C22B1/005

Chemical dismantling of permanent magnet material and battery material

Certain method embodiments are described and useful for recycling permanent magnet materials (e.g. permanent magnet alloys) and battery materials (e.g. battery electrode materials) to extract critical and/or valuable elements including REEs, Co and Ni. Method embodiments involve reacting such material with at least one of an ammonium salt and an iron (III) salt to achieve at least one of a liquid phase chemical reaction and a mechanochemical reaction.

PLANT FOR THE DISPOSAL OF LITHIUM BATTERIES AND RECOVERY OF LITHIUM
20220021042 · 2022-01-20 ·

Plant for disposing and recovering lithium batteries, including: storage; supply; crushing, submerged in liquid solution and in overpressure of inert gas, for destroying the batteries through cutting discs and milling cutters; torch for burning the gaseous residue and possible organic solvents; centrifugation and screening of the scrap; evaporation, for removing the volatile solvents and concentrating the lithium in solution; recovery of the heavy metals, with chemical/physical reactor which, by way of a filter press, distributes the products between a liquids tank and a solids tank; recovery of lithium wherein the lithium is recovered through the crystallisation of lithium carbonate by adding sodium carbonate and heating, contained in a tank and heating the solution in a special heated tank, in a chemical/physical reactor.

BATTERY RECYCLING PROCESS
20220017989 · 2022-01-20 · ·

A method for the recovery of metals from a feed stream containing one or more value metals and lithium, the method comprising: subjecting the feed stream to a sulphuric acid leach to form a slurry comprising a pregnant leach solution of soluble metal salts and a solid residue; separating the pregnant leach solution and the solid residue; subjecting the pregnant leach solution to one or more separate solvent extraction steps, wherein each solvent extraction step recovers one or more value metals from the pregnant leach solution, the remaining pregnant leach solution comprising lithium; and recovery of lithium from the pregnant leach solution.

Method for preparing ferrovanadium alloys based on aluminothermic self-propagating gradient reduction and slag washing refining

The present invention provides a method for preparing ferrovanadium alloys based on aluminothermic self-propagating gradient reduction and slag washing refining. The method includes the steps of (1) performing aluminothermic self-propagating gradient reduction; (2) performing heat preserving and smelting to obtain an upper layer alumina-based slag and a lower layer alloy melt; (3) jetting refining slags into the lower layer alloy melt, and performing stirring and slag washing refining; and (4) cooling the refined high-temperature melt to room temperature, and removing an upper layer smelting slag to obtain the ferrovanadium alloys.

PRODUCTION OF FINE GRAIN MAGNESIUM OXIDE AND FIBROUS AMORPHOUS SILICA FROM SERPENTINITE MINE TAILINGS

The present disclosure broadly relates to a process for recovering magnesium as magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. More specifically, but not exclusively, the present disclosure relates to metallurgical and chemical processes for recovering magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. The process broadly comprises applying a sufficient amount of shear deformation force to the serpentine feedstocks to produce a particulate material of reduced size; subjecting the particulate material to magnetic separation to produce a primary magnetic separation product and iron-reduced tailings; and digesting the iron-reduced tailings into nitric acid, producing a magnesium-rich pregnant solution and insoluble solids. The process further comprises adjusting the pH of the pregnant solution to values ranging from about 5.0 to about 7.0.

Process for Recycling Cobalt and Nickel from Lithium Ion Batteries

A process for recovering a nickel cobalt manganese hydroxide from recycled lithium-ion battery (LIB) material such as black mass, black powder, filter cake, or the like. The recycled LIB material is mixed with water and either sulfuric acid or hydrochloric acid at a pH less than 2. Cobalt, nickel, and manganese oxides from the recycled lithium-ion battery material dissolve into the acidic water with the reductive assistance of gaseous sulfur dioxide. Anode carbon is filtered from the acidic water, leaving the dissolved cobalt, nickel, and manganese oxides in a filtrate. The filtrate is mixed with aqueous sodium hydroxide at a pH greater than 8. Nickel cobalt manganese hydroxide precipitates from the filtrate. The nickel cobalt manganese hydroxide is filtered from the filtrate and dried. The filtrate may be treated ammonium fluoride or ammonium bifluoride to precipitate lithium fluoride from the filtrate. The composition ratio of nickel to cobalt to manganese in the acid filtrate may be adjusted to a desired ratio. The anode carbon is recovered and purified for reuse.

SYSTEM AND METHOD FOR RECOVERING DESIRED MATERIALS USING A BALL MILL OR ROD MILL
20220001391 · 2022-01-06 ·

A method for recovering metals from waste in which material is screened to leave a nonfibrous feedstock, the nonfeedstock is comminuted with a mill (e.g., a ball mill or rod) to liberate, flatten and separate the nonfibrous feedstock to obtain a mix of a metal fraction and residue, and the metal fraction and the residue are collected. There is a system employing the same to treat such materials.

Process for upgrading waste powders from mines, containing iron oxides
11168381 · 2021-11-09 · ·

A process for upgrading waste powders of the mining industry containing iron oxides is described, which includes preparing a mixture containing powder based on iron oxides, an aqueous dispersion of a thermosetting resin and optionally carbon powder, and a catalyst of acidic nature; kneading the mixture at a temperature between 5 and 100° C. to form a homogeneous paste, and granulating such homogeneous paste at a temperature between 100 and 300° C., thus obtaining granules of powder based on iron oxides and optionally carbon powder bound by the resin that has been polymerized.

Apparatus and method for feeding material
11167347 · 2021-11-09 · ·

A material feeding apparatus is disclosed. An apparatus for removing a surface oxide of a metal material and feeding the metal material to a melting furnace, according to an embodiment of the present disclosure, includes: a housing including a material dropping chamber for feeding and discharging the metal material and a material etching chamber for performing a plasma etching process; and a pretreatment casing configured to reciprocate between the material dropping chamber and the material etching chamber in the housing, wherein the pretreatment casing receives the metal material from the material dropping chamber to store the metal material, moves to the material etching chamber to plasma-etch a surface oxide layer of the stored metal material, and then returns to the material dropping chamber to drop the etched metal material into the melting furnace.

Hard drive non-destructive dismantling system
11167384 · 2021-11-09 · ·

A system and method for dismantling components of electronic media electronic storage devices such as hard disk drives, solid state drives and hybrid hard drives. The components are dismantled in a nondestructive manner so as to be capable of reuse. First devices loosen the various components of the storage device, Second devices are provided for removing components from the storage device. A holding chassis receives the storage device, and moves the storage device for engagement with the first and second devices. A mechanism may be provided for destroying the data containing portion of the electric storage device when it is removed from the storage device. A database of information concerning past and current storage devices including their configurations, component locations and screw/fastener locations is provided along with a scanning system for retrieving information about the storage device being introduced into the system. The scanned information and information from the database is used to control and position the first and second devices and holding chassis.