C22B7/001

METHOD AND SYSTEM FOR ASH TREATMENT
20210388463 · 2021-12-16 ·

A method of the invention for treatment of particulate material for metal recovery includes heating a furnace to a first temperature, feeding a particulate material into the furnace, and before or after heating of the raw material, feeding a reducing gas flow through the furnace. The particulate material is heated in the furnace for volatilizing one or more metals contained in the ash into the gas flow, and the volatilized particles are recovered in one or more collection units. A system for treatment of particulate material for metal recovery includes a heated furnace for receiving flows of reduction gas and particulate material, a collection unit for volatilized particles, and a collection unit for non-volatilized material.

Plant and method for recovering metals and/or metal oxides from industrial process waste, in particular refinery waste
11199360 · 2021-12-14 · ·

A plant for recovering metals and/or metal oxides from industrial process waste, in particular oil product refining waste, comprises a furnace; a feed line connected to a main inlet of the furnace and configured to feed the furnace with a solid waste containing metals, in particular in oxide form; an outlet line, connected to a solid phase outlet of the furnace and configured to draw a metal-enriched solid phase out of the furnace; the furnace is a belt conveyor furnace having a belt conveyor closed in a loop with a substantially horizontal configuration and having a top face, which receives the waste to treat and conveys it between two longitudinal opposite ends of the belt conveyor furnace respectively provided with the main inlet and the solid phase outlet.

PROCESS FOR THE SELECTIVE RECOVERY OF TRANSITION METALS FROM ORGANIC RESIDUES
20210388462 · 2021-12-16 · ·

There is a process for the selective recovery of transition metals from an organic stream containing transition metals. The organic stream and possibly a first extractor if solid, are melted up to the liquid state. The extractor consists of an ionic liquid or a mixture of two or more ionic liquids and the ionic liquid contains an ammonium salt as cation and as anion an anion with chelating properties. A melted organic stream and a first extractor, optionally melted, are fed to a first liquid-liquid extraction unit working at a temperature of at least 150° C. where the liquid-liquid extraction is carried out obtaining a liquid mixture containing an ionic liquid, or a mixture of two or more ionic liquids, and metals. After extraction, the liquid mixture is cooled at a temperature between 0° C. and 70° C. and becomes biphasic; then the cooled mixture is sent to a first separation unit, to separate a liquid phase that contains ionic liquids and metals, and a metal-depleted solid phase. After the first separation, the separated metal-depleted solid phase is optionally sent to a washing unit to which a solvent is fed, so as to eliminate the residual ionic liquid by transferring it into the solvent and obtaining a metal-depleted solid phase. Then the separate liquid phase containing ionic liquids and metals is sent into a liquid-liquid precipitation and separation unit, adding a counter-solvent, thereby obtaining a solid phase containing the metals and a liquid stream containing counter-solvent and ionic liquids.

Comprehensive Recovery Method Of Pyrolysis Polymetallic Product From Waste Integrated Circuit Board
20220205063 · 2022-06-30 ·

The invention relates to a method for multi-metal products recovery from pyrolytic waste integrated circuit boards. The method mainly comprises the steps of smelting and blending, atomization, acidolysis and filtration, noble metal recycling, copper extraction and back extraction, nickel extraction and back extraction. Compared with the prior art, the method has the advantages that smoke pollution and the smelting slag treatment in the process of preparing a black copper ingot through multi-metal collaborative smelting are reduced, and the problems of low anode efficiency of the black copper electrolysis process are solved. Meanwhile, the high-temperature high-oxygen atomized gas generated in the atomizing process provides a heat source and an oxygen source for subsequent acidolysis, so that the energy consumption is further reduced. The method has the advantages such as short process, remarkable energy conservation and emission reduction.

Method of recovering materials bound to a metallic substrate using cryogenic cooling
11359259 · 2022-06-14 · ·

A recycling process that facilitates separation of materials from metallic substrates by cryogenically cooling the recyclable items to induce embrittlement of the metals. Embrittled metals may be shattered more efficiently and with a higher yield of materials bound to the metallic substrates. Metal embrittlement may be induced by mixing the source stream with liquid nitrogen, and cooling the stream to approximately minus 200° F. Multiple recovery stages may be employed to maximize the yield of the target materials. Embodiments may enable recovery of platinum group metals (PGMs) from catalytic converters with metallic foil substrates. Yield of PGMs may be enhanced by employing a primary recovery stage and a secondary recovery stage, by cryogenically cooling input materials for each stage, by mixing the pulverized material in secondary recovery with an aqueous solution to dissipate attractive charges, and by wet screening the pulverized material slurry to obtain the PGM particles.

