which a structure ranging from an outer surface of a head portion as an origin to a depth of 25 mm includes 95% or greater of a pearlite structure by area ratio, the hardness of the structure is in a range of Hv 360 to 500, and in ferrite of the pearlite structure at a position at a depth of 25 mm from the outer surface of the head portion as the origin, the number density of a V nitride having a grain size of 0.5 to 4.0 nm and including Cr is in a range of 1.0×10.sup.17 to 5.0×10.sup.17 cm.sup.−3.

A predetermined composition is had, when a C content is represented by (C %), in a case of (C %) being not less than 0.35% nor more than 0.65%, a volume fraction of pearlite is 64×(C %)+52% or more, and in a case of (C %) being greater than 0.65% and 0.85% or less, the volume fraction of pearlite is not less than 94% nor more than 100%, and a structure of the other portion is composed of one or two of proeutectoid ferrite and bainite. Further, in a region to a depth of 1.0 mm from a surface, a volume fraction of pearlite block having an aspect ratio of 2.0 or more is not less than 70% nor more than 95%, and a volume fraction of pearlite having an angle between an axial direction and a lamellar direction on a cross section parallel to the axial direction of 40° or less is 60% or more with respect to all pearlite.

A steel pipe for fuel injection pipe has a tensile strength of 500 to 900 MPa and a yield ratio of 0.50 to 0.85, and has a critical internal pressure (IP) satisfying [IP≥0.41×TS×α] (α=[(D/d).sup.2−1]/[0.776×(D/d).sup.2], where TS: tensile strength (MPa) of the steel pipe, D: steel pipe outer diameter (mm), and d: steel pipe inner diameter (mm)), wherein a circumferential-direction residual stress on an inner surface of the pipe is −20 MPa or lower after the steel pipe is split in half in a pipe axis direction.

A method for manufacturing a bainite high-strength seamless steel tube, comprising the following steps: smelting, manufacturing a billet, heating, perforating, rolling, stretch reducing or sizing to obtain tube, and cooling. In the cooling step, the quenching starting temperature is controlled to be at least 20° C. higher than the Ar3 temperature of the steel grade; the finish cooling temperature is controlled to be within a range between T1 and T2, where T1=519-423 C-30.4Mn, T2=780-270 C-90Mn, and the units of the T1 and the T2 are ° C.; in the formulas, C and Mn respectively represent the mass percents of element C and element Mn of the steel grade, the content of the element C is 0.06-0.2%, and the content of the element Mn is 1-2.5%; the cooling rate is controlled to be 15-80° C./s; and the finished product of the bainite high-strength seamless steel tube is directly obtained after the cooling step. The manufacturing of a bainite high-strength seamless steel tube using the method requires neither the addition of precious alloying elements nor the subsequent heat treatment. Therefore the production costs are low.

This hot-rolled steel sheet has a predetermined chemical composition. The metallographic structure at a sheet thickness ¼ depth from a surface and at a center position in a sheet width direction in a sheet width cross section parallel to a rolling direction contains, by area %, 77.0% to 97.0% of bainite and tempered martensite in total, 0% to 5.0% of ferrite, 0% to 5.0% of pearlite, 3.0% or more of residual austenite, and 0% to 10.0% of martensite. The average grain size of the metallographic structure excluding the residual austenite is 7.0 μm or less. The C concentration in the residual austenite is 0.5 mass % or more. The number density of iron-based carbides having a diameter of 20 nm or more is 1.0×10.sup.6 carbides/mm.sup.2 or more.