The present disclosure provides Molecularly Imprinted Polymer (MIP) technology for selectively sequestering one or more target molecules from chemical mixtures. Also disclosed herein are MIP beads and methods of making and using thereof.

The present disclosure relates to a method for extracting lithium from a lithium-containing material. For example, the method can comprise leaching a roasted lithium-containing material under conditions suitable to obtain an aqueous composition comprising a lithium compound such as lithium sulfate and/or lithium bisulfate. The aqueous composition comprising lithium sulfate and/or lithium bisulfate can optionally be used, for example, in a method for preparing lithium hydroxide comprising an electromembrane process. The roasted lithium-containing material can be prepared, for example by a method which uses an aqueous composition comprising optionally lithium sulfate and/or lithium bisulfate which can be obtained from a method for preparing lithium hydroxide comprising an electromembrane process such as a two-compartment monopolar or bipolar electrolysis process.

The present disclosure relates to a method for extracting lithium from a lithium-containing material. For example, the method can comprise leaching a roasted lithium-containing material under conditions suitable to obtain an aqueous composition comprising a lithium compound such as lithium sulfate and/or lithium bisulfate. The aqueous composition comprising lithium sulfate and/or lithium bisulfate can optionally be used, for example, in a method for preparing lithium hydroxide comprising an electromembrane process. The roasted lithium-containing material can be prepared, for example by a method which uses an aqueous composition comprising optionally lithium sulfate and/or lithium bisulfate which can be obtained from a method for preparing lithium hydroxide comprising an electromembrane process such as a two-compartment monopolar or bipolar electrolysis process.

The present invention is related to a polymer membrane for the selective extraction of cobalt (II) ions as well as a method for extracting cobalt (II) ions using said polymer membrane.

A method of producing substantially pure rare earth elements (REEs) from a mixture, including the steps of dissolving a mixture containing REEs in a strong acid to result in a dissolved mixture of metal ions, including that of REEs, capturing metal ions of REEs in a first set of chromatographic columns comprising strong acid cation exchange resins, washing said first set of chromatographic columns with a salt solution to remove non-adsorbing metal ions, eluting metal ions of REES from said first set of chromatographic columns with a first ligand solution to result in a solution of enriched metal ions of REEs, loading said solution of enriched metal ions of REEs onto a second set of chromatographic columns, and eluting bound metal ions of REEs stepwise from said second set of chromatographic columns using a second ligand solution to afford a substantially pure REE. The second set of chromatographic columns comprises hydrous polyvalent metal oxide selected from the group consisting of TiO.sub.2, ZrO.sub.2, or SnO.sub.2. The ligand of the second ligand solution coordinates with said hydrous polyvalent metal oxide.

This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

The invention relates to a method for producing a scandium-containing concentrate from the wastes of alumina production and extracting high-purity scandium oxide from the same. Provided is a method for producing a scandium-containing concentrate from a red mud, wherein the Sc.sub.2O.sub.3 content therein is least of 15 wt. %, the TiO.sub.2 content not more than 3 wt. %, the ZrO.sub.2 content not more than 15 wt. %, and wherein scandium in the concentrate is in form of a mixture of Sc(OH).sub.3 hydroxide with ScOHCO.sub.3.4H.sub.2O. Also provided is a method for producing high-purity scandium oxide, with a purity of approximately 99 wt. %.

The invention relates to a method for producing a scandium-containing concentrate from the wastes of alumina production and extracting high-purity scandium oxide from the same. Provided is a method for producing a scandium-containing concentrate from a red mud, wherein the Sc.sub.2O.sub.3 content therein is least of 15 wt. %, the TiO.sub.2 content not more than 3 wt. %, the ZrO.sub.2 content not more than 15 wt. %, and wherein scandium in the concentrate is in form of a mixture of Sc(OH).sub.3 hydroxide with ScOHCO.sub.3.4H.sub.2O. Also provided is a method for producing high-purity scandium oxide, with a purity of approximately 99 wt. %.

This invention relates to a hydrometallurgical process for the recovery and separation of valuable precious, base or rare elements such as platinum group metals (PGMs), gold or silver, and other valuable base and rare metals such as nickel, cobalt, copper, rare earth elements (REE), yttrium and scandium, as well as uranium, thorium, manganese, zinc, cadmium, molybdenum, titanium, tin, and other minor elements such as vanadium, germanium and gallium from a feed material comprising ores, concentrates and other materials. In particular, the process comprises quantitative removal of additional base, rare and gangue elements for increased efficiency of further treatment of the solids for valuable metals recovery and/or recycling and/or separation of valuable metals from pressure leach residue and may be integrated into one or more existing valuable element extraction processes.