METHOD FOR PROCESSING ELECTRONIC/ELECTRICAL DEVICE COMPONENT SCRAPS

Provided is a method for processing electronic and electrical device component scrap, which can improve an efficiency of sorting of raw materials fed to the smelting step from electronic and electrical device component scrap, and reduce losses of valuable metals. A method for processing electronic and electrical device component scrap which includes removing powdery objects contained in electronic and electrical device component scrap prior to a step of separating non-metal objects or metal objects from the electronic and electrical device component scrap containing the metal objects and the non-metal objects, using a metal sorter including: a metal sensor, a color camera, an air valve, and a conveyor.

PROCESS OF EXTRACTION OF METALS FROM A WET MASS OF WASTE

Described is a process of extracting metals from a wet mass which comprises: a step A of concentrating the metals in a carbonaceous solid by means of a thermochemical treatment of the wet mass, with the ancillary production of a treatment gas; a step B of thermochemical decomposition of the carbonaceous solid in an atmosphere constituted by an operating gas which contains oxygen in substoichiometric quantity to carry out the thermochemical decomposition in order to promote a combination of the metals with substances present in the carbonaceous solid to form salts and others solid compounds and to concentrate the latter in residual ashes of the carbonaceous solid at the same time providing for the formation of a combustible synthesis gas comprising hydrocarbons from the carbonaceous solid; a step C of extraction of the metals from the ashes produced.

METHOD FOR RECYCLING BATTERY BY INCOMPLETE EXTRACTION
20230272503 · 2023-08-31 ·

Disclosed is an incomplete extraction method for recycling batteries, which may include: introducing a pretreatment gas into a device loaded with a waste battery powder, and bringing a gas outlet into communication with absorption liquid A and absorption liquid B in order; raising the temperature and introducing the pretreatment gas; reducing the temperature and introducing a reaction gas; raising the temperature, introducing the reaction gas, and then introducing the pretreatment gas; and reducing the temperature, and turning off the pretreatment gas; adding an extractant to absorption liquid A, mixing the mixture, taking organic phase A, adding a stripping agent, and taking aqueous phase A; and adjusting the pH to acidity, then adding an extractant, taking organic phase B, adding a stripping agent to obtain a stock solution enriched in Li, Mn, Ni and Co.

ACTIVE MATERIAL RECOVERY METHOD USING POSITIVE ELECTRODE SCRAP
20230275278 · 2023-08-31 ·

A method of recovering an active material from a positive electrode scrap and reusing the active material is provided. The method includes (a) heat treating a positive electrode scrap including a positive electrode active material layer on a current collector in air to thermally decompose a binder and a conductive material in the positive electrode active material layer, separating the current collector from the positive electrode active material layer, and recovering an active material in the positive electrode active material layer, wherein the active material comprises a lithium composite transition metal oxide; (b) washing the recovered active material with a cleaning solution; (c) adding a lithium precursor to the washed active material and annealing the active material; and (d) optionally performing surface coating on the annealed active material and obtaining a reusable active material, wherein an amount of the lithium precursor added in step (c) is determined so that an amount of a remaining lithium compound in the reusable active material is 0.0001 to 1.2 wt %.

Separating and melting system and method for waste lead grid in waste lead acid storage battery recycling

A separating and melting system and method for a waste lead grid in waste lead acid storage battery recycling is provided. A drying drum is mounted on an upper end of a smelting apparatus, a dust remover is connected to an upper end of the drying drum by a flue gas duct, a lead grid turnover box is connected to the upper end of the drying drum, and a lead-containing liquid agitator passes through the drying drum into the smelting apparatus; a spiral feeder is mounted on the smelting apparatus and located in the drying drum, one end of a lead grid barrier plate is placed on the spiral feeder, and the other end of the lead grid barrier plate is placed on an inner wall of the drying drum; an automatic ash acquiring machine is mounted on the smelting apparatus